Conversion of CO into CO2 by high active and stable PdNi nanoparticles supported on a metal-organic framework
Fateme Abbasi1, Javad Karimi-Sabet2(), Zeinab Abbasi1, Cyrus Ghotbi1
1. Department of Petroleum and Chemical Engineering, Sharif University of Technology, Tehran, Iran 2. Nuclear Fuel Cycle Research School, Nuclear Science and Technology Research Institute, Tehran, Iran
The solubility of Pd(NO3)2 in water is moderate whereas it is completely soluble in diluted HNO3 solution. Pd/MIL-101(Cr) and Pd/MIL-101-NH2(Cr) were synthesized by aqueous solution of Pd(NO3)2 and Pd(NO3)2 solution in dilute HNO3 and used for CO oxidation reaction. The catalysts synthesized with Pd(NO3)2 solution in dilute HNO3 showed lower activity. The aqueous solution of Pd(NO3)2 was used for synthesis of mono-metal Ni, Pd and bimetallic PdNi nanoparticles with various molar ratios supported on MOF. Pd70Ni30/MIL-101(Cr) catalyst showed higher activity than monometallic counterparts and Pd+ Ni physical mixture due to the strong synergistic effect of PdNi nanoparticles, high distribution of PdNi nanoparticles, and lower dissociation and desorption barriers. Comparison of the catalysts synthesized by MIL-101(Cr) and MIL-101-NH2(Cr) as the supports of metals showed that Pd/MIL-101-NH2(Cr) outperforms Pd/MIL-101-(Cr) because of the higher electron density of Pd resulting from the electron donor ability of the NH2 functional group. However, the same activities were observed for Pd70Ni30/MIL-101(Cr) and Pd70Ni30/MIL-101-NH2(Cr), which is due to a less uniform distribution of Pd nanoparticles in Pd70Ni30/MIL-101-NH2(Cr) originated from amorphization of MIL-101-NH2(Cr) structure during the reduction process. In contrast, Pd70Ni30/MIL-101(Cr) revealed the stable structure and activity during reduction and CO oxidation for a long time.
. [J]. Frontiers of Chemical Science and Engineering, 2022, 16(7): 1139-1148.
Fateme Abbasi, Javad Karimi-Sabet, Zeinab Abbasi, Cyrus Ghotbi. Conversion of CO into CO2 by high active and stable PdNi nanoparticles supported on a metal-organic framework. Front. Chem. Sci. Eng., 2022, 16(7): 1139-1148.
K Talha, B Wang, J H Liu, R Ullah, F Feng, J Yu, S Chen, J R Li. Effective adsorption of metronidazole antibiotic from water with a stable Zr(IV)-MOFs: insights from DFT, kinetics and thermodynamics studies. Journal of Environmental Chemical Engineering, 2020, 8(1): 103642 https://doi.org/10.1016/j.jece.2019.103642
2
J R Li, Y Tao, Q Yu, X H Bu, H Sakamoto, S Kitagawa. Selective gas adsorption and unique structural topology of a highly stable guest-free zeolite-type MOF material with N-rich chiral open channels. Chemistry (Weinheim an der Bergstrasse, Germany), 2008, 14(9): 2771–2776 https://doi.org/10.1002/chem.200701447
3
X Zhao, Y Wang, D S Li, X Bu, P Feng. Metal-organic frameworks for separation. Advanced Materials, 2018, 30(37): 1705189 https://doi.org/10.1002/adma.201705189
4
S Zhang, X Li, B Ding, H Li, X Liu, Q Xu. A novel spitball-like Co3(NO3)2(OH)4@ Zr-MOF@ RGO anode material for sodium-ion storage. Journal of Alloys and Compounds, 2020, 822: 153624 https://doi.org/10.1016/j.jallcom.2019.153624
5
