Polymer-nanoinorganic particles composite membranes: a brief overview
Polymer-nanoinorganic particles composite membranes: a brief overview
Zhen-liang XU1,2(), Li-yun YU2, Ling-feng HAN2
1. State Key Laboratory of Chemical Engineering, East China University of Science and Technology , Shanghai 200237, China; 2. Membrane Science and Engineering R&D Lab, Chemical Engineering Research Center, East China University of Science and Technology, Shanghai 200237, China
Polymer-nanoinorganic particles composite membranes present an interesting approach for improving the physical and chemical, as well as separation properties of polymer membranes, because they possess characteristics of both organic and inorganic membranes such as good permeability, selectivity, mechanical strength, thermal stability and so on. The preparations and structures of polymer-nanoinorganic particles composite membranes and their unique properties are reviewed.
Clarizia G, Algieri C, Drioli E. Filler-polymer combination: a route to modify gas transport properties of a polymeric membrane. Polymer , 2004, 45: 5671-5681 doi: 10.1016/j.polymer.2004.06.001
2
Yang Y N, Wang P. Preparation and characterizations of a new PS/TiO2 hybrid membranes by sol-gel process. Polymer , 2006, 47: 2683-2688 doi: 10.1016/j.polymer.2006.01.019
3
Guizard C, Bac A, Barboiu M, Hovnanian N. Hybrid organic-inorganic membranes with specific transport properties: applications in separation and sensors technologies. Sep Purif Technol , 2001, 25: 167-180 doi: 10.1016/S1383-5866(01)00101-0
4
Lu Z H, Liu G J, Duncan S. Poly(2-hydroxyethyl acrylate-co-methyl acrylate)/SiO2/TiO2 hybrid membranes. J Membr Sci , 2003, 221: 113-122 doi: 10.1016/S0376-7388(03)00251-5
5
Chiang P C, Whang W T, Tsai M H, Wu S C. Physical and mechanical properties of polyimide/titania hybrid films. Thin Solid Films , 2004, 447-448: 359-364 doi: 10.1016/S0040-6090(03)01081-2
6
Taniguchi A, Cakmak M. The suppression of strain induced crystallization in PET through submicron TiO2 particle incorporation. Polymer , 2004, 45: 6647-6654 doi: 10.1016/j.polymer.2004.06.056
7
Peng F, Lu L, Sun H, Wang Y, Wu H, Jiang Z. Correlations between free volume characteristics and pervaporation permeability of novel PVA-GPTMS hybrid membranes. J Membr Sci , 2006, 275: 97-104 doi: 10.1016/j.memsci.2005.09.008
8
Peng F, Lu L, Sun H, Wang Y, Liu J, Jiang Z. Hybrid organic-inorganic membrane: solving the tradeoff between permeability and selectivity. Chem Mater , 2005, 17: 6790-6796 doi: 10.1021/cm051890q
9
Patel N P, Zielinski J M, Samseth J, Spontak R J. Effects of pressure and nanoparticle functionality on CO2-selective nanocomposites derived from cross-linked poly(ethylene glycol). Macromol Chem Phys , 2004, 205: 2409-2419 doi: 10.1002/macp.200400356
10
Shekhawat D, Luebke D R, Pennline H W. A review of carbon dioxide selective membranes. US Department of Energy , 2003
11
Okui T, Saito Y, Okubo T, Sadakata M. Gas permeation of porous organic/inorganic hybrid membranes. J Sol-Gel Sci Technol , 1995, 5: 127-134 doi: 10.1007/BF00487728
12
Ai X, Hu X. Study on organic-inorganic hybrid membranes. Huaxue Jinzhan , 2003, 16: 654-659 (in Chinese)
13
Genne I, Kuypers S, Leysen R. Effect of the addition of ZrO2 to polysulfone based UF membranes. J Membr Sci , 1996, 113: 343-350 doi: 10.1016/0376-7388(95)00132-8
