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Degradation of antipyrine in the Fenton-like process with a La-doped heterogeneous catalyst |
Shicheng Wei, Cuiping Zeng, Yaobin Lu(), Guangli Liu, Haiping Luo, Renduo Zhang |
Guangdong Provincial Key Laboratory of Environmental Pollution Control and Remediation Technology, School of Environmental Science and Engineering, Sun Yat-sen University, Guangzhou 510006, China |
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Abstract A La-doped Co-Cu-Fe catalyst was synthesized for the antipyrine (ANT) removal. The La-doped catalyst had higher ANT removal than the control (95% vs. 54%). La reduced the particle size and increased the specific surface area of catalyst. The aim of this study was to synthesize a novel lanthanum (La) doped catalyst and to investigate antipyrine removal in wastewater using the Fenton-like process with the catalyst. The La-doped Co-Cu-Fe catalyst was synthesized using the modified hydrothermal method. Results showed that the La-doped catalyst had higher specific surface area and lower particle size than the catalyst without La doping (i.e., the control) (267 vs. 163 m2/g and 14 vs. 32 nm, respectively). Under the conditions of catalyst dosage 0.5 g/L, H2O2 concentration 1.70 g/L, and NaHCO3 0.1 g/L, the antipyrine removal within 60 min using the Fenton-like process with the La-doped catalyst was much higher than that with the control (95% vs. 54%). The hydroxyl radical concentration with the La-doped catalyst within 60 min was two times higher than that with the control (49.2 vs. 22.1 mg/L). The high catalytic activity of La-doped catalyst was mainly attributed to its high specific surface area based on the X-ray photoelectron spectroscopy result. Our La-doped catalyst should have great potential to remove antipyrine in wastewater using the heterogeneous Fenton-like process.
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Keywords
Antipyrine
Lanthanum
Catalyst
Fenton-like process
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Corresponding Author(s):
Yaobin Lu
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Online First Date: 10 July 2019
Issue Date: 10 July 2019
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|
1 |
A D Bokare, W Choi (2014). Review of iron-free Fenton-like systems for activating H2O2 in advanced oxidation processes. Journal of Hazardous Materials, 275: 121–135
https://doi.org/10.1016/j.jhazmat.2014.04.054
pmid: 24857896
|
2 |
M Q Cai, L Feng, J Jiang, F Qi, L Q Zhang (2013). Reaction kinetics and transformation of antipyrine chlorination with free chlorine. Water Research, 47(8): 2830–2842
https://doi.org/10.1016/j.watres.2013.02.047
pmid: 23521978
|
3 |
Y Ding, H Tang, S Zhang, S Wang, H Tang (2016). Efficient degradation of carbamazepine by easily recyclable microscaled CuFeO2 mediated heterogeneous activation of peroxymonosulfate. Journal of Hazardous Materials, 317: 686–694
https://doi.org/10.1016/j.jhazmat.2016.06.004
pmid: 27329789
|
4 |
T Divya, N K Renuka (2015). Modulated heterogeneous Fenton-like activity of ‘M’ doped nanoceria systems (M=Cu, Fe, Zr, Dy, La): Influence of reduction potential of doped cations. Journal of Molecular Catalysis A Chemical, 408: 41–47
https://doi.org/10.1016/j.molcata.2015.07.018
|
5 |
E N Evgenidou, I K Konstantinou, D A Lambropoulou (2015). Occurrence and removal of transformation products of PPCPs and illicit drugs in wastewaters: A review. Science of the Total Environment, 505: 905–926
