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Bioreduction of nitrate in groundwater using
a pilot-scale hydrogen-based membrane biofilm reactor |
Youneng TANG1,Michal ZIV-EL1,Chen ZHOU1,Jung Hun SHIN1,Chang Hoon AHN1,Bruce E. RITTMANN1,Kerry MEYER2,Daniel CANDELARIA2,David FRIESE3,Ryan OVERSTREET3,Rick SCOTT4, |
1.Center for Environmental
Biotechnology, Biodesign Institute at Arizona State University, Tempe,
AZ 85287, USA; 2.CH2M Hill, Englewood,
CO 80112, USA; 3.Applied Process Technology,
Inc., Pleasant Hill, CA 94523, USA; 4.City of Glendale, Glendale,
AZ 85303, USA; |
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Abstract A long-term pilot-scale H2-based membrane biofilm reactor (MBfR) was tested for removal of nitrate from actual groundwater. A key feature of this second-generation pilot MBfR is that it employed lower cost polyester hollow fibers and still achieved high loading rate. The steady-state maximum nitrate surface loading at which the effluent nitrate and nitrite concentrations were below the Maximum Contaminant Level (MCL) was at least 5.9 g·N·(m2·d)−1, which corresponds to a maximum volumetric loading of at least 7.7 kg·N·(m3·d) −1. The steady-state maximum nitrate surface area loading was higher than the highest nitrate surface loading reported in the first-generation MBfRs using composite fibers (2.6 g·N·(m2·d)−1). This work also evaluated the H2-utilization efficiency in MBfR. The measured H2 supply rate was only slightly higher than the stoichiometric H2-utilization rate. Thus, H2 utilization was controlled by diffusion and was close to 100% efficiency, as long as biofilm accumulated on the polyester-fiber surface and the fibers had no leaks.
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Keywords
denitrification
groundwater treatment
hydrogen
membrane biofilm reactor (MBfR)
polyester fiber
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Issue Date: 05 September 2010
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