14
Wara N M, Francis L F, Velamakanni B V. Addition of alumina to cellulose acetate membranes. J Membr Sci , 1995, 104: 43-49 doi: 10.1016/0376-7388(95)00010-A
15
Stephen R, Ranganathaiah C, Varghese S, Joseph K, Thomas S. Gas transport through nano and micro composites of natural rubber (NR) and their blends with carboxylated styrene butadiene rubber (XSBR) latex membranes. Polymer , 2006, 47: 858-870 doi: 10.1016/j.polymer.2005.12.020
16
Mascia L, Zhang Z, Shaw S J. Carbon fibre composites based on polyimide/silica ceramers: aspects of structure-properties relationship. Composites A, 1996, 27: 1211-1221 doi: 10.1016/1359-835X(96)00082-6
17
Shi D, Kong Y, Yang J, Du H. Study on transitional metal organic complex-polyimide hybrid material for gas separation membranes. Acta Polym Sin , 2000, 4: 457-461
18
Liu H. Synthesis of TiO2 nanopowder enwrapped by organic membrane with microwave induced plasma method. Huaxue Tongbao , 1997, 10: 44-46
19
Doucoure A, Guizard C, Durand J, Berjoan R, Cot L. Plasma polymerization of fluorinated monomers on mesoporous silica membranes and application to gas permeation. J Membr Sci , 1996, 117: 143-150 doi: 10.1016/0376-7388(96)00052-X
20
Patel N P, Miller A C, Spontak R J. Highly CO2-permeable and selective polymer nanocomposite membranes. Adv Mater , 2003, 15: 729-733 doi: 10.1002/adma.200304712
21
Patel N P, Aberg C M, Sanchez A M, Capracotta M D, Martin J D, Spontak R J. Morphological, mechanical and gas-transport characteristics of cross-linked poly(propylene glycol): homopolymers, nanocomposites and blends. Polymer , 2004, 45: 5941-5950 doi: 10.1016/j.polymer.2004.06.024
22
Nunes S P, Peinenmann K V, Ohlorogge K, Alpers A, Keller M, Pires A T N. Membranes of poly(ether imide) and nanodispersed silica. J Membr Sci , 1999, 157: 219-226 doi: 10.1016/S0376-7388(98)00379-2
23
Brzesowsky R H, de With G, van den Cruijsem S, Snijkers-Hendrickx I J M, Wolter W A M, van Lierop J G. Glass strengthening by silica particle reinforced organic-inorganic coatings. J Non-Cryst Solids , 1998, 241: 27-37 doi: 10.1016/S0022-3093(98)00750-9
Kioul A, Mascia L. Compatibility of polyimide-silicate ceramers induced by alkoxysilane silane coupling agents. J Non-Cryst Solids , 1994, 175: 169-186 doi: 10.1016/0022-3093(94)90009-4
26
Smaihi M, Jermoumi T, Marignan J, Noble R D. Organic-inorganic gas separation membranes: preparation and characterization. J Membr Sci , 1996, 116: 211-220 doi: 10.1016/0376-7388(96)00042-7
27
Iwata M, Adachi T, Tomidokoro M, Ohta M, Kobayashi T. Hybrid sol-gel membranes of polyacrylonitrile–tetraethoxysilane composites for gas permselectivity. J Appl Polym Sci , 2003, 88: 1752-1759 doi: 10.1002/app.11895
28
Gomes D, Nunes S P, Peinemann K V. Membranes for gas separation based on poly(1-trimetylsilyl-1-propyne)-silica nanocomposites. J Membr Sci , 2005, 246: 13-25 doi: 10.1016/j.memsci.2004.05.015
29
Vollenberg P H T, Heikens D. Particle size dependence of the Young's modulus of filled polymers: 1. preliminary experiments. Polymer , 1989, 30: 1656-1662 doi: 10.1016/0032-3861(89)90326-1
30
Chan C M, Wu J, Li J X, Cheung Y K. Polypropylene/calcium carbonate nanocomposites. Polymer , 2002, 43: 2981-2992 doi: 10.1016/S0032-3861(02)00120-9
31