S Proch, J Herrmannsdörfer, R Kempe, C Kern, A Jess, L Seyfarth, J Senker. Pt@ MOF-177: synthesis, room-temperature hydrogen storage and oxidation catalysis. Chemistry (Weinheim an der Bergstrasse, Germany), 2008, 14(27): 8204–8212 https://doi.org/10.1002/chem.200801043
6
P Horcajada, C Serre, M Vallet-Regí, M Sebban, F Taulelle, G Férey. Metal-organic frameworks as efficient materials for drug delivery. Angewandte Chemie International Edition, 2006, 45(36): 5974–5978 https://doi.org/10.1002/anie.200601878
7
X Fang, B Zong, S Mao. Metal-organic framework-based sensors for environmental contaminant sensing. Nano-Micro Letters, 2018, 10(4): 64 https://doi.org/10.1007/s40820-018-0218-0
8
C V Reddy, K R Reddy, V Harish, J Shim, M Shankar, N P Shetti, T M Aminabhavi. Metal-organic frameworks (MOFs)-based efficient heterogeneous photocatalysts: synthesis, properties and its applications in photocatalytic hydrogen generation, CO2 reduction and photodegradation of organic dyes. International Journal of Hydrogen Energy, 2020, 45(13): 7656–7679 https://doi.org/10.1016/j.ijhydene.2019.02.144
9
E Dhivya, D Magadevan, Y Palguna, T Mishra, N Aman. Synthesis of titanium based hetero MOF photocatalyst for reduction of Cr(VI) from wastewater. Journal of Environmental Chemical Engineering, 2019, 7(4): 103240 https://doi.org/10.1016/j.jece.2019.103240
10
M Zhang, B Huang, H Jiang, Y Chen. Metal-organic framework loaded manganese oxides as efficient catalysts for low-temperature selective catalytic reduction of NO with NH3. Frontiers of Chemical Science and Engineering, 2017, 11(4): 594–602 https://doi.org/10.1007/s11705-017-1668-5
11
F Abbasi, J Karimi-Sabet, C Ghotbi. Reactivity and characteristics of Pd/MOF and Pd/calcinated-MOF catalysts for CO oxidation reaction: effect of oxygen and hydrogen. International Journal of Hydrogen Energy, 2021, 46(24): 12822–12834 https://doi.org/10.1016/j.ijhydene.2021.01.237
12
F Abbasi, J Karimi-Sabet, C Ghotbi. Efficient CO oxidation over palladium supported on various MOFs: synthesis, amorphization, and space velocity of hydrogen stream. International Journal of Hydrogen Energy, 2020, 45(41): 21450–21463 https://doi.org/10.1016/j.ijhydene.2020.05.223
13
E Rahmani, M Rahmani. Catalytic process modeling and sensitivity analysis of alkylation of benzene with ethanol over MIL-101 (Fe) and MIL-88 (Fe). Frontiers of Chemical Science and Engineering, 2020, 14(6): 1100–1111 https://doi.org/10.1007/s11705-019-1891-3
14
Y Hu, S Zheng, F Zhang. Fabrication of MIL-100 (Fe)@ SiO2@ Fe3O4 core-shell microspheres as a magnetically recyclable solid acidic catalyst for the acetalization of benzaldehyde and glycol. Frontiers of Chemical Science and Engineering, 2016, 10(4): 534–541 https://doi.org/10.1007/s11705-016-1596-9
15
W G Cui, T L Hu. Incorporation of active metal species in crystalline porous materials for highly efficient synergetic catalysis. Small, 2021, 17(22): 2003971 https://doi.org/10.1002/smll.202003971
16
A Aijaz, Q Xu. Catalysis with metal nanoparticles immobilized within the pores of metal-organic frameworks. Journal of Physical Chemistry Letters, 2014, 5(8): 1400–1411 https://doi.org/10.1021/jz5004044
17
J Y Ye, C J Liu. Cu3(BTC)2: CO oxidation over MOF based catalysts. Chemical Communications, 2011, 47(7): 2167–2169 https://doi.org/10.1039/c0cc04944a