https://doi.org/10.1016/j.scitotenv.2014.10.021
pmid: 25461093
|
6 |
R Fareghi-Alamdari, M Golestanzadeh, N Zekri (2014). Application of nanosized Cu0.5Co0.5Fe2O4 spinel ferrite as a nanocatalyst in the synthesis of 14-aryl-14h-dibenzo[a,j] xanthene derivatives under solvent-free conditions. Journal of the Chinese Chemical Society, 61(12): 1341–1350 (in Chinese)
https://doi.org/10.1002/jccs.201400148
|
7 |
H Fida, G Zhang, S Guo, A Naeem (2017). Heterogeneous Fenton degradation of organic dyes in batch and fixed bed using La-Fe montmorillonite as catalyst. Journal of Colloid and Interface Science, 490: 859–868
https://doi.org/10.1016/j.jcis.2016.11.085
pmid: 28002774
|
8 |
A Fischbacher, C von Sonntag, T C Schmidt (2017). Hydroxyl radical yields in the Fenton process under various pH, ligand concentrations and hydrogen peroxide/Fe(II) ratios. Chemosphere, 182: 738–744
https://doi.org/10.1016/j.chemosphere.2017.05.039
pmid: 28531840
|
9 |
L B Fraigi, D G Lamas, N E Walsöe De Reca (2001). Comparison between two combustion routes for the synthesis of nanocrystalline SnO2 powders. Materials Letters, 47(4–5): 262–266
https://doi.org/10.1016/S0167-577X(00)00246-9
|
10 |
H Gong, W Chu, M Chen, Q Wang (2017). A systematic study on photocatalysis of antipyrine: Catalyst characterization, parameter optimization, reaction mechanism a toxicity evolution to plankton. Water Research, 112: 167–175
https://doi.org/10.1016/j.watres.2017.01.041
pmid: 28160696
|
11 |
I Gultekin, N H Ince (2004). Degradation of reactive azo dyes by UV/H2O2: Impact of radical scavengers. Journal of Environmental Science and Health, Part A, 39(4): 1069–1081
|
12 |
J Jiang, G Li, Z Li, X Zhang, F Zhang (2016). An Fe–Mn binary oxide (FMBO) modified electrode for effective electrochemical advanced oxidation at neutral pH. Electrochimica Acta, 194: 104–109
https://doi.org/10.1016/j.electacta.2016.02.075
|
13 |
Y Lei, C S Chen, Y J Tu, Y H Huang, H Zhang (2015). Heterogeneous degradation of organic pollutants by persulfate activated by CuO-Fe3O4: Mechanism, stability, and effects of pH and bicarbonate ions. Environmental Science & Technology, 49(11): 6838–6845
https://doi.org/10.1021/acs.est.5b00623
pmid: 25955238
|
14 |
F Li, T Lei, Y Zhang, J Wei, Y Yang (2015). Preparation, characterization of sludge adsorbent and investigations on its removal of hydrogen sulfide under room temperature. Frontiers of Environmental Science & Engineering, 9(2): 190–196
https://doi.org/10.1007/s11783-014-0628-2
|
15 |
W Li, H Liu, Y Chen (2017). Promotion of transition metal oxides on the NH3-SCR performance of ZrO2-CeO2 catalyst. Frontiers of Environmental Science & Engineering, 11(2): 6
https://doi.org/10.1007/s11783-017-0914-x
|
16 |
L Lyu, L Zhang, C Hu (2015). Enhanced Fenton-like degradation of pharmaceuticals over framework copper species in copper-doped mesoporous silica microspheres. Chemical Engineering Journal, 274: 298–306
https://doi.org/10.1016/j.cej.2015.03.137
|
17 |
J Ma, N J D Graham (2000). Degradation of atrazine by manganese-catalysed ozonation—influence of radical scavengers. Water Research, 34(15): 3822–3828
https://doi.org/10.1016/S0043-1354(00)00130-5
|
18 |
J M Monteagudo, A Durán, J Latorre, A J Expósito (2016). Application of activated persulfate for removal of intermediates from antipyrine wastewater degradation refractory towards hydroxyl radical. Journal of Hazardous Materials, 306: 77–86
