Preparation and permeability of ZSM-35 zeolite membranes on porous stainless steel tubes
Preparation and permeability of ZSM-35 zeolite membranes on porous stainless steel tubes
ZHU Gang1, WANG Jinqu2, ZHANG Yan2, LU Jinming2, XIU Jinghai2
1.State Key Laboratory of Fine Chemicals, Institute of Adsorption and Inorganic Membrane, Dalian University of Technology, Dalian 116012, China; Dalian University of Technology Greentech Co., Ltd, Dalian 116012, China; 2.State Key Laboratory of Fine Chemicals, Institute of Adsorption and Inorganic Membrane, Dalian University of Technology, Dalian 116012, China
Abstract：ZSM-35 zeolite membranes were prepared on porous stainless steel tubes with silica sol and tetraethoxysilane as silica source, and with 1-butylamine and ethylenediamine as templates, respectively. The characterization of X-ray diffraction (XRD) and scanning electron microscopy (SEM) showed that the membranes prepared with ethylenediamine as the template displayed growth orientation with their crystal planes (h00) parallel to the support surface. The single-component permeability tests of H2, N2 and C3H8 showed that the membranes synthesized with ethylenediamine as the template, compared with those with 1-butylamine as the template, showed relatively higher permeation rates and ideal separation factors, and above their corresponding ideal Knudsen diffusion factors, which might be attributed to the different growth orientation of zeolite membranes synthesized with different templates.
出版日期: 2007-09-05
引用本文:
. Preparation and permeability of ZSM-35 zeolite membranes on porous stainless steel tubes[J]. Frontiers of Chemical Engineering in China, 2007, 1(3): 217-220.
ZHU Gang, WANG Jinqu, ZHANG Yan, LU Jinming, XIU Jinghai. Preparation and permeability of ZSM-35 zeolite membranes on porous stainless steel tubes. Front. Chem. Sci. Eng., 2007, 1(3): 217-220.
