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Frontiers of Physics

ISSN 2095-0462

ISSN 2095-0470(Online)

CN 11-5994/O4

邮发代号 80-965

2019 Impact Factor: 2.502

Frontiers of Physics  2018, Vol. 13 Issue (1): 138202   https://doi.org/10.1007/s11467-017-0686-6
  本期目录
NMR investigation of degradation processes of ancient and modern paper at different hydration levels
Domenico Mallamace1(), Sebastiano Vasi2, Mauro Missori3, Francesco Mallamace2,4,5, Carmelo Corsaro2,4
1. Consorzio interuniversitario per lo sviluppo dei Sistemi a Grande Interfase- CSGI, Via della Lastruccia 3, 50019 Sesto Fiorentino, Firenze, Italy
2. Dipartimento MIFT, Sezione di Fisica, Università di Messina, Viale F. Stagno D’Alcontres 31, 98166 Messina, Italy
3. Istituto dei Sistemi Complessi, Consiglio Nazionale delle Ricerche, Unit Sapienza, Piazzale Aldo Moro 5, 00185 Roma, Italy
4. CNR-IPCF Messina, Istituto per i Processi Chimico-Fisici, Viale F. Stagno D’Alcontres 37, 98158 Messina, Italy
5. Center for Polymer Studies and Department of Physics, Boston University, Boston, MA 02215, USA
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Abstract

The degradation process of cellulose-made materials was investigated by means of nuclear magnetic resonance (NMR) spectroscopy, with particular emphasis on the role of water and on the hydration mechanism of cellulose fibrils. To accomplish this, the structure and dynamics of water within ancient and modern samples with different aging histories were investigated. The results mainly indicated that hydrolytic and oxidative reactions provoked the formation of acidic by-products. Furthermore, degradation processes were enhanced by higher amounts of water giving a progressive consumption of the amorphous regions of the cellulose. We propose NMR experiments as a benchmark for characterization of the degradation state of paper, as well as for investigating the effectiveness of restoration treatments.

Key wordsancient paper    degradation    NMR    hydration    solvent dynamics
收稿日期: 2017-02-24      出版日期: 2018-02-28
Corresponding Author(s): Domenico Mallamace   
 引用本文:   
. [J]. Frontiers of Physics, 2018, 13(1): 138202.
Domenico Mallamace, Sebastiano Vasi, Mauro Missori, Francesco Mallamace, Carmelo Corsaro. NMR investigation of degradation processes of ancient and modern paper at different hydration levels. Front. Phys. , 2018, 13(1): 138202.
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https://academic.hep.com.cn/fop/CN/10.1007/s11467-017-0686-6
https://academic.hep.com.cn/fop/CN/Y2018/V13/I1/138202
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