Advantageous mechanochemical synthesis of copper(I) selenide semiconductor, characterization, and properties
Katarína Gáborová1,2, Marcela Achimovičová1(), Michal Hegedüs3, Vladimír Girman4, Mária Kaňuchová5, Erika Dutková1
1. Institute of Geotechnics, Slovak Academy of Sciences, Košice 04001, Slovakia 2. Institute of Metallurgy, Faculty of Materials, Metallurgy and Recycling, Technical University, Košice 04201, Slovakia 3. Synthon, s.r.o., Blansko 67801, Czech Republic 4. Faculty of Science, Pavol Jozef Šafárik University, Košice 04154, Slovakia 5. Institute of Earth Resources, Faculty of Mining, Ecology, Process Control and Geotechnologies, Technical University, Košice 04200, Slovakia
Copper(I) selenide-nanocrystalline semiconductor was synthesized via one-step mechanochemical synthesis after 5 min milling in a planetary ball mill. The kinetics of synthesis was followed by X-ray powder diffraction analysis and specific surface area measurements of milled 2Cu/Se mixtures. The X-ray diffraction confirmed the orthorhombic crystal structure of Cu2Se with the crystallite size ~25 nm. The surface chemical structure was studied by X-ray photoelectron spectroscopy, whereby the binding energy of the Cu 2p and Se 3d signals corresponded to Cu+ and Se2– oxidation states. Transmission electron microscopy revealed agglomerated nanocrystals and confirmed their orthorhombic structure, as well. The optical properties were studied utilizing ultraviolet-visible spectroscopy and photoluminescence spectroscopy. The direct bandgap energy 3.7 eV indicated a blue-shift phenomenon due to the quantum size effect. This type of Cu2Se synthesis can be easily adapted to production dimensions using an industrial vibratory mill. The advantages of mechanochemical synthesis represent the potential for inexpensive, environmentally-friendly, and waste-free manufacturing of Cu2Se.
. [J]. Frontiers of Chemical Science and Engineering, 2022, 16(3): 433-442.
Katarína Gáborová, Marcela Achimovičová, Michal Hegedüs, Vladimír Girman, Mária Kaňuchová, Erika Dutková. Advantageous mechanochemical synthesis of copper(I) selenide semiconductor, characterization, and properties. Front. Chem. Sci. Eng., 2022, 16(3): 433-442.
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