Please wait a minute...
Frontiers of Environmental Science & Engineering

ISSN 2095-2201

ISSN 2095-221X(Online)

CN 10-1013/X

Postal Subscription Code 80-973

2018 Impact Factor: 3.883

Front.Environ.Sci.Eng.    2008, Vol. 2 Issue (1) : 44-50    https://doi.org/10.1007/s11783-008-0012-1
Experimental study on oxidative decomposition of nitrobenzene in aqueous solution by honeycomb ceramic-catalyzed ozonation
ZHAO Lei1, MA Jun1, LIU Zhengqian1, YANG Yixin1, SUN Zhizhong2
1.School of Municipal and Environmental Engineering, Harbin Institute of Technology; 2.School of Chemistry and Materials Science, Heilongjiang University;
 Download: PDF(362 KB)   HTML
 Export: BibTeX | EndNote | Reference Manager | ProCite | RefWorks
Abstract The ozonation of nitrobenzene in aqueous solution was carried out in a semi-batch reactor to investigate the degradation efficiency, the effect factors, and the reaction mechanism, where honeycomb ceramic was used as a catalyst. The presence of honeycomb ceramic could improve the degradation rate of nitrobenzene by 15.46% compared to the results of ozonation alone. Under the conditions of this experiment, the degradation rate of honeycomb ceramic-catalyzed ozonation increased by 12.94% with the increase of the amount of catalyst from 1 to 5 blocks. The degradation rates all increased greatly with the increase of temperature and pH of the solution in the processes of honeycomb ceramic-catalyzed ozonation and ozonation alone. But, when the pH of the solution increased to 9.50, the advantage of the honeycomb ceramic-catalyzed ozonation process would be lost. The experimental findings indicated that in the processes of ozonation alone and honeycomb ceramic-catalyzed ozonation, nitrobenzene was primarily oxidized by OH free radical in aqueous solution. The adsorption of nitrobenzene was too limited to have an important influence on the degradation rate of nitrobenzene. With the same total dosage of applied ozone, the multiple step addition of ozone showed much higher removal efficiency than that obtained by one step in the two processes.
Issue Date: 05 March 2008
 Cite this article:   
MA Jun,ZHAO Lei,SUN Zhizhong, et al. Experimental study on oxidative decomposition of nitrobenzene in aqueous solution by honeycomb ceramic-catalyzed ozonation[J]. Front.Environ.Sci.Eng., 2008, 2(1): 44-50.
 URL:  
https://academic.hep.com.cn/fese/EN/10.1007/s11783-008-0012-1
https://academic.hep.com.cn/fese/EN/Y2008/V2/I1/44
1 Kasprzyk-Hordern B Ziólek M Nawrocki J Catalytic ozonation and methods of enhancing molecularozone reactions in water treatmentAppliedCatalysis B: Environmental 2003 46639669.
doi:10.1016/S0926‐3373(03)00326‐6
2 Legube B Karpel V L N Catalytic ozonation: A promisingadvanced oxidation technology for water treatmentCatalysis Today 1999 536172.
doi:10.1016/S0920‐5861(99)00103‐0
3 Ma J Graham N J D Degradation of atrazine bymanganese-catalyzed ozonation: Influence of humic substancesWater Res 1999 33(3)785793.
doi:10.1016/S0043‐1354(98)00266‐8
4 Andreozzi R Insola A Caprio V Amore M G D The kineticsof Mn(II)-catalyzed ozonation of oxalic acid in aqueous solutionWater Res 1992 26(7)917921.
doi:10.1016/0043‐1354(92)90197‐C
5 Kasprzyk-Hordern B Andrzejewski P Dabrowska A Czaczyk K Nawrocki J MTBE, DIPE, ETBE and TAME degradation inwater using perfluorinated phases as catalysts for ozonation processApplied Catalysis B: Environmental 2004 51(1)5166.
doi:10.1016/j.apcatb.2004.02.004
6 Huang W J Fang G C Wang C C A nanometer-ZnO catalyst to enhance the ozonation of 2,4,6-trichlorophenolin waterColloids and Surfaces A: PhysicochemEng Aspects 2005 2604551.
doi:10.1016/j.colsurfa.2005.01.031
