Selective catalytic reduction (SCR) is a major commercial technology for NOx removal in power plants. There are a lot of complex chemical reactions in SCR reactors, and it is of great significance to understand the internal process of chemical reactions for SCR DeNOx and study the impact of various factors on NOx removal efficiency. In this paper, the impact of reaction temperature, ammonia-nitrogen molar ratio and resident time in the catalyst bed layer on NOx removal efficiency were studied by simulation of chemical reactions. Then calculated results were compared with catalyst activity test data in a power plant, which proved that the simulated results were accurate. As a result, the reaction conditions were optimized in order to get the best removal efficiency of NO, so that we can provide a reference for optimal running of SCR in power plants.
. Numerical simulation and experimental verification of chemical reactions for SCR DeNOx[J]. Frontiers of Chemical Engineering in China, 2010, 4(4): 523-528.
Qiang ZHANG, Yonglin FAN, Wenyan LI. Numerical simulation and experimental verification of chemical reactions for SCR DeNOx. Front Chem Eng Chin, 2010, 4(4): 523-528.
Zhang Q. Coal Fired Power Plants SCR Nitrogen Oxides Control and Removal. Beijing: Chemical Industry Press, 2007, 16-20 (in Chinese)
2
Sun K Q, Zhong Q. Flue Gas DeNOx Technology and Engineering Applications in Thermal Power Plant. Beijing: Chemical Industry Press, 2007, 18-19 (in Chinese)
3
Hao J M, Ma G D. Air Pollution Control Engineering. Beijing: Higher Education Press, 2002, 209-210 (in Chinese)
4
Tronconi E. Interaction between chemical kinetics and transport phenomena in monolithic catalysts. Catalysis Today , 1997, 34(3-4): 421-427 doi: 10.1016/S0920-5861(96)00064-8
5
Tronconi E. The role of inter-and intra-phase mass transfer in the SCR-DeNOx reaction over catalysts of different shapes. Catalysis Today , 1999, 52(2-3): 249-258 doi: 10.1016/S0920-5861(99)00079-6
6
Busca G, Lietti L, Ramis G, Berti F. Chemical and mechanistic aspects of the selective catalytic reduction of NOx by ammonia over oxide catalysts: a review. Applied Catalysis B: Environmental , 1998, 18(1-2): 1-36 doi: 10.1016/S0926-3373(98)00040-X
7
Lietti L, Nova I, Tronconi E, Forzatti P. Transient kinetic study of the SCR-DeNOx reaction. Catalysis Today , 1998, 45(1-4): 85-92 doi: 10.1016/S0920-5861(98)00253-3
8
Nova I, Lietti L, Tronconi E, Forzatti P. Dynamics of SCR reaction over a TiO2-supported vanadia-tungsta commercial catalyst. Catalysis Today , 2000, 60(1-2): 73-82 doi: 10.1016/S0920-5861(00)00319-9
9
Tronconi E, Lietti L, Forzatti P, Malloggi S. Experimental and theoretical investigation of the dynamics of the SCR-DeNOx reaction. Chemical Engineering Science , 1996, 51(11): 2965-2970 doi: 10.1016/0009-2509(96)00182-0
10
Nova I, Lietti L, Tronconi E, Forzatti P. Transient response method applied to the kinetic analysis of the DeNOx-SCR reaction. Chemical Engineering Science , 2001, 56(4): 1229-1237 doi: 10.1016/S0009-2509(00)00344-4