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Effects of environmental factors on the production and release of matrix-bound phosphine from lake sediments |
GENG Jinju1, WANG Qiang1, WANG Xiaorong1, NIU Xiaojun2 |
1.State Key Laboratory of Pollution Control and Resource Reuse, School of Environment, Nanjing University, Nanjing 210093, China; 2.South China University of Technology, School of Environmental Science and Engineering, Guangzhou 510641, China; |
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Abstract Effects of pH, temperature, and oxygen on the production and release of phosphine in eutrophic lake sediments were investigated under laboratory tests. Results indicated that the elimination of matrix-bound phosphine was accelerated under initial pH 1 or 12. Phosphine levels could reach maximum under initial pH 10. The contents of phosphine increased with the addition of alkali under pH 4 12. The rates of phosphine production and release from lake sediments varied with temperature. 20?C was the most favorable temperature for the production of matrix-bound phosphine. Oxygen showed little effect on matrix-bound phosphine. Matrix-bound phosphine concentrations in lake sediments were concluded to be dependent on a balance of natural generation and depletion processes.
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Issue Date: 05 March 2007
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