Calculation on phase diagrams of polyetherimide/ N,N-dimethylacetamide/H2O-BuOH casting system and their relevance to membrane performances
Ming TAN1,2,Gaohong HE1,*(),Yan DAI1,Rujie WANG1,Wenhua SHI1
1. State Key Laboratory of Fine Chemicals, R&D Center of Membrane Science and Technology, School of Chemical Engineering, Dalian University of Technology, Dalian 116024, China 2. Key Laboratory of Biobased Materials, Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao 266101, China
The ternary phase diagrams of polyetherimide (PEI)/N,N-dimethylacetamide (DMAc) with H2O and BuOH as non-solvent were simulated using solubility parameter and Flory-Huggins theory. The phase diagrams show that 5.5% H2O/BuOH system containing 5% BuOH and 0.5% H2O, or 6.5% H2O/BuOH system containing 6.2% BuOH and 0.3% H2O is required to induce liquid-liquid demixing for 20 wt-% PEI/DMAc casting solution. Therefore, BuOH can enhance the phase separation of the PEI casting solution and hereby induce higher porosity of the membrane, and the diffusion of BuOH into the water coagulation bath causes larger pore size easily compared with DMAc. Our predictions that the membrane pure water flux first increases then decreases, and the rejection ratio of bovine serum albumin decreases with the increasing concentration of BuOH were validated by the experiments using the prepared membranes.
. [J]. Frontiers of Chemical Science and Engineering, 2014, 8(3): 312-319.
Ming TAN,Gaohong HE,Yan DAI,Rujie WANG,Wenhua SHI. Calculation on phase diagrams of polyetherimide/ N,N-dimethylacetamide/H2O-BuOH casting system and their relevance to membrane performances. Front. Chem. Sci. Eng., 2014, 8(3): 312-319.
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