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Frontiers of Chemical Science and Engineering

ISSN 2095-0179

ISSN 2095-0187(Online)

CN 11-5981/TQ

邮发代号 80-969

2019 Impact Factor: 3.552

Frontiers of Chemical Engineering in China  2010, Vol. 4 Issue (4): 472-475   https://doi.org/10.1007/s11705-010-0525-6
  RESEARCH ARTICLE 本期目录
Synthesis of methanol and ethanol over CuZnAl slurry catalyst prepared by complete liquid-phase technology
Synthesis of methanol and ethanol over CuZnAl slurry catalyst prepared by complete liquid-phase technology
Wei HUANG(), Linmei YU, Wenhui LI, Zhili MA
Key Laboratory of Coal Science and Technology(Ministry of Education and Shanxi Province), Taiyuan University of Technology, Taiyuan 030024, China
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Abstract

A new method, named the complete liquid-phase technology, has been applied to prepare catalysts for methanol synthesis. Its main innovative thought lies in preparing slurry catalysts directly from raw solution. Activity tests indicate that the CuZnAl slurry catalyst prepared by the new method can efficiently catalyze conversion of syngas to ethanol in a slurry reactor, while CO conversion reaches 35.9% and ethanol selectivity is more than 20%, with a total alcohol selectivity of more than 87%. No deactivation was found during the 192 h reaction .

Key wordsmethanol    slurry    ethanol    complete liquid-phase technology    CuZnAl catalyst
收稿日期: 2010-04-18      出版日期: 2010-12-05
Corresponding Author(s): HUANG Wei,Email:huangwei@tyut.edu.cn   
 引用本文:   
. Synthesis of methanol and ethanol over CuZnAl slurry catalyst prepared by complete liquid-phase technology[J]. Frontiers of Chemical Engineering in China, 2010, 4(4): 472-475.
Wei HUANG, Linmei YU, Wenhui LI, Zhili MA. Synthesis of methanol and ethanol over CuZnAl slurry catalyst prepared by complete liquid-phase technology. Front Chem Eng Chin, 2010, 4(4): 472-475.
 链接本文:  
https://academic.hep.com.cn/fcse/CN/10.1007/s11705-010-0525-6
https://academic.hep.com.cn/fcse/CN/Y2010/V4/I4/472
catalystspecific surface area /(m2·g-1)Pore specific volume /(cm3·g-1)average pore diameter /nm
before reduction41.390.08231.66
after reaction62.460.16130.93
Tab.1  
Fig.1  
Fig.2  
Fig.3  
Fig.4  
Fig.5  
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