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Investigation of the effects of humic acid and
H 2 O 2 on the photocatalytic
degradation of atrazine assisted by microwave |
Chao QIN1,Shaogui YANG1,Cheng SUN1,Jia ZHOU1,Manjun ZHAN2,Rongjun WANG3,Huanxing CAI3, |
1.State Key Laboratory
of Pollution Control and Resource Reuse, School of the Environment,
Nanjing University, Nanjing 210093, China; 2.Nanjing Research Institude
of Environmental Protection, Nanjing 210013, China; 3.Changzhou Environmental
Monitoring Center, Changzhou 210093, China; |
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Abstract A solution of atrazine in a TiO2 suspension, an endocrine disruptor in natural water, was tentatively treated by microwave-assisted photocatalytic technique. The effects of mannitol, oxygen, humic acid, and hydrogen dioxide on the photodegradation rate were explored. The results could be deduced as follows: the photocatalytic degradation of atrazine fits the pseudo-first-order kinetic well with k = 0.0328 s−1, and ·OH was identified as the dominant reactant. Photodegradation of atrazine was hindered in the presence of humic acid, and the retardation effect increased as the concentration of humic acid increased. H2O2 displayed a significant negative influence on atrazine photocatalysis efficiency. Based on intermediates identified with gas chromatography-mass spectrometry (GC-MS) and Liquid chromatography-mass spectrometry (LC-MS/MS) techniques, the main degradation routes of atrazine are proposed.
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Keywords
atrazine
retardation effect
photocatalysis
TiO2
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Issue Date: 05 September 2010
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USEPA. National Pesticide Survey Factsheet, CLARIT 570990―NPS10. United States Environmental Protection Agency: Washington, DC, 1990
|
|
Graziano N, McGuire M J, Roberson A, Adams C, Jiang H, Blute N. 2004 National atrazine occurrence monitoringprogram using the abraxis elisa method. Environmental Science & Technology, 2006, 40(4): 1163―1171
doi: 10.1021/es051586y
|
|
Cooper R L, Stoker T E, Tyrey L, Goldman J M, McElroy W K. Atrazine disrupts the hypothalamic control of pituitary-ovarian function. Toxicological Sciences, 2000, 53(2): 297―307
doi: 10.1093/toxsci/53.2.297
|
|
USEPA. Consumer Factsheet on: ATRAZINE. UnitedStates Environmental Protection Agency: Washington, DC,2005
|
|
Banerjee K, Cheremisinoff P N, Cheng S L. Sorption of organic contaminantsby fly ash in a single solute system. EnvironmentalScience & Technology, 1995, 29(9): 2243―2251
doi: 10.1021/es00009a014
|
|
Mascolo G, Lopez A, Foldenyi R, Passino R, TiravantiG. Prometryne oxidation by sodium hypochlorite in aqueous solution:kinetics and mechanism. Environmental Science& Technology, 1995, 29(12): 2987―2991
doi: 10.1021/es00012a015
|
|
Yang H, Lin W Y, Rajeshwar K. Homogeneous and heterogeneous photocatalyticreactions involving As(III) and As(V) species in aqueous media. Journal of Photochemistry and Photobiology A Chemistry, 1999, 123(1―3): 137―143
doi: 10.1016/S1010-6030(99)00052-0
|
|
Moraes J E F, Quina F H, Nascimento C A O, Silva D N, Chiavone-Filho O. Treatmentof saline wastewater contaminated with hydrocarbons by the photo-Fentonprocess. Environmental Science & Technology, 2004, 38(4): 1183―1187
doi: 10.1021/es034217f
|
|
Skoumal M, Cabot P L, Centellas F, Arias C, Rodriguez R M, Garrido J A, Brillas E. Mineralizationof paracetamol by ozonation catalyzed with Fe2+, Cu2+ and UVA light. Applied Catalysis B: Environmental, 2006, 66(3―4): 228―240
doi: 10.1016/j.apcatb.2006.03.016
|
|
Zalazar C S, Satuf M L, Alfano O M, Cassano A E. Comparison of H2O2/UVand heterogeneous photocatalytic processes for the degradation ofdichloroacetic acid in water. EnvironmentalScience & Technology, 2008, 42(16): 6198―6204
doi: 10.1021/es800028h
|
|
Horikoshi S, Hidaka H, Serpone N. Environmental remediationby an integrated microwave/UV illumination technique: VI. A simplemodified domestic microwave oven integrating an electrodeless UV-Vislamp to photodegrade environmental pollutants in aqueous media. Journal of Photochemistry and Photobiology A Chemistry, 2004, 161(2―3): 221―225
|
|
Yang S G, Fu H B, Sun C, Gao Z Q. Rapid photocatalytic destruction of pentachlorophenol in F-Si-comodifiedTiO2 suspensions under microwave irradiation. Journal of Hazardous Materials, 2009, 161(2―3): 1281―1287
