Integrating of metal-organic framework UiO-66-NH2 and cellulose nanofibers mat for high-performance adsorption of dye rose bengal
Yuyao Han1,2, Lei Xia1,2(), Xupin Zhuang1,2, Yuxia Liang3
1. State Key Laboratory of Separation Membranes and Membrane Processes, National Center for International Joint Research on Separation Membranes, Tiangong University, Tianjin 300387, China 2. School of Textile Science and Engineering, Tiangong University, Tianjin 300387, China 3. School of Mathematical Sciences, Tianjin Normal University, Tianjin 300387, China
UiO-66-NH2 is an efficient material for removing pollutants from wastewater due to its high specific surface area, high porosity and water stability. However, recycling them from wastewater is difficult. In this study, the cellulose nanofibers mat deacetylated from cellulose acetate nanofibers were used to combine with UiO-66-NH2 by the method of in-situ growth to remove the toxic dye, rose bengal. Compared to previous work, the prepared composite could not only provide ease of separation of UiO-66-NH2 from the water after adsorption but also demonstrate better adsorption capacity (683 mg∙g‒1 (T = 25 °C, pH = 3)) than that of the simple UiO-66-NH2 (309.6 mg∙g‒1 (T = 25 °C, pH = 3)). Through the analysis of adsorption kinetics and isotherms, the adsorption for rose bengal is mainly suitable for the pseudo-second-order kinetic model and Freundlich model. Furthermore, the relevant research revealed that the main adsorption mechanism of the composite was electrostatic interaction, hydrogen bonding and π–π interaction. Overall, the approach depicts an efficient model for integrating metal-organic frameworks on cellulose nanofibers to improve metal-organic framework recovery performance with potentially broad applications.
. [J]. Frontiers of Chemical Science and Engineering, 2022, 16(9): 1387-1398.
Yuyao Han, Lei Xia, Xupin Zhuang, Yuxia Liang. Integrating of metal-organic framework UiO-66-NH2 and cellulose nanofibers mat for high-performance adsorption of dye rose bengal. Front. Chem. Sci. Eng., 2022, 16(9): 1387-1398.
L W Lee, S Y Pao, A Pathak, D Y Kang, K L Lu. Membrane adsorber containing a new Sm(III)-organic framework for dye removal. Environmental Science: Nano, 2019, 6( 4): 1067– 1076 https://doi.org/10.1039/C9EN00018F
2
V K Gupta, A Mittal, D Jhare, J Mittal. Batch and bulk removal of hazardous colouring agent rose bengal by adsorption techniques using bottom ash as adsorbent. RSC Advances, 2012, 2( 22): 8381– 8389 https://doi.org/10.1039/c2ra21351f
G McMullan, C Meehan, A Conneely, N Kirby, T Robinson, P Nigam, I M Banat, R Marchant, W E Smyth. Microbial decolourisation and degradation of textile dyes. Applied Microbiology and Biotechnology, 2001, 56( 1-2): 81– 87 https://doi.org/10.1007/s002530000587
M Rafatullah, O Sulaiman, R Hashim, A Ahmad. Adsorption of methylene blue on low-cost adsorbents: a review. Journal of Hazardous Materials, 2010, 177( 1-3): 70– 80 https://doi.org/10.1016/j.jhazmat.2009.12.047
8
P Kumar, A Pournara, K H Kim, V Bansal, S Rapti, M J Manos. Metal-organic frameworks: challenges and opportunities for ion-exchange/sorption applications. Progress in Materials Science, 2017, 86 : 25– 74 https://doi.org/10.1016/j.pmatsci.2017.01.002
9