A Aijaz, A Karkamkar, Y J Choi, N Tsumori, E Rönnebro, T Autrey, H Shioyama, Q Xu. Immobilizing highly catalytically active Pt nanoparticles inside the pores of metal-organic framework: a double solvents approach. Journal of the American Chemical Society, 2012, 134(34): 13926–13929 https://doi.org/10.1021/ja3043905
20
E V Ramos-Fernandez, C Pieters, B van der Linden, J Juan-Alcañiz, P Serra-Crespo, M Verhoeven, H Niemantsverdriet, J Gascon, F Kapteijn. Highly dispersed platinum in metal organic framework NH2-MIL-101 (Al) containing phosphotungstic acid—characterization and catalytic performance. Journal of Catalysis, 2012, 289: 42–52 https://doi.org/10.1016/j.jcat.2012.01.013
21
M S El-Shall, V Abdelsayed, S K Abd El Rahman, H M Hassan, H M El-Kaderi, T E Reich. Metallic and bimetallic nanocatalysts incorporated into highly porous coordination polymer MIL-101. Journal of Materials Chemistry, 2009, 19(41): 7625–7631 https://doi.org/10.1039/b912012b
22
Z M El-Bahy, A I Hanafy, S M El-Bahy. Preparation of Pt, Pd and Cu nano single and bimetallic systems-supported NaY zeolite and test their activity in p-nitrophenol reduction and as anticancer agents. Journal of Environmental Chemical Engineering, 2019, 7(3): 103117 https://doi.org/10.1016/j.jece.2019.103117
23
N Cao, L Yang, H Dai, T Liu, J Su, X Wu, W Luo, G Cheng. Immobilization of ultrafine bimetallic Ni-Pt nanoparticles inside the pores of metal-organic frameworks as efficient catalysts for dehydrogenation of alkaline solution of hydrazine. Inorganic Chemistry, 2014, 53(19): 10122–10128 https://doi.org/10.1021/ic5010352
24
C Menghuan, L Zhou, L Di, L Yue, N Honghui, P Yaxi, X Hongkun, P Weiwei, Z Shuren. RuCo bimetallic alloy nanoparticles immobilized on multi-porous MIL-53(Al) as a highly efficient catalyst for the hydrolytic reaction of ammonia borane. International Journal of Hydrogen Energy, 2018, 43(3): 1439–1450 https://doi.org/10.1016/j.ijhydene.2017.11.160
25
Y Z Chen, Y X Zhou, H Wang, J Lu, T Uchida, Q Xu, S H Yu, H L Jiang. Multifunctional PdAg@ MIL-101 for one-pot cascade reactions: combination of host-guest cooperation and bimetallic synergy in catalysis. ACS Catalysis, 2015, 5(4): 2062–2069 https://doi.org/10.1021/cs501953d
26
N Z Shang, C Feng, S T Gao, C Wang. Ag/Pd nanoparticles supported on amine-functionalized metal-organic framework for catalytic hydrolysis of ammonia borane. International Journal of Hydrogen Energy, 2016, 41(2): 944–950 https://doi.org/10.1016/j.ijhydene.2015.10.062
27
G Francisco, A L P Cirujano, C Avelino. Xamena FXLI. MOFs as multifunctional catalysts: synthesis of secondary aylamines, quinolines, pyrroles, and arylpyrrolidines over bifunctional MIL-101. ChemCatChem, 2013, 5(2): 538–549 https://doi.org/10.1002/cctc.201200878
28
Y Huang, Z Lin, R Cao. Palladium nanoparticles encapsulated in a metal-organic framework as efficient heterogeneous catalysts for direct C2 arylation of indoles. Chemistry (Weinheim an der Bergstrasse, Germany), 2011, 17(45): 12706–12712 https://doi.org/10.1002/chem.201101705
29
