Characterization of polybenzoxazine and its electrochemical
polymerization mechanism

doi:10.1007/s11458-009-0105-9

Front. Chem. China

2009, Vol. 4

Issue (4) : 390-395 https://doi.org/10.1007/s11458-009-0105-9

Research articles

Characterization of polybenzoxazine and its electrochemical polymerization mechanism

Wei CHEN,Jinbo HE,Liang LI,

Department of Polymer Science and Engineering, College of Chemistry and Chemical Engineering, National Lab of Microstructure Studies, Nanjing University, Nanjing 210093, China;

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Abstract Poly(3-(p-methyl)benzyl-3,4-dihydro-6-methyl-2H-1,3-benzoxazine) (poly(pCpT)), which was obtained from electrochemical polymerization in acetonitrile/alkali aqueous solution, was characterized by FT-IR, UV-Vis and ¹H-NMR. The results indicate a ring-opening structure of the polymer. By using a rotating-ring disc electrode (RRDE), the electrochemical behaviors of polymerization were studied and the polymerization mechanism was proposed.

Keywords polybenzoxazine electropolymerization heat-resistance rotating-ring disc electrode electrochemical behavior

Issue Date: 05 December 2009

Cite this article:

Wei CHEN,Liang LI,Jinbo HE. Characterization of polybenzoxazine and its electrochemical polymerization mechanism[J]. Front. Chem. China, 2009, 4(4): 390-395.

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https://academic.hep.com.cn/fcc/EN/10.1007/s11458-009-0105-9
https://academic.hep.com.cn/fcc/EN/Y2009/V4/I4/390

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