Shelley J S, Mather P T, DeVries K L. Reinforcement and environmental degradation of nylon-6/clay nanocomposites. Polymer , 2001, 42: 5849-5858 doi: 10.1016/S0032-3861(00)00900-9
32
Park C I L, Park O O, Lim J G, Kim H J. The fabrication of syndiotactic polystyrene/organophilic clay nanocomposites and their properties. Polymer , 2001, 42: 7465-7475 doi: 10.1016/S0032-3861(01)00213-0
33
Jordan J, Jacob K I, Tannenbaum R, Sharaf M A, Jasiuk I. Experimental trends in polymer nanocomposites—a review. Mat Sci Eng A , 2005, 393: 1-11 doi: 10.1016/j.msea.2004.09.044
34
Reynaud E, Jouen T, Gautheir C, Vigier G. Nanofillers in polymeric matrix: a study on silica reinforced PA6. Polymer , 2001, 42: 8759-8768 doi: 10.1016/S0032-3861(01)00446-3
35
Rong M Z, Zhang M Q, Zheng Y X, Zeng H M, Walter R, Friedrich K. Structure-property relationships of irradiation grafted nano-inorganic particle filled polypropylene composites. Polymer , 2001, 42: 167-183 doi: 10.1016/S0032-3861(00)00325-6
36
Sheng N, Boyce M C, Parks D M, Rutledge G C, Abes J I, Cohen R E. Multiscale micromechanical modeling of polymer/clay nanocomposites and the effective clay particle. Polymer , 2004, 45: 487-506 doi: 10.1016/j.polymer.2003.10.100
37
Priya L, Jog J P. Poly(vinylidene fluoride)/clay nanocomposites prepared by melt intercalation: crystallization and dynamic mechanical behavior studies. J Polym Sci B: Polym Phys , 2002, 40: 1682-1689 doi: 10.1002/polb.10223
38
Tortora M, Gorrasi G, Vittoria V, Galli G, Ritrovati S, Chiellini E. Structural characterization and transport properties of organically modified montmorillonite/polyurethane nanocomposites. Polymer , 2002, 43: 6147-6157 doi: 10.1016/S0032-3861(02)00556-6
39
Varlot K M, Reynaud E, Vigier G, Varlet J. Mechanical properties of clay-reinforced polyamide. J Polym Sci B: Polym Phys , 2002, 40: 272-283 doi: 10.1002/polb.10088
40
Arocha P U, Mehler C, Puskas J E, Altstat V. Effect of sample thickness on the mechanical properties of injection-molded polyamide-6 and polyamide-6 clay nanocomposites. Polymer , 2003, 44: 2441-2446 doi: 10.1016/S0032-3861(03)00115-0
41
Zoppi R A, das Neves S, Nunes S P. Hybrid films of poly(ethylene oxide-b-amide-6) containing sol-gel silicon or titanium oxide as inorganic fillers: effect of morphology and mechanical properties on gas permeability. Polymer , 2000, 41: 5461-5470 doi: 10.1016/S0032-3861(99)00751-X
42
Park C I, Choi W M, Kim M H, Park O O. Thermal and mechanical properties of syndiotactic polystyrene/organoclay nanocomposites with different microstructures. J Polym Sci B: Polym Phys , 2004, 42: 1685-1693
43
Gangopadhyay R, De A. Conducting polymer nanocomposites: a brief overview. Chem Mater , 2000, 12: 608-622 doi: 10.1021/cm990537f
44
Xiao Y C, Wang K Y, Chung T S, Tan J. Evolution of nano-particle distribution during the fabrication of mixed matrix TiO2-polyimide hollow fiber membranes. Chem Eng Sci , 2006, 61: 6228-6233 doi: 10.1016/j.ces.2006.05.040
45
Jiang L Y, Chung T S, Cao C, Huang Z, Kulprathipanja S. Fundamental understanding of nano-sized zeolite distribution in the formation of the mixed matrix single- and dual-layer asymmetric hollow fiber membranes. J Membr Sci , 2005, 252: 89-100 doi: 10.1016/j.memsci.2004.12.004
46
Lu Y, Yu S L, Chai B X, Shun X D. Effect of nano-sized Al2O3-particle addition on PVDF ultrafiltration membrane performance. J Membr Sci , 2006, 276: 162-167 doi: 10.1016/j.memsci.2005.09.044
