Selective removal of Cu(II) from contaminated
water using molecularly imprinted polymer

doi:10.1007/s11705-008-0019-y

Frontiers of Chemical Engineering in China - Selected Publications from Chinese Universities

2008, Vol. 2

Issue (1): 109-114 https://doi.org/10.1007/s11705-008-0019-y

本期目录

Selective removal of Cu(II) from contaminated water using molecularly imprinted polymer

QI Jingyao¹, LI Xin², LI Ying², ZHU Jianhua², QIANG Liangsheng²

1.School of Municipal and Environment, Harbin Institute of Technology; 2.Department of Applied Chemistry, Harbin Institute of Technology

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Abstract：A synthetic molecularly imprinted polymer (MIP) was prepared by noncovalent imprinting technique for the selective removal of Cu²⁺ from aqueous solutions. In the preparation of imprinted polymer, Cu²⁺ was used as the template, oleic acid as the functional monomer and divinylbenzene as the cross-linker. The surface morphologies and characteristics of the MIP were determined by BET, scanning electron microscopy (SEM), FTIR and energy dispersive X-ray spectrometer (EDS). The proper adsorption and selective recognition ability of the MIP were studied by an equilibrium-adsorption method. In general, the removal efficiency of Cu²⁺ increased rapidly with pH from 2 to 7 and decreased at a pH 8. The removal efficiency of Cu²⁺ increased with temperature from 25°C to 50°C. Competitive adsorption studies showed that the coexisting cations have no obvious influence on the adsorption of Cu²⁺. In addition, the variation in the adsorption ability of the MIP that was repeatedly used was investigated, and it showed excellent reproducibility.

出版日期: 2008-03-05

引用本文:

. Selective removal of Cu(II) from contaminated water using molecularly imprinted polymer[J]. Frontiers of Chemical Engineering in China - Selected Publications from Chinese Universities, 2008, 2(1): 109-114.
QI Jingyao, LI Xin, LI Ying, ZHU Jianhua, QIANG Liangsheng. Selective removal of Cu(II) from contaminated water using molecularly imprinted polymer. Front. Chem. Sci. Eng., 2008, 2(1): 109-114.

链接本文:

https://academic.hep.com.cn/fcse/CN/10.1007/s11705-008-0019-y
https://academic.hep.com.cn/fcse/CN/Y2008/V2/I1/109

1	Korngold E Belfer S Urtizberea C Removal of heavy metals from tap water by a cation exchangerDesalination 1996 104197201
2	Li Y H Luan Z K Zhou X W Xu C Wu D Wei B Q Removal ofCu²⁺ ions from aqueous solutions by carbonnanotubesAdsorpt Sci Technol 2003 21475485
3	Huang C Huang C P Morehart A L The removal of Cu(II) from dilute aqueous solutions byS. cerevisiaeWater Res 1989 24433439
4	Jang L K Nauyen D Geesey G G Effect of pH on the absorption of Cu(II) by alginate gelWater Res 1995 29315321
5	Huang C Huang C P Application of aspergillusoryzae and rhizoupus oryzae for Cu(II) removalWater Res 1996 3019851990
6	An H K Park B Y Kim D S Crab shell for the removal of heavy metals from aqueoussolutionWater Res 2001 3535513556
7	Kim M S Hong K M Chung J G Removal of Cu(II) from aqueous solutions by adsorptionprocess with anatase-type titanium dioxideWater Res 2003 3735243529
8	Ajmal M Rao R A K Khan M A Adsorption of copper from aqueous solution on Brassicacumpestris (mustard oil cake)J Hazard MaterB 2005 122177183
9	Ozsoy H D Kumbur H Adsorption of Cu(II) ions oncotton bollJ Hazard Mater B 2006 136911916
10	Rengaraj S Yeon J Kim Y Jung Y Ha Y Kim W Adsorption characteristicsof Cu(II) onto ion exchange resins 252H and 1500H: kinetics, isothermsand error analysisJ Hazard Mater B 2007 143469477
11	Piletsky S A Alcock S Turner A P Molecular imprinting at the edg of the third millennium,TrendsBiotechnol 2001 19912
12	Haupt K Mosbach K Molecularly imprinted polymersand their use in biomimetic sensorsChemRev 2000 10024952504
13	Wulff G Enzyme-likecatalysis by molecularly imprinted polymersChem Rev 2002 102124
14	Cormack P A G Elorza A Z Molecularly imprinted polymers:synthesis and characterizationJ ChromatogrB 2004 804173182
15	Haupt K Molecularlyimprinted polymers: the next generationAnal Chem 2003 75376A383A
16	Haupt K Imprintedpolymers-tailor-made mimics of antibodies and receptorsChem Commun 2003 2171178
17	Mahony J O Nolan K Smyth M R Mizaikoff B Molecularlyimprinted polymers-potential and challenges in analytical chemistryAnal Chim Acta 2005 5343139
18	Dai S Shin Y S Barnes C E Toth L M Enhancementof uranyl adsorption capacity and selectivity on silica sol-gel glassesvia molecular imprintingChem Mate 1997 925212525
19	Meng Z Chen W Mulchandani A Removal of estrogenic pollutants from contaminated waterusing molecularly imprinted polymersEnvironSci Technol 2005 3989588962
20	Noir M L Lepeuple A S Guieysse B Mattiasson B Selectiveremoval of 17β-estradiol at trace concentration using a molecularlyimprinted polymerWater Res 2007 4128252831

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