Synthesis of magnetic Pb/Fe3O4/SiO2 and its catalytic activity for propylene carbonate synthesis via urea and 1,2-propylene glycol

doi:10.1007/s11705-009-0055-2

Front Chem Eng Chin

2009, Vol. 3

Issue (2) : 215-218 https://doi.org/10.1007/s11705-009-0055-2

RESEARCH ARTICLE

Synthesis of magnetic Pb/Fe₃O₄/SiO₂ and its catalytic activity for propylene carbonate synthesis via urea and 1,2-propylene glycol

Hualiang AN, Xinqiang ZHAO(

), Zhiguang JIA, Changcheng WU, Yanji WANG

Hebei Provincial Key Lab of Green Chemical Technology and High Efficient Energy Saving, Hebei University of Technology, Tianjin 300130, China

Download: PDF(180 KB) HTML
Export: BibTeX | EndNote | Reference Manager | ProCite | RefWorks

Abstract

To facilitate the recovery of Pb/SiO₂ catalyst, magnetic Pb/Fe₃O₄/SiO₂ samples were prepared separately by emulsification, sol-gel and incipient impregnation methods. The catalyst samples were characterized by means of X-ray diffraction and N₂ adsorption-desorption, and their catalytic activity was investigated in the reaction for synthesizing propylene carbonate from urea and 1,2-propylene glycol. When the gelatin was applied in the preparation of Fe₃O₄ at 60°C and the pH value was controlled at 4 in the preparation of Fe₃O₄/SiO₂, the Pb/Fe₃O₄/SiO₂ sample shows good catalytic activity and magnetism. Under the reaction conditions of a reaction temperature of 180°C, reaction time of 2 h, catalyst percentage of 1.7 wt-% and a molar ratio of urea to PG of 1∶4, the yield of propylene carbonate attained was 87.7%.

Keywords Pb/Fe₃O₄/SiO₂ magnetic particle urea 1 2-propylene glycol propylene carbonate

Corresponding Author(s): ZHAO Xinqiang,Email:zhaoxq@hebut.edu.cn

Issue Date: 05 June 2009

Cite this article:

Hualiang AN,Xinqiang ZHAO,Zhiguang JIA, et al. Synthesis of magnetic Pb/Fe₃O₄/SiO₂ and its catalytic activity for propylene carbonate synthesis via urea and 1,2-propylene glycol[J]. Front Chem Eng Chin, 2009, 3(2): 215-218.

URL:

https://academic.hep.com.cn/fcse/EN/10.1007/s11705-009-0055-2
https://academic.hep.com.cn/fcse/EN/Y2009/V3/I2/215

Fig.1 Synthesis of PC from PG and urea

Fig.2 Catalytic activity of Pb/FeO/SiO catalysts

Tab.1 BET surface areas(), pore volumes() and pore sizes() of catalysts

Fig.3 XRD pattern of Pb/FeO/SiO-3 catalyst

Fig.4 Effect of temperature of gelatin on catalytic performance of Pb/FeO/SiO-4

Tab.2 BET surface areas (), pore volumes () and pore sizes () of catalysts prepared at different using temperature of gelatin

Fig.5 XRD pattern of Pb/FeO/SiO-4 catalyst (the catalyst was prepared with FeO synthesized at 60°C after adding gelatin)

Fig.6 Effect of pH value on catalytic performance of Pb/FeO/SiO-4

Tab.3 BET surface areas (), pore volumes () and pore sizes () of catalysts prepared at different pH value

1	Su W Y. Speranza G P. EP Patent 0443758A1,1991 —02—11
2	Masaharu D, Takashi O, Yutaka K, Atsushi O and Kenlchi K. EP Patent 0581131A2, 1993—7—15
3	Li Q B, Zhang W Y, Zhao N, Wei W, Sun Y H. Synthesis of cyclic carbonate from urea and diols over metal oxides. Catalysis Today , 2006, 115: 111–116 doi: 10.1016/j.cattod.2006.02.033
4	Zhao X Q, Jia Z G, Wang Y J. Clean synthesis of propylene carbonate from urea and 1,2-propylene glycol over zinc-iron double oxide catalyst. Journal of Chemical Technology & Biotechnology , 2006, 81: 794–798 doi: 10.1002/jctb.1412
5	Jia Z G, Zhao X Q, An H L, Wu C C, Wang Y J. Synthesis of propylene carbonate from urea and 1,2-propylene glycol over silica-supported lead catalyst. Petrochemical Technology , 2006, 35: 927–931
6	Lou M Y, Wang D P, Huang W H, Liu B, Jia Q L. Preparation and properties of monodisperse core-shell silica magnetic microspheres. Journal of the Chinese Ceramic Society , 2006, 34: 277–283 (inChinese)

