Spent rechargeable lithium batteries in e-waste: composition and its implications

doi:10.1007/s11783-014-0705-6

Front.Environ.Sci.Eng.

2014, Vol. 8

Issue (5) : 792-796 https://doi.org/10.1007/s11783-014-0705-6

SHORT COMMUNICATION

Spent rechargeable lithium batteries in e-waste: composition and its implications

Xianlai ZENG,Jinhui LI(

)

State Key Joint Laboratory of Environment Simulation and Pollution Control, School of Environment, Tsinghua University, Beijing 100084, China

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Abstract

The amount of spent rechargeable lithium batteries (RLBs) is growing rapidly owing to wide application of these batteries in portable electronic devices and electric vehicles, which obliges that spent RLBs should be handled properly. Identification of spent RLBs can supply fundamental information for spent RLBs recycling. This study aimed to determine the differences of physical components and chemical compositions among various spent RLBs. All the samplings of RLBs were rigorously dismantled and measured by an inductive coupled plasma atomic emission spectrometer. The results indicate that the average of total weight of the separator, the anode and the cathode accounted for over 60% of all the RLBs. The weight ratio of valuable metals ranged from 26% to 76%, and approximately 20% of total weight was Cu and Al. Moreover, no significant differences were found among different manufacturers, applications, and electrolyte types. And regarding portable electronic devices, there is also no significant difference in the Co-Li concentration ratios in the leaching liquid of RLBs.

Keywords rechargeable lithium batteries e-waste physical components difference analysis recycling

Corresponding Author(s): Jinhui LI

Issue Date: 20 June 2014

Cite this article:

Xianlai ZENG,Jinhui LI. Spent rechargeable lithium batteries in e-waste: composition and its implications[J]. Front.Environ.Sci.Eng., 2014, 8(5): 792-796.

URL:

https://academic.hep.com.cn/fese/EN/10.1007/s11783-014-0705-6
https://academic.hep.com.cn/fese/EN/Y2014/V8/I5/792

Fig.1 (a) Average component ratio of various RLBs (wt. %); (b) Metal contents and their total errors of various spent RLBs

Fig.2 Clustering analysis of the Co-Li concentration ratio in various spent RLBs

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