47
Li J F, Xu Z L, Yang H, Yu L Y, Liu M. Effect of TiO2 nanoparticles on the surface morphology and performance of microporous PES membrane. Appl Surf Sci , 2009, 255(9), 4725-4732 doi: 10.1016/j.apsusc.2008.07.139
48
Zulfikar M A, Mohammad A W, Hilal N. Preparation and characterization of novel porous PMMA-SiO2 hybrid membranes. Desalination , 2006, 192: 262-270 doi: 10.1016/j.desal.2005.09.022
49
Merkel T C, Freeman B D, Spontak R J, He Z, Pinnau I, Meakin P, Hill A J. Ultrapermeable, reverse-selective nanocomposite membranes. Science , 2002, 296: 519-522 doi: 10.1126/science.1069580
50
Moaddeb M, Koros W J. Gas transport properties of thin polymeric membranes in the presence of silicon dioxide particles. J Membr Sci , 1997, 125: 143-163 doi: 10.1016/S0376-7388(96)00251-7
51
Hibshman C, Cornelius C J, Marand E. The gas separation effects of annealing polyimide-organosilicate hybrid membranes. J Membr Sci , 2003, 211: 25-40 doi: 10.1016/S0376-7388(02)00306-X
Merkel T C, He Z, Pinnau I, Freeman B D, Hill A J, Meakin P. Sorption and transport in poly(2,2-bis(trifluoromethyl)-4,5-difluoro-1,3-dioxole-cotetrafluoroethylene) containing nanoscale fumed silica. Macromolecules , 2003, 36: 8406-8484 doi: 10.1021/ma034975q
54
Winberg P, DeSitter K, Dotremont C, Mullens S, Vankelecom I F J, Maurer F H J. Free volume and interstitial mesopores in silica filled poly(1-trimethylsilyl-1-propyen) nanocomposites. Macromolecules , 2005, 38: 3776-3782 doi: 10.1021/ma047369j
55
Kim J H, Lee Y M. Gas permeation properties of poly(amide-6-b-ethyleneoxide)-silica hybrid membranes. J Membr Sci , 2001, 193: 209-225 doi: 10.1016/S0376-7388(01)00514-2
56
Hu Q, Marand E, Dhingra S, Fritsch D, Wen J, Wilkes G. Poly(amideimide)/TiO2 nano-composite gas separation membranes: fabrication and characterization. J Membr Sci , 1997, 135: 65-79 doi: 10.1016/S0376-7388(97)00120-8
57
Cong H L, Radosz M, Towler B F, Shen Y Q. Polymer-inorganic nanocomposite membranes for gas separation. Sep Purif Technol , 2007, 55: 281-291 doi: 10.1016/j.seppur.2006.12.017
58
Lu Y, Yu S L, Chai B X. Preparation of poly(vinylidene fluoride) (pvdf) ultrafiltration membrane modified by nano-sized alumina (Al2O3) and its antifouling research. Polymer , 2005, 46: 7701-7706 doi: 10.1016/j.polymer.2005.05.155
59
Yang Y N, Zhang H X, Wang P, Zheng Q Z, Li J. The influence of nano-sized TiO2 fillers on the morphologies and properties of PSF UF membrane. J Membr Sci , 2007, 288: 231-238 doi: 10.1016/j.memsci.2006.11.019
60
Bae T H, Tak T M. Preparation of TiO2 self-assembled polymeric nanocomposite membranes and examination of their fouling mitigation effects in a membrane bioreactor system. J Membr Sci , 2005, 266: 1-5 doi: 10.1016/j.memsci.2005.08.014
61
Yuan H K, Xu Z L, Shi J H, Ma X H. Perfluorosulfonic acid-tetraethoxysilane/polyacrylonitrile (PFSA-TEOS/PAN) hollow fiber composite membranes prepared for pervaporation dehydration of ethyl acetate-water solutions. J Appl Polym Sci , 2008, 109: 4025-4035 doi: 10.1002/app.28500
62
Lang W Z, Xu Z L, Yang H, Tong W. Preparation and characterization of PVDF-PFSA blend hollow fiber UF membrane. J Membr Sci , 2007, 288: 123-131 doi: 10.1016/j.memsci.2006.11.009
63
Aerts P, Greenberg A R, Leysen R, Krantz W B, Reinsch V E, Jacobs P A. The influence of filler concentration on the compaction and filtration properties of zirfon-composite ultrafiltration membranes. Sep Purif Technol , 2001, 22–23: 663-669 doi: 10.1016/S1383-5866(00)00165-9
64
Bottino A, Capannelli G, Asti V D. Preparation and properties of novel organic-inorganic porous membranes. Sep Purif Technol , 2001, 22-23: 269-275 doi: 10.1016/S1383-5866(00)00127-1
65
Bottino A, Capannelli G, Comite A. Preparation and characterization of novel porous PVDF-ZrO2 composite membranes. Desalination , 2002, 146: 35-40 doi: 10.1016/S0011-9164(02)00469-1
66
Lin D J, Chang C L, Huang F M, Cheng L P. Effect of salt additive on the formation of microporous poly(vinylidene fluoride) membranes by phase inversion from LiClO4/water/DMF/PVDF system. Polymer , 2003, 44: 413-422 doi: 10.1016/S0032-3861(02)00731-0
67
Yang Y N, Wu J, Zheng Q Z, Chen X S, Zhang H X. The research of rheology and thermodynamics of organic-inorganic hybrid membrane during the membrane formation. J Membr Sci , 2008, 311: 200-207 doi: 10.1016/j.memsci.2007.12.014
68
Bottino A, Capannelli G, Comite A. Preparation and characterization of novel porous PVDF-ZrO2 composite membranes. Desalination , 2002, 146: 35-40 doi: 10.1016/S0011-9164(02)00469-1
69
Yang Y N, Wang P, Zheng Q Z. Preparation and properties of polysulfone/TiO2 composite ultrafiltration membranes. J Polym Sci Part B: Polym Phys , 2006, 44: 879-887 doi: 10.1002/polb.20715
70
Lee H S, Im S J, Kim J H, Kim H J, Kim J P, Min B R. Polyamide thin-film nanofiltration membranes containing TiO2 nanoparticles. Desalination , 2008, 219: 48-56 doi: 10.1016/j.desal.2007.06.003
71
Chang C L, Chang M S. Preparation of multi-layer silicone/PVDF composite membranes for pervaporation of ethanol aqueous solutions. J Membr Sci , 2004, 238: 117-122 doi: 10.1016/j.memsci.2004.03.026
72
Sairam M, Patil M B, Veerapur R S, Patil S A, Aminabhavi T M. Novel dense poly(vinyl alcohol)-TiO2 mixed matrix membranes for pervaporation separation of water-isopropanol mixtures at 30°C. J Membr Sci , 2006, 281: 95-102 doi: 10.1016/j.memsci.2006.03.022
73
Chen J H, Liu Q L, Fang J, Zhu A M, Zhang Q G. Composite hybrid membrane of chitosan-silica in pervaporation separation of MeOH/DMC mixtures. J Colloid Interf Sci , 2007, 316: 580-588 doi: 10.1016/j.jcis.2007.09.022
74
Veerapur R S, Patil M B, Gudasi K B, Aminabhavi T M. Poly(vinyl alcohol)-zeolite T mixed matrix composite membranes for pervaporation separation of water+ 1,4-dioxane mixtures. Sep Purif Technol . 2008, 58: 377-385 doi: 10.1016/j.seppur.2007.05.015
75
Wang Y B, Yang D, Zheng X H, Jiang Z Y, Li J. Zeolite beta-filled chitosan membrane with low methanol permeability for direct methanol fuel cell. J Power Sources , 2008, 183: 454-463 doi: 10.1016/j.jpowsour.2008.06.003
76
Navarra M A, Abbati C, Scrosati B. Properties and fuel cell performance of a Nafion-based, sulfated zirconia-added, composite membrane. J Power Sources , 2008, 183: 109-113 doi: 10.1016/j.jpowsour.2008.04.033
77
Xu T W. Ion exchange membranes: State of their development and perspective. J Membr Sci , 2005, 263: 1-29 doi: 10.1016/j.memsci.2005.05.002
78
Mahendran. Filtration membrane with calcined alpha-alumina particles therein. United States Patent, US 5914039