Q Liang, Z Zhao, J Liu, Y C Wei, G Y Jiang, A J Duan. Pd nanoparticles deposited on metal-organic framework of MIL-53(Al) an active catalyst for CO oxidation. Acta Physico-Chimica Sinica, 2014, 30(1): 129–134 https://doi.org/10.3866/PKU.WHXB201311201
30
P Liu, X Gu, Y Wu, J Cheng, H Su. Construction of bimetallic nanoparticles immobilized by porous functionalized metal-organic frameworks toward remarkably enhanced catalytic activity for the room-temperature complete conversion of hydrous hydrazine into hydrogen. International Journal of Hydrogen Energy, 2017, 42(30): 19096–19105 https://doi.org/10.1016/j.ijhydene.2017.06.191
Z Wang, J Yu, R Xu. Needs and trends in rational synthesis of zeolitic materials. Chemical Society Reviews, 2012, 41(5): 1729–1741 https://doi.org/10.1039/C1CS15150A
33
X Gu, Z H Lu, H L Jiang, T Akita, Q Xu. Synergistic catalysis of metal–organic framework-immobilized Au-Pd nanoparticles in dehydrogenation of formic acid for chemical hydrogen storage. Journal of the American Chemical Society, 2011, 133(31): 11822–11825 https://doi.org/10.1021/ja200122f
34
G Férey, C Mellot-Draznieks, C Serre, F Millange, J Dutour, S Surblé, I Margiolaki. A chromium terephthalate-based solid with unusually large pore volumes and surface area. Science, 2005, 309(5743): 2040–2042 https://doi.org/10.1126/science.1116275
35
M Wen, K Mori, T Kamegawa, H Yamashita. Amine-functionalized MIL-101(Cr) with imbedded platinum nanoparticles as a durable photocatalyst for hydrogen production from water. Chemical Communications, 2014, 50(79): 11645–11648 https://doi.org/10.1039/C4CC02994A
36
Y Zhai, N Li, L Lei, X Yang, H Zhang. Dispersive micro-solid-phase extraction of hormones in liquid cosmetics with metal-organic framework. Analytical Methods, 2014, 6(23): 9435–9445 https://doi.org/10.1039/C4AY01763C
37
H Li, Z Zhu, F Zhang, S Xie, H Li, P Li, X Zhou. Palladium nanoparticles confined in the cages of MIL-101: an efficient catalyst for the one-pot indole synthesis in water. ACS Catalysis, 2011, 1(11): 1604–1612 https://doi.org/10.1021/cs200351p
38
M Yurderi, A Bulut, M Zahmakiran, M Gülcan, S Özkar. Ruthenium (0) nanoparticles stabilized by metal-organic framework (ZIF-8): highly efficient catalyst for the dehydrogenation of dimethylamine-borane and transfer hydrogenation of unsaturated hydrocarbons using dimethylamine-borane as hydrogen source. Applied Catalysis B: Environmental, 2014, 160: 534–541 https://doi.org/10.1016/j.apcatb.2014.06.009
39
L T M Nguyen, H Park, M Banu, J Y Kim, D H Youn, G Magesh, W Y Kim, J S Lee. Catalytic CO2 hydrogenation to formic acid over carbon nanotube-graphene supported PdNi alloy catalysts. RSC Advances, 2015, 5(128): 105560–105566 https://doi.org/10.1039/C5RA21017H
40
S Jiang, B Yi, Q Zhao, H Yu, Z Shao. Palladium-nickel catalysts based on ordered titanium dioxide nanorod arrays with high catalytic peformance for formic acid electro-oxidation. RSC Advances, 2017, 7(19): 11719–11723 https://doi.org/10.1039/C7RA00194K
41
Z H Lu, J Li, G Feng, Q Yao, F Zhang, R Zhou, D Tao, X Chen, Z Yu. Synergistic catalysis of MCM-41 immobilized Cu-Ni nanoparticles in hydrolytic dehydrogeneration of ammonia borane. International Journal of Hydrogen Energy, 2014, 39(25): 13389–13395 https://doi.org/10.1016/j.ijhydene.2014.04.086