7 Beltrán F J Rivas F J Ramón M E A TiO2/Al2O3 catalyst to improve the ozonation of oxalicacid in waterApplied Catalysis B: Environmental 2004 47101109.
doi:10.1016/j.apcatb.2003.07.007
8 Li G Zhao X S Ray M B Advanced oxidation of orange II using TiO2 supported on porous adsorbents: The role of pH, H2O2 and O3Separation and Purification Technology 2007 559197.
doi:10.1016/j.seppur.2006.11.003
9 Zhou Y R Zhu W P Liu F D Wang J B Yang S X Catalytic activity of Ru/Al2O3 for ozonation of dimethyl phthalate inaqueous solutionChemosphere 2007 66145150.
doi:10.1016/j.chemosphere.2006.06.004
10 Jorge V Patricio R Gina P Catalytic and photocatalytic ozonation of phenol on MnO2 supported catalystsCatalysisToday 2002 76121131.
doi:10.1016/S0920‐5861(02)00212‐2
11 Ma J Graham N J D Preliminary investigation ofmanganese-catalyzed for the destruction of atrazineOzone Sci Eng 1997 19227233
12 Cooper C Burch R An investigation of catalyticozonation for the oxidation of halocarbons in drinking water preparationWater Res 1999 23(18)3,6953,700
13 Andreozzi R Marotta R Sanchirico R Manganese-catalyzed ozonation of glyoxalic acid in aqueoussolutionsJournal of Chemical Technologyand Biotechnology 2000 755965.
doi:10.1002/(SICI)1097‐4660(200001)75:1<59::AID‐JCTB175>3.0.CO;2‐X
14 David S David P Reckhow A Effect of dissolved Cobalt (II) on the ozonation of oxalicacidEnviron Sci Technol 2002 364,0464,051
15 Dong Y M He K Zhao B Yin Y Yin L Zhang A M Catalytic ozonationof azo dye active brilliant red X-3B in water with natural mineralbruciteCatalysis Communications 2007 81,5991,603
16 Ma J Graham N J D Degradation of atrazine bymanganese-catalysed ozonation: Influence of radical scavengersWater Res 2000 34(15)3,8223,828.
doi:10.1016/S0043‐1354(00)00130‐5
17 Beltrán F J Rivas F J Ramón M E Catalytic ozonation of oxalic acid in an aqueous TiO2 slurry reactorApplied CatalysisB: Environmental 2002 39221231.
doi:10.1016/S0926‐3373(02)00102‐9
18 Mathias E Franck L Schrotter J C Catalytic ozonation of refractory organic model compoundsin aqueous solution by aluminum oxideAppliedCatalysis B: Environmental 2004 471525.
doi:10.1016/S0926‐3373(03)00290‐X
19 Carbajo M Beltrán F J Medina F Crimeno O Rivas F J Catalytic ozonation of phenolic compounds:The case of gallic acidApplied CatalysisB: Environmental 2006 67177186.
doi:10.1016/j.apcatb.2006.04.019
20 Ebru C C Fikret K Color, TOC and AOX removalsfrom pulp mill effluent by advanced oxidation processes: A comparativestudyJournal of Hazardous Materials’B 2007 139244253.
doi:10.1016/j.jhazmat.2006.06.023
21 Bader H Hoigné J Determination of ozone in waterby the indigo methodWater Res 1981 15449456.
doi:10.1016/0043‐1354(81)90054‐3
22 Hoigne J Bader H Rate constants of reactionsof ozone with organic and inorganic compounds in water-I: Non-dissociatingorganic compoundsWater Res 1983 17(2)173183.
doi:10.1016/0043‐1354(83)90098‐2
23 Hoigne J Bader H The role of hydroxyl radicalreactions in ozonation process in aqueous solutionsWater Res 1976 10377386.
doi:10.1016/0043‐1354(76)90055‐5
24 Gracia R Cortes S Sarasa J Ormad P Ovelleiro J L TiO2-catalysed ozonation of raw river waterWater Res 2000 34(5)1,5251,532.
doi:10.1016/S0043‐1354(99)00297‐3
25 Langlais B Reckhow D A Brink D R Ozone in Water Treatment: Application and EngineeringChelsea, USALewis Publishers 1991 1819
26 Park J S Choi H Cho J Kinetic decomposition of ozone and parachlorobenzoic acid(pCBA) during catalytic ozonationWater Res 2004 382,2842,291
27 Zhang S J Feng S H Yu H Q Li Q R Degradationof nitrobenzene in wastewater by γ-ray irradiationJournal of EnvironmentalSciences 2004 16(3)364366
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed