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Unimolecular half-adders and half-subtractors
based on acid-base reaction |
Wei JIANG , Hengyi ZHANG , Yu LIU , |
Department of Chemistry,
State Key Laboratory of Elemento-Organic Chemistry, Nankai University,
Tianjin 300071, China.; |
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Abstract According to the structural analysis of reported molecular processors with acids and bases as inputs, we proposed a general method for constructing molecular half-adders and/or half-subtractors based on acid-base reaction. The method is preliminarily supported by four molecular processors (8-hydroxyquinoline, 4-hydroxypyridine, 4-aminophenol and 5-amino-1-naphthol) capable of the elementary addition and/or subtraction algebraic operations. Noticeably, 8-hydroxyquinoline can mimic the functions of three logic devices, i.e. half-adder, half-subtractor and digital comparator, by the use of superposition and reconfiguration. The method described in this paper may be useful not only for designing new unimolecular arithmetical processors with the same inputs and outputs as standard devices for the construction of future molecular computers, but it can also help us disclose the simplest molecules and biomolecules with computational properties concealed around us.
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Issue Date: 05 September 2009
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de Silva, A. P.; Gunaratne, H. Q.N.; McCoy, C. P., Nature1993, 364, 42
doi: 10.1038/364042a0
|
|
Callan, J. F.; de Silva, A. P.; Magri, D. C., Tetrahedron2005, 61, 8551
doi: 10.1016/j.tet.2005.05.043
|
|
Pischel, U., Angew. Chem. Int. Ed. 2007, 46, 4026
doi: 10.1002/anie.200603990
|
|
Szaciłowski, K., Chem. Rev. 2008, 108, 3481
doi: 10.1021/cr068403q
|
|
de Silva, A. P.; McClenaghan, N. D., J. Am. Chem. Soc. 2000, 122, 3965
doi: 10.1021/ja994080m
|
|
Remacle, F.; Speiser, S.; Levine, R. D., J. Phys. Chem. B2001, 105, 5589
doi: 10.1021/jp0101211
|
|
Andréasson, J.; Kodis, G.; Terazono, Y.; Liddell, P. A.; Bandyopadhyay, S.; Mitchell, R. H.; Moore, T. A.; Moore, A. L.; Gust, D., J. Am. Chem. Soc. 2004, 126, 15926
doi: 10.1021/ja045577l
|
|
Guo, X. F.; Zhang, D. Q.; Zhang, G. X.; Zhu, D. B., J. Phys. Chem. B2004, 108, 11942
doi: 10.1021/jp047706q
|
|
Qu, D. H.; Wang, Q. C.; Tian, H., Angew. Chem. Int. Ed. 2005, 44, 5296
doi: 10.1002/anie.200501215
|
|
Zhou, Y. C.; Wu, H.; Qu, L.; Zhang, D. Q.; Zhu, D. B., J. Phys. Chem. B2006, 110, 15676
doi: 10.1021/jp062849t
|
|
Andréasson, J.; Straight, S. D.; Kodis, G.; Park, C. D.; Hambourger, M.; Gervaldo, M.; Albinsson, B.; Moore, T. A.; Moore, A. L.; Gust, D., J. Am. Chem. Soc. 2006, 128, 16259
doi: 10.1021/ja0654579
|
|
Margulies, D.; Melman, G.; Felder, C. E.; Arad-Yellin, R.; Shanzer, A., J. Am. Chem. Soc. 2004, 126, 15400
doi: 10.1021/ja0453329
|
|
Margulies, D.; Melman, G.; Shanzer, A., Nature Mater. 2005, 4, 768
doi: 10.1038/nmat1469
|
|
Margulies, D.; Melman, G.; Shanzer, A., J. Am. Chem. Soc. 2006, 128, 4865
doi: 10.1021/ja058564w
|
|
Liu, Y.; Jiang, W.; Zhang, H. Y.; Li, C. J., J. Phys. Chem. B2006, 110, 14231
doi: 10.1021/jp061749k
|
|
Sun, W.; Xu, C. H.; Zhu, Z.; Fang, C. J.; Yan, C. H., J. Phys.Chem. C2008, 112, 16973
doi: 10.1021/jp804628u
|
|
Langford, S. J.; Yann, T., J. Am. Chem. Soc. 2003, 125, 11198
doi: 10.1021/ja036909+
|
|
Coskun, A.; Deniz, E.; Akkaya, E., Org. Lett. 2005, 7, 5187
doi: 10.1021/ol052020h
|
|
Guo, Z. Q.; Zhao, P.; Zhu, W. H.; Huang, X. M.; Xie, Y. S.; Tian, H., J. Phys. Chem. C2008, 112, 7047
doi: 10.1021/jp0777162
|
|
Suresh, M.; Jose, D. A.; Das, A., Org. Lett. 2007, 9, 441
doi: 10.1021/ol0628457
|
|
Andréasson, J.; Straight, S. D.; Bandyopadhyay, S.; Mitchell, R. H.; Moore, T. A.; Moore, A. L.; Gust, D., Angew. Chem. Int. Ed. 2007, 46, 958
doi: 10.1002/anie.200603856
|
|
Amelia, M.; Baroncini, M.; Credi, A., Angew. Chem. Int. Ed. 2008, 47, 6240
doi: 10.1002/anie.200802018
|
|
Margulies, D.; Felder, C. E.; Melman, G.; Shanzer, A., J. Am. Chem. Soc. 2007, 129, 347
doi: 10.1021/ja065317z
|
|
Guo, Z. Q.; Zhu, W. H.; Shen, L. J.; Tian, H., Angew. Chem. Int. Ed. 2007, 46, 5549
doi: 10.1002/anie.200700526
|
|
de Silva, A. P.; McClenaghan, N. D., Chem. Eur. J. 2004, 10, 574
doi: 10.1002/chem.200305054
|
|
Tang, C. W.; VanSlyke, S. A., Appl. Phys. Lett. 1987, 51, 913
doi: 10.1063/1.98799
|
|
Bardez, E.; Devol, I.; Larrey, B.; Valeur, B., J. Phys. Chem. B1997, 101, 7786
doi: 10.1021/jp971293u
|
|
Goldman, M.; Wehry, E. L., Anal. Chem. 1970, 42, 1178
doi: 10.1021/ac60293a045
|
|
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