P M Schoenecker, C G Carson, H Jasuja, C J J Flemming, K S Walton. Effect of water adsorption on retention of structure and surface area of metal-organic frameworks. Industrial & Engineering Chemistry Research, 2012, 51( 18): 6513– 6519 https://doi.org/10.1021/ie202325p
10
A O Yazaydin, A I Benin, S A Faheem, P Jakubczak, J J Low, R R Willis, R Q Snurr. Enhanced CO2 adsorption in metal-organic frameworks via occupation of open-metal sites by coordinated water molecules. Chemistry of Materials, 2009, 21( 8): 1425– 1430 https://doi.org/10.1021/cm900049x
11
P Kumar, A Deep, K H Kim. Metal organic frameworks for sensing applications. Trends in Analytical Chemistry, 2015, 73 : 39– 53 https://doi.org/10.1016/j.trac.2015.04.009
12
E Haque, V Lo, A I Minett, A T Harris, T L Church. Dichotomous adsorption behaviour of dyes on an amino-functionalised metal-organic framework, amino-MIL-101(Al). Journal of Materials Chemistry A, 2014, 2( 1): 193– 203 https://doi.org/10.1039/C3TA13589F
13
H Wang, X Z Yuan, Y Wu, G M Zeng, X H Chen, L J Leng, H Li. Synthesis and applications of novel graphitic carbon nitride/metal-organic frameworks mesoporous photocatalyst for dyes removal. Applied Catalysis B: Environmental, 2015, 174 : 445– 454 https://doi.org/10.1016/j.apcatb.2015.03.037
14
J Abdi, M Vossoughi, N M Mahmoodi, I Alemzadeh. Synthesis of metal-organic framework hybrid nanocomposites based on GO and CNT with high adsorption capacity for dye removal. Chemical Engineering Journal, 2017, 326 : 1145– 1158 https://doi.org/10.1016/j.cej.2017.06.054
15
G W Peterson, D T Lee, H F Barton, T H III Epps, G N Parsons. Fibre-based composites from the integration of metal-organic frameworks and polymers. Nature Reviews Materials, 2021, 6( 7): 605– 621 https://doi.org/10.1038/s41578-021-00291-2
16
C H Wang, P Cheng, Y Y Yao, Y Yamauchi, X Yan, J S Li, J Na. In-situ fabrication of nanoarchitectured MOF filter for water purification. Journal of Hazardous Materials, 2020, 392 : 122164 https://doi.org/10.1016/j.jhazmat.2020.122164
17
Y Y Yang, W Huang, Z P Guo, S Y Zhang, F Wu, J J Huang, H J Yang, Y S Zhou, W L Xu, S J Gu. Robust fluorine-free colorful superhydrophobic PDMS/NH2-MIL-125(Ti)@cotton fabrics for improved ultraviolet resistance and efficient oil-water separation. Cellulose, 2019, 26( 17): 9335– 9348 https://doi.org/10.1007/s10570-019-02707-3
18
M J Lis, B B Caruzi, G A Gil, R B Samulewski, A Bail, F A P Scacchetti, M P Moises, F M Bezerra. In-situ direct synthesis of HKUST-1 in wool fabric for the improvement of antibacterial properties. Polymers, 2019, 11( 4): 713 https://doi.org/10.3390/polym11040713
19
L Xia, J G Ju, W Xu, C K Ding, B W Cheng. Preparation and characterization of hollow Fe2O3 ultra-fine fibers by centrifugal spinning. Materials & Design, 2016, 96 : 439– 445 https://doi.org/10.1016/j.matdes.2016.02.053
20
L Y Ren, R Ozisik, S P Kotha, P T Underhill. Highly efficient fabrication of polymer nanofiber assembly by centrifugal jet spinning: process and characterization. Macromolecules, 2015, 48( 8): 2593– 2602 https://doi.org/10.1021/acs.macromol.5b00292
21
M R Hu, Y F Wang, Z F Yan, G D Zhao, Y X Zhao, L Xia, B W Cheng, Y B Di, X P Zhuang. Hierarchical dual-nanonet of polymer nanofibers and supramolecular nanofibrils for air filtration with a high filtration efficiency, low air resistance and high moisture permeation. Journal of Materials Chemistry A, 2021, 9( 24): 14093– 14100 https://doi.org/10.1039/D1TA01505B
