A new method for the synthesis of molybdovanadophosphoric heteropoly acids and their catalytic activities
A new method for the synthesis of molybdovanadophosphoric heteropoly acids and their catalytic activities
ZHANG Fumin, GUO Maiping, GE Hanqing, WANG Jun
Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing 210009, China;
Abstract：An environmentally benign method for the synthesis of heteropoly acids H3+nPMo12 nVnO40·xH2O (PMoVn, n = 1−3) was developed by the reaction of an aqueous slurry which contained stoichiometric amounts of MoO3, V2O5 and H3PO4. Characterization of the as-synthesized catalysts with inductively coupled plasma (ICP) elemental analysis, thermogravimetry (TG), X-ray diffraction (XRD) and infrared (IR) spectroscopy indicated that V ions substituted for Mo ions in Keggin-type phosphomolybdic acid. The as-synthesized samples were found to be an efficient catalyst for the hydroxylation of benzene which was carried out in a mixed solvent of acetonitrile and acetic acid with aqueous hydrogen peroxide as oxidant. PMoV2 exhibi ted the highest benzene conversion of 34.5% with phenol selectivity of 100%.
出版日期: 2007-09-05
引用本文:
. A new method for the synthesis of molybdovanadophosphoric heteropoly acids and their catalytic activities[J]. Frontiers of Chemical Engineering in China, 2007, 1(3): 296-299.
ZHANG Fumin, GUO Maiping, GE Hanqing, WANG Jun. A new method for the synthesis of molybdovanadophosphoric heteropoly acids and their catalytic activities. Front. Chem. Sci. Eng., 2007, 1(3): 296-299.
