Cooperative recognition of Cu 2+ based on amino acids tethered benzothiadiazoyl-bistriazoles

doi:10.1007/s11458-010-0117-5

Front. Chem. China

2010, Vol. 5

Issue (2) : 208-213 https://doi.org/10.1007/s11458-010-0117-5

Research articles

Cooperative recognition of Cu 2+ based on amino acids tethered benzothiadiazoyl-bistriazoles

Yi-Bin RUAN¹,Stephane MAISONNEUVE¹,Juan XIE¹,Chun LI²,Jie TANG³,

1.PPSM, Institut d’Alembert, ENS Cachan, CNRS, Universud, 61 av President Wilson, F-94230 Cachan, France; 2.PPSM, Institut d’Alembert, ENS Cachan, CNRS, Universud, 61 av President Wilson, F-94230 Cachan, France；Institute of Medicinal Chemistry, Department of Chemistry, East China Normal University, Shanghai 200062, China; 3.Institute of Medicinal Chemistry, Department of Chemistry, East China Normal University, Shanghai 200062, China;

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Abstract Fluoroionophoric properties of benzothiadiazoyl-bistriazoyl amino acids derivatives toward metal ions were investigated by UV-Vis and fluorescence spectroscopy. Our results show that the water soluble lysine derivative 2 exhibited a significant selectivity toward Cu²⁺ in “on-off” type response in buffer solution at pH 7.4.

Keywords benzothiadiazoyl-bistriazoles fluoroionophores Cu2+ fluorescence quenching cooperative recognition

Issue Date: 05 June 2010

Cite this article:

Yi-Bin RUAN,Stephane MAISONNEUVE,Juan XIE, et al. Cooperative recognition of Cu 2+ based on amino acids tethered benzothiadiazoyl-bistriazoles[J]. Front. Chem. China, 2010, 5(2): 208-213.

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https://academic.hep.com.cn/fcc/EN/10.1007/s11458-010-0117-5
https://academic.hep.com.cn/fcc/EN/Y2010/V5/I2/208

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