22
J Ru, X M Wang, F B Wang, X L Cui, X Z Du, X Q Lu. UiO series of metal-organic frameworks composites as advanced sorbents for the removal of heavy metal ions: synthesis, applications and adsorption mechanism. Ecotoxicology and Environmental Safety, 2021, 208 : 111577 https://doi.org/10.1016/j.ecoenv.2020.111577
23
V V Butova, M A Soldatov, A A Guda, K A Lomachenko, C Lamberti. Metal-organic frameworks: structure, properties, methods of synthesis and characterization. Russian Chemical Reviews, 2016, 85( 3): 280– 307 https://doi.org/10.1070/RCR4554
24
K Kalwar, L Hu, D L Li, D Shan. AgNPs incorporated on deacetylated electrospun cellulose nanofibers and their effect on the antimicrobial activity. Polymers for Advanced Technologies, 2018, 29( 1): 394– 400 https://doi.org/10.1002/pat.4127
25
M Vahidi, A Tavasoli, A M Rashidi. Preparation of amine functionalized UiO-66, mixing with aqueous N-methyldiethanolamine and application on CO2 solubility. Journal of Natural Gas Science and Engineering, 2016, 28 : 651– 659 https://doi.org/10.1016/j.jngse.2015.11.050
26
Z Hasan, N A Khan, S H Jhung. Adsorptive removal of diclofenac sodium from water with Zr-based metal-organic frameworks. Chemical Engineering Journal, 2016, 284 : 1406– 1413 https://doi.org/10.1016/j.cej.2015.08.087
27
T Hashem, A H Ibrahim, C Woll, M H Alkordi. Grafting zirconium-based metal-organic framework UiO-66-NH2 nanoparticles on cellulose fibers for the removal of Cr(VI) ions and methyl orange from water. ACS Applied Nano Materials, 2019, 2( 9): 5804– 5808 https://doi.org/10.1021/acsanm.9b01263
28
G W Peterson, A X Lu, T H III Epps. Tuning the morphology and activity of electrospun polystyrene/UiO-66-NH2 metal-organic framework composites to enhance chemical warfare agent removal. ACS Applied Materials & Interfaces, 2017, 9( 37): 32248– 32254 https://doi.org/10.1021/acsami.7b09209
29
J L Wang, X Guo. Adsorption kinetic models: physical meanings, applications, and solving methods. Journal of Hazardous Materials, 2020, 390 : 122156 https://doi.org/10.1016/j.jhazmat.2020.122156
30
S Zaboon, H R Abid, Z X Yao, R Gubner, S B Wang, A Barifcani. Removal of monoethylene glycol from wastewater by using Zr-metal organic frameworks. Journal of Colloid and Interface Science, 2018, 523 : 75– 85 https://doi.org/10.1016/j.jcis.2018.03.084
31
X Guo, J L Wang. A general kinetic model for adsorption: theoretical analysis and modeling. Journal of Molecular Liquids, 2019, 288 : 111100 https://doi.org/10.1016/j.molliq.2019.111100
N Mohammadi, H Khani, V K Gupta, E Amereh, S Agarwal. Adsorption process of methyl orange dye onto mesoporous carbon material-kinetic and thermodynamic studies. Journal of Colloid and Interface Science, 2011, 362( 2): 457– 462 https://doi.org/10.1016/j.jcis.2011.06.067
34
S Lin, Y F Zhao, Y S Yun. Highly effective removal of nonsteroidal anti-inflammatory pharmaceuticals from water by Zr(IV)-based metal- organic framework: adsorption performance and mechanisms. ACS Applied Materials & Interfaces, 2018, 10( 33): 28076– 28085 https://doi.org/10.1021/acsami.8b08596
35
Y G Peng, H L Huang, Y X Zhang, C F Kang, S M Chen, L Song, D H Liu, C L Zhong. A versatile MOF-based trap for heavy metal ion capture and dispersion. Nature Communications, 2018, 9( 1): 187 https://doi.org/10.1038/s41467-017-02600-2
36
Q Chen, Q Q He