[1]	Jinhua Zhang, Yuanbin She. Mechanism of methanol decomposition on the Pd/WC(0001) surface unveiled by first-principles calculations[J]. Front. Chem. Sci. Eng., 2020, 14(6): 1052-1064.
[2]	Yifei Wang, Shouying Huang, Xinsheng Teng, Hongyu Wang, Jian Wang, Qiao Zhao, Yue Wang, Xinbin Ma. Controllable Fe/HCS catalysts in the Fischer-Tropsch synthesis: Effects of crystallization time[J]. Front. Chem. Sci. Eng., 2020, 14(5): 802-812.
[3]	Chenggang Qiu, Alei Zhang, Sha Tao, Kang Li, Kequan Chen, Pingkai Ouyang. Combination of ARTP mutagenesis and color-mediated high-throughput screening to enhance 1-naphthol yield from microbial oxidation of naphthalene in aqueous system[J]. Front. Chem. Sci. Eng., 2020, 14(5): 793-801.
[4]	Shumei Wei, Yarong Xu, Zhaoyang Jin, Xuedong Zhu. Co-conversion of methanol and n-hexane into aromatics using intergrown ZSM-5/ZSM-11 as a catalyst[J]. Front. Chem. Sci. Eng., 2020, 14(5): 783-792.
[5]	Ye Zhang, Jian Song, Josue Quispe Mayta, Fusheng Pan, Xue Gao, Mei Li, Yimeng Song, Meidi Wang, Xingzhong Cao, Zhongyi Jiang. Enhanced desulfurization performance of hybrid membranes using embedded hierarchical porous SBA-15[J]. Front. Chem. Sci. Eng., 2020, 14(4): 661-672.
[6]	Cyrine Ayed, Wei Huang, Kai A. I. Zhang. Covalent triazine framework with efficient photocatalytic activity in aqueous and solid media[J]. Front. Chem. Sci. Eng., 2020, 14(3): 397-404.
[7]	Siming Chen, Yue Wu, Geoffrey W. Stevens, Guoping Hu, Wenshou Sun, Kathryn A. Mumford. Precipitation study of CO₂-loaded glycinate solution with the introduction of ethanol as an antisolvent[J]. Front. Chem. Sci. Eng., 2020, 14(3): 415-424.
[8]	Mahboube Ghahramaninezhad, Fatemeh Mohajer, Mahdi Niknam Shahrak. Improved CO₂ capture performances of ZIF-90 through sequential reduction and lithiation reactions to form a hard/hard structure[J]. Front. Chem. Sci. Eng., 2020, 14(3): 425-435.
[9]	Tingting Zhao, Niamat Ullah, Yajun Hui, Zhenhua Li. Review of plasma-assisted reactions and potential applications for modification of metal–organic frameworks[J]. Front. Chem. Sci. Eng., 2019, 13(3): 444-457.
[10]	Navid Azizi, Mojgan Isanejad, Toraj Mohammadi, Reza M. Behbahani. Effect of TiO₂ loading on the morphology and CO₂/CH₄ separation performance of PEBAX-based membranes[J]. Front. Chem. Sci. Eng., 2019, 13(3): 517-530.
[11]	Lei Zhang, Lisha Zhao, Ping-Kai Ouyang, Pu Chen. *Insight into the role of cholesterol in modulation of morphology and mechanical properties of CHO-K1 cells: An in situ* AFM study**[J]. Front. Chem. Sci. Eng., 2019, 13(1): 98-107.
[12]	Jiao Feng, Qiuhao Lu, Weimin Tan, Kequan Chen, Pingkai Ouyang. The influence of the NCO/OH ratio and the 1,6-hexanediol/dimethylol propionic acid molar ratio on the properties of waterborne polyurethane dispersions based on 1,5-pentamethylene diisocyanate[J]. Front. Chem. Sci. Eng., 2019, 13(1): 80-89.
[13]	Shewei Hu, Qian Gao, Xin Wang, Jianming Yang, Nana Xu, Kequan Chen, Sheng Xu, Pingkai Ouyang. *Efficient production of D-1,2,4-butanetriol from D-xylose by engineered Escherichia coli* whole-cell biocatalysts**[J]. Front. Chem. Sci. Eng., 2018, 12(4): 772-779.
[14]	Elena Graczová, Branislav Šulgan, Samuel Barabas, Pavol Steltenpohl. Methyl acetate–methanol mixture separation by extractive distillation: Economic aspects[J]. Front. Chem. Sci. Eng., 2018, 12(4): 670-682.
[15]	Yaodong Huang, Shuxue Liu, Zhuofeng Xie, Zipei Sun, Wei Chai, Wei Jiang. Novel 1,2,3-triazole-based compounds: Iodo effect on their gelation behavior and cation response[J]. Front. Chem. Sci. Eng., 2018, 12(2): 252-261.

Viewed

Full text

Abstract

Cited

Shared

Discussed