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Investigation into ramie whisker reinforced arylated
soy protein composites |
Rakesh KUMAR1,Lina ZHANG2, |
1.Department of Chemistry,
Wuhan University, Wuhan 430072, China;CSIR MSM, Port Elizabeth
6000, South Africa; 2.Department of Chemistry,
Wuhan University, Wuhan 430072, China; |
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Abstract Whiskers were prepared from ramie fibers and were characterized using atomic force microscopy to evaluate their dimensions. SPI/whiskers composites (SW) were prepared by incorporating different weight contents (wt.%) of the whiskers into soy protein isolate (SPI). Thiodiglycol was used as a plasticizer for the preparation of SW composites. The SW composites were arylated with 2,2-diphenyl-2-hydroxyethanoic acid through the process of “dip-coating” and coded as SW-B. In this paper, the characterization of SW and SW-B composites, such as their morphologies, mechani- cal properties, thermal stability, optical transmittance, and water uptake, are discussed. The results indicated substantial improvement in the water resistance, thermal stability, and the modulus of the SW-B composites after arylation due to the formation of hydrophobic diphenylhydroxymethane (DPHM) microparticles on the surface. This work provides a novel method to increase the water resistance of protein based composites.
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Keywords
soy protein
ramie whiskers
water uptake
arylation
composites
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Issue Date: 05 March 2010
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Lodha, P.; Netravali A. N., J. Mat. Sci. 2002, 37, 3657–3665
doi: 10.1023/A:1016557124372
|
|
Mohanty, A. K.; Khan, M. A.; Sahoo, S.; Hinrichsen, G., J. Mat. Sci. 2000, 35, 2589–2595
doi: 10.1023/A:1004723330799
|
|
Otaigbe, J. U.; Goel, H.; Babcock, T.; Jane, J., J. Elast. Plast. 1999, 31, 56–71
|
|
Paetau, I.; Chen, C. Z.; Jane, J. L., Ind. Eng. Chem. Res. 1994, 33, 1821–1827
doi: 10.1021/ie00031a023
|
|
Liu, W.; Mohanty, A. K.; Askeland, P.; Drzal, L. T.; Misra, M., Polymer2004, 45, 7589–7596
doi: 10.1016/j.polymer.2004.09.009
|
|
Lu, Y.; Weng, L.; Zhang, L., Biomacromolecules2004, 5, 1046–1051
doi: 10.1021/bm034516x
|
|
Wang, Y.; Cao, X.; Zhang, L., Macromol. Biosci. 2006, 6, 524–531
doi: 10.1002/mabi.200600034
|
|
Tjong, S. C.; Meng, Y. Z., J. Appl. Polym. Sci. 1999, 72, 501–508
doi: 10.1002/(SICI)1097-4628(19990425)72:4<501::AID-APP6>3.0.CO;2-2
|
|
Angellier, H.; Boisseau, S. M.; Dole, P.; Dufresne, A., Biomacromolecules2006, 7, 531–539
doi: 10.1021/bm050797s
|
|
Chazeau, L.; Paillet, M.; Cavaill, J. Y.,?J. Polym. Sci. Part B:Polym. Phys. 1999, 37, 2151–2164
doi: 10.1002/(SICI)1099-0488(19990815)37:16<2151::AID-POLB17>3.0.CO;2-V
|
|
Chazeau, L.; Cavaill, J. Y.; Perez, J., J. Polym. Sci. Part B:Polym. Phys. 2000, 38, 383–392
doi: 10.1002/(SICI)1099-0488(20000201)38:3<383::AID-POLB5>3.0.CO;2-Q
|
|
Nair, K. G.; Dufresne, A., Biomacromolecules2003, 4, 657–665
doi: 10.1021/bm020127b
|
|
Nair, K. G.; Dufresne, A., Biomacromolecules2003, 4, 666–674
doi: 10.1021/bm0201284
|
|
Malkapuram R.; Kumar, V.; Negi, Y. S., J. Reinf. Plast. Compos. 2009, 28, 1169–1189
doi: 10.1177/0731684407087759
|
|
Kumar, R.; Wang, L.; Zhang, L., J. Appl. Polym. Sci. 2009, 111, 970–977
doi: 10.1002/app.28888
|
|
Kumar, R.; Zhang, L., Biomacromolecules2008, 9, 2430–2437
doi: 10.1021/bm800396x
|
|
Kumar, R.; Zhang, L., Ind. Crops Prod. 2009, 29, 485–494
doi: 10.1016/j.indcrop.2008.09.010
|
|
Kumar, R.; Zhang, L., Compos. Sci. Techn. 2009, 69, 555–560
doi: 10.1016/j.compscitech.2008.10.027
|
|
de Rodriguez, N. L. G.; Thielemans, W.; Dufresne, A., Cellulose2006, 13, 261–270
doi: 10.1007/s10570-005-9039-7
|
|
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