Please wait a minute...
Frontiers of Chemical Science and Engineering

ISSN 2095-0179

ISSN 2095-0187(Online)

CN 11-5981/TQ

邮发代号 80-969

2019 Impact Factor: 3.552

Frontiers of Chemical Science and Engineering  2011, Vol. 5 Issue (1): 74-78   https://doi.org/10.1007/s11705-010-0542-5
  RESEARCH ARTICLE 本期目录
Synthesis of poly(maleic acid alkylamide-co-α-olefin-co-styrene) and their effect on flow ability of oils
Synthesis of poly(maleic acid alkylamide-co-α-olefin-co-styrene) and their effect on flow ability of oils
Jingjing XU1, Jun XU1(), Jie SUN2, Shili XING1, Li LI1, Xuhong GUO1
1. State Key Laboratory of Chemical Engineering, East China University of Science and Technology, Shanghai 200237, China; 2. Institute of Chemical Materials, China Academy of Engineering Physics, Sichuan 621900, China
 全文: PDF(367 KB)   HTML
Abstract

To improve the flow ability of crude oil with high content of aromatic asphaltenes, new comb-type copolymers of poly(maleic anhydride-co-α-olefin-co-styrene) (MASCs) with different ratios of maleic anhydride (MA) to styrene were designed and synthesized. 1H NMR and FTIR spectra were used to characterize the chemical structure of the copolymers. The effect of copolymers on the flow ability of model waxy oil and crude oil were studied by rheological method and polarizing light microscopy. Upon the addition of MASCs, the yield stresses of oils were decreased by 1 to 3 orders of magnitude, and the morphology of paraffin crystals were reduced and changed from plates to needles.

Key wordscomb-polymers    styrene    paraffin    crystallization    flow ability
收稿日期: 2010-03-10      出版日期: 2011-03-05
Corresponding Author(s): XU Jun,Email:wiselyxj@126.com   
 引用本文:   
. Synthesis of poly(maleic acid alkylamide-co-α-olefin-co-styrene) and their effect on flow ability of oils[J]. Frontiers of Chemical Science and Engineering, 2011, 5(1): 74-78.
Jingjing XU, Jun XU, Jie SUN, Shili XING, Li LI, Xuhong GUO. Synthesis of poly(maleic acid alkylamide-co-α-olefin-co-styrene) and their effect on flow ability of oils. Front Chem Sci Eng, 2011, 5(1): 74-78.
 链接本文:  
https://academic.hep.com.cn/fcse/CN/10.1007/s11705-010-0542-5
https://academic.hep.com.cn/fcse/CN/Y2011/V5/I1/74
Fig.1  
samplemolecular weights /(kg·mol-1)
MASC0.516.9
MASC0.7524.4
MASC1.021.9
Tab.1  
Fig.2  
Fig.3  
Fig.4  
Fig.5  
Fig.6  
Fig.7  
1 Tinsley J F, Prud’homme R K, Guo X, Adamson D H, Callahan S, Amin D, Shao S, Kriegel R M, Saini R. Novel laboratory cell for fundamental studies of the effect of polymer additives on wax deposition from model crude oils. Energy & Fuels , 2007, 21(3): 1301–1308
doi: 10.1021/ef060446m
2 García M C, Carbognani L, Lante C. Asphaltene-paraffin structural interactions: effect on crude oil stability. Energy & Fuels , 2001, 15(5): 1021–1027
doi: 10.1021/ef0100303
3 Guo X, Pethica B A, Huang J S, Prud’homme R K, Adamson D H, Fetters L J. Crystallization of mixed paraffin from model waxy oil and the influence of micro-crystalline poly(ethylene-butene) random copolymers. Energy & Fuels , 2004, 18(4): 930–937
doi: 10.1021/ef034098p
4 Guo X H, Prud’homme R K. Synthesis of comb polymers based on poly(maleic anhydride-co-α-olefin) and their influence on paraffin crystallization. Papers Presented at the Meeting. American Chemical Society. Division of Polymer Chemistry , 2005, 46(2): 1051
5 Guo X, Pethica B A, Huang J S, Prud’homme R K. Crystallization of long chain n-paraffins from solutions and melt as observed by differential scanning calorimetry. Macromolecules , 2004, 37(15): 5628–5645
doi: 10.1021/ma035848x
6 Probjot S, Ramachandran V, Scott Fogler H, Nagarajan N R. Morphological evolution of thick wax deposits during aging. Fluid Mechanics and Transport Phenomena , 2001, 47: 6–18
7 Ashbaugh H S, Fetters L J, Adamson D H, Prud’homme R K. Flow imoprovment of waxy oils mediated by self-aggregating partially crystallizable diblock copolymers. Journal of Rheology , 2002, 46(4): 763–776
doi: 10.1122/1.1485280
8 Paso K G, Fogler H S. Bulk stabilization in wax deposition systems. Energy & Fuels , 2004, 18(4): 1005–1013
doi: 10.1021/ef034105+
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed