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Synthesis, characterization and photosensitivity
of tetrakis--(2-methyl-8-quinolinoxy)
metallophthalocyanines |
| XUE Jinping1, LIU Hong1, CHEN Naisheng1, HUANG Jinling1, FAN Changan2, HONG Huming3 |
| 1.Institute of Functional Materials, College of Chemistry and Chemical Engineering, Fuzhou University; 2.Fujian Sanming Jianning Fire Company; 3.Laboratory of Physics and Chemistry, Taigu Aeroengineering Ltd. |
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Abstract Four amphipathic cobalt(II), nickel(II), copper(II), and zinc(II) coordination compounds of tetrakis-?-(2-methyl-8-quinolinoxy)phthalocyanine are synthesized using “DBU catalytic method”. The titled complexes are characterized by elemental analysis, mass spectra, UV-Vis, and IR spectra. In addition, the rates of photogenerated singlet oxygen and the rate constants of photodynamic oxidation of amino-acid substrate by the complexes are measured under the optical excitation at 670 nm, and the relations between their structures and their photosensitivities are discussed.
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Issue Date: 05 September 2008
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