|
|
Ju Y M, Yang S G, Ding Y C, Sun C, Zhang A Q, Wang L. Microwave-Assisted Rapid Photocatalytic Degradation ofMalachite Green in TiO2 Suspensions: Mechanismand Pathways. Journal of Physical ChemistryA, 2008, 112(44): 11172―11177
doi: 10.1021/jp804439z
|
|
Zhanqi G, Shaogui Y, Na T, Cheng S. Microwave assisted rapid and complete degradation ofatrazine using TiO2 nanotube photocatalystsuspensions. Journal of Hazardous Materials, 2007, 145(3): 424―430
doi: 10.1016/j.jhazmat.2006.11.042
|
|
Lin C, Lin K S. Photocatalyticoxidation of toxic organohalides with TiO2/UV:the effects of humic substances and organic mixtures. Chemosphere, 2007, 66(10): 1872―1877
|
|
Lee H, Choi W. Photocatalyticoxidation of arsenite in TiO2 suspension: kineticsand mechanisms. Environmental Science &Technology, 2002, 36(17): 3872―3878
doi: 10.1021/es0158197
|
|
Ta N, Hong J, Liu T, Sun C. Degradationof atrazine by microwave-assisted electrodeless discharge mercurylamp in aqueous solution. Journal of HazardousMaterials, 2006, 138(1): 187―194
doi: 10.1016/j.jhazmat.2006.05.050
|
|
Konstantinou I K, Sakellarides T M, Sakkas V A, Albanis T A. Photocatalytic degradation of selected s-triazine herbicidesand organophosphorus insecticides over aqueous TiO2 suspensions. Environmental Science &Technology, 2001, 35(2): 398―405
doi: 10.1021/es001271c
|
|
Lackhoff M, Niessner R. Photocatalyticatrazine degradation by synthetic minerals, atmospheric aerosols,and soil particles. Environmental Science& Technology, 2002, 36(24): 5342―5347
doi: 10.1021/es025590a
|
|
Cao Y, Yi L, Huang L, Hou Y, Lu Y. Mechanism and pathways ofchlorfenapyr photocatalytic degradation in aqueous suspension of TiO2. Environmental Science &Technology, 2006, 40(10): 3373―3377
doi: 10.1021/es052073u
|
|
Garbin J R, Milori D M B P, Sim?es M L, da Silva W T L, Neto L M. Influenceof humic substances on the photolysis of aqueous pesticide residues. Chemosphere, 2007, 66(9): 1692―1698
|
|
Chu W, Choy W K. The mechanismsof rate enhancing and quenching of trichloroethene photodecay in thepresence of sensitizer and hydrogen sources. Water Research, 2002, 36(10): 2525―2532
doi: 10.1016/S0043-1354(01)00471-7
|
|
Ilisz I, Dombi A. The photochemicalbehavior of hydrogen peroxide in near UV-irradiated aqueous TiO2 suspensions. Journal ofMolecular Catalysis A Chemical, 1998, 135(1): 55―61
doi: 10.1016/S1381-1169(97)00296-3
|
|
Dionysiou D D, Suidan M T, Bekou E, Baudin I, Laine J M. Effect ofionic strength and hydrogen peroxide on the photocatalytic degradationof 4-chlorobenzoic acid in water. AppliedCatalysis B: Environmental, 2000, 26(3): 153―171
doi: 10.1016/S0926-3373(00)00124-7
|
|
Chemseddine A. A study of the primary step in the photochemical degradationof acetic-acid and chloroacetic acids on a TiO2 photocatalyst. Journal of Molecular Catalysis, 1990, 60(3): 295―311
doi: 10.1016/0304-5102(90)85253-E
|
|
Pelizzetti E. Enhancement of the rate of photocatalytic degradationon TiO2 of 2-chlorophenol, 2,7-dichlorodibenzodioxinand atrazine by inorganic oxidizing species. New Journal of Chemistry, 1991, 15(5): 351―359
|
|
Granados-Oliveros G, Paez-Mozo E A, Ortega F M, Ferronato C, Chovelon J M. Degradation of atrazine using metalloporphyrins supported on TiO2 under visible light irradiation. Applied Catalysis B: Environmental, 2009, 89(3―4): 448―454
|
|
Héquet V, Gonzalez C, Le Cloirec P. Photochemical processes foratrazine degradation: methodological approach. Water Research, 2001, 35(18): 4253―4260
doi: 10.1016/S0043-1354(01)00166-X
|
|
Pelizzetti E, Maurino V, Minero C, Carlin V, Tosato M L, Pramauro E, Zerbinati O. Photocatalytic degradation of atrazine and other striazineherbicides. Environmental Science &Technology, 1990, 24(10): 1559―1565
|
|
Canelli E. Chemical, bacteriological, and toxicological propertiesof cyanuric acid and chlorinated isocyanurates as applied to swimmingpool disinfection: a review. American Journalof Public Health, 1974, 64(2): 155―162
doi: 10.2105/AJPH.64.2.155
|
|
Hiskia A, Ecke M, Troupis A, Kokorakis A, Hennig H, Papaconstantinou E. Sonolytic, photolytic, and photocatalyticdecomposition of atrazine in the presence of polyoxometalates. Environmental Science & Technology, 2001, 35(11): 2358―2364
doi: 10.1021/es000212w
|
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