https://doi.org/10.1016/j.jhazmat.2015.12.001
pmid: 26698672
|
19 |
M Munoz, Z M De Pedro, J A Casas, J J Rodriguez (2015). Preparation of magnetite-based catalysts and their application in heterogeneous Fenton oxidation: A review. Applied Catalysis B: Environmental, 176–177: 249–265
https://doi.org/10.1016/j.apcatb.2015.04.003
|
20 |
H Na, T Zhu, Z Liu, Y Sun (2014). Promoting effect of Zr on the catalytic combustion of methane over Pd/g-Al2O3 catalyst. Frontiers of Environmental Science & Engineering, 8(5): 659–665
https://doi.org/10.1007/s11783-013-0613-1
|
21 |
X Ou, J Yan, F Zhang, C Zhang (2018). Accelerated degradation of orange G over a wide pH range in the presence of FeVO4. Frontiers of Environmental Science & Engineering, 12(1): 7
https://doi.org/10.1007/s11783-018-1013-3
|
22 |
C M Park, J Heo, Y Yoon (2017). Oxidative degradation of bisphenol A and 17α-ethinyl estradiol by Fenton-like activity of silver nanoparticles in aqueous solution. Chemosphere, 168: 617–622
https://doi.org/10.1016/j.chemosphere.2016.11.016
pmid: 27838031
|
23 |
S R Patil, L Kumar, G Kohli, A K Bansal (2012). Validated HPLC method for concurrent determination of antipyrine, carbamazepine, furosemide and phenytoin and its application in assessment of drug permeability through Caco-2 cell monolayers. Scientia Pharmaceutica, 80(1): 89–100
https://doi.org/10.3797/scipharm.1109-03
pmid: 22396906
|
24 |
K Rajasekhar Babu, K R Rao, B Rajesh Babu (2017). Cu2+-modified physical properties of cobalt-nickel ferrite. Journal of Magnetism and Magnetic Materials, 434: 118–125
https://doi.org/10.1016/j.jmmm.2017.03.044
|
25 |
Y Rao, Y Zhang, F Han, H Guo, Y Huang, R Li, F Qi, J Ma (2018). Heterogeneous activation of peroxymonosulfate by LaFeO3 for diclofenac degradation: DFT-assisted mechanistic study and degradation pathways. Chemical Engineering Journal, 352: 601–611
https://doi.org/10.1016/j.cej.2018.07.062
|
26 |
M M Rashad, D A Rayan, A O Turky, M M Hessien (2015). Effect of Co2+ and Y3+ ions insertion on the microstructure development and magnetic properties of Ni0.5Zn0.5Fe2O4 powders synthesized using co-precipitation method. Journal of Magnetism and Magnetic Materials, 374: 359–366
https://doi.org/10.1016/j.jmmm.2014.08.031
|
27 |
K Reddersen, T Heberer, U Dünnbier (2002). Identification and significance of phenazone drugs and their metabolites in ground- and drinking water. Chemosphere, 49(6): 539–544
https://doi.org/10.1016/S0045-6535(02)00387-9
pmid: 12430641
|
28 |
A Samavati, M K Mustafa, A F Ismail, M H D Othman, M A Rahman (2016). Copper-substituted cobalt ferrite nanoparticles: Structural, optical and antibacterial properties. Materials Express, 6(6): 473–482
https://doi.org/10.1166/mex.2016.1338
|
29 |
R Sharma, S Bansal, S Singhal (2016). Augmenting the catalytic activity of CoFe2O4 by substituting rare earth cations into the spinel structure. RSC Advances, 6(75): 71676–71691
https://doi.org/10.1039/C6RA14325C
|
30 |
C Su, W Li, X Liu, X Huang, X Yu (2016). Fe-Mn-sepiolite as an effective heterogeneous Fenton-like catalyst for the decolorization of reactive brilliant blue. Frontiers of Environmental Science & Engineering, 10(1): 37–45
https://doi.org/10.1007/s11783-014-0729-y
|
31 |
C Tai, J F Peng, J F Liu, G B Jiang, H Zou (2004). Determination of hydroxyl radicals in advanced oxidation processes with dimethyl sulfoxide trapping and liquid chromatography. Analytica Chimica Acta, 527(1): 73–80
https://doi.org/10.1016/j.aca.2004.08.019
|
32 |
C Tan, N Gao, Y Deng, W Rong, S Zhou, N Lu (2013). Degradation of antipyrine by heat activated persulfate. Separation and Purification Technology, 109: 122–128
https://doi.org/10.1016/j.seppur.2013.03.003
|
33 |
C Tan, N Gao, D Fu, J Deng, L Deng (2017). Efficient degradation of paracetamol with nanoscaled magnetic CoFe2O4 and MnFe2O4 as a heterogeneous catalyst of peroxymonosulfate. Separation and Purification Technology, 175: 47–57
https://doi.org/10.1016/j.seppur.2016.11.016
|
34 |
J Wang, S Wang (2016). Removal of pharmaceuticals and personal care products (PPCPs) from wastewater: A review. Journal of Environmental Management, 182: 620–640
https://doi.org/10.1016/j.jenvman.2016.07.049
pmid: 27552641
|
35 |
J Wei, X Zhang, Q Liu, Z Li, L Liu, J Wang (2014). Magnetic separation of uranium by CoFe2O4 hollow spheres. Chemical Engineering Journal, 241: 228–234
https://doi.org/10.1016/j.cej.2013.12.035
|
36 |
C Wu, K G Linden (2010). Phototransformation of selected organophosphorus pesticides: Roles of hydroxyl and carbonate radicals. Water Research, 44(12): 3585–3594
https://doi.org/10.1016/j.watres.2010.04.011
pmid: 20537677
|
37 |
Y Yao, H Chen, C Lian, F Wei, D Zhang, G Wu, B Chen, S Wang (2016a). Fe, Co, Ni nanocrystals encapsulated in nitrogen-doped carbon nanotubes as Fenton-like catalysts for organic pollutant removal. Journal of Hazardous Materials, 314: 129–139
https://doi.org/10.1016/j.jhazmat.2016.03.089
pmid: 27111426
|
38 |
Y Yao, H Chen, J Qin, G Wu, C Lian, J Zhang, S Wang (2016b). Iron encapsulated in boron and nitrogen codoped carbon nanotubes as synergistic catalysts for Fenton-like reaction. Water Research, 101: 281–291
https://doi.org/10.1016/j.watres.2016.05.065
pmid: 27267476
|
39 |
H Zhang, S Chen, H Zhang, X Fan, C Gao, H Yu, X Quan (2019). Carbon nanotubes-incorporated MIL-88B-Fe as highly efficient Fenton-like catalyst for degradation of organic pollutants. Frontiers of Environmental Science & Engineering, 13(2): 18
https://doi.org/10.1007/s11783-019-1101-z
|
40 |
M Zhang, J Lu, Y He, P C Wilson (2016). Photocatalytic degradation of polybrominated diphenyl ethers in pure water system. Frontiers of Environmental Science & Engineering, 10(2): 229–235
https://doi.org/10.1007/s11783-014-0762-x
|
41 |
T Zhang, J Li, H He, Q Song, Q Liang (2017). NO oxidation over Co-La catalysts and NOx reduction in compact SCR. Frontiers of Environmental Science & Engineering, 11(2): 4
https://doi.org/10.1007/s11783-017-0906-x
|
42 |
X Zhang, Y Ding, H Tang, X Han, L Zhu, N Wang (2014). Degradation of bisphenol A by hydrogen peroxide activated with CuFeO2 microparticles as a heterogeneous Fenton-like catalyst: Efficiency, stability and mechanism. Chemical Engineering Journal, 236: 251–262
https://doi.org/10.1016/j.cej.2013.09.051
|
43 |
L Zhou, W Song, Z Chen, G Yin (2013). Degradation of organic pollutants in wastewater by bicarbonate-activated hydrogen peroxide with a supported cobalt catalyst. Environmental Science & Technology, 47(8): 3833–3839
https://doi.org/10.1021/es400101f
pmid: 23495717
|
44 |
S Zuehlke, U Duennbier, B Lesjean, R Gnirss, H Buisson (2006). Long-term comparison of trace organics removal performances between conventional and membrane activated sludge processes. Water Environment Research, 78(13): 2480–2486
https://doi.org/10.2175/106143006X111826
pmid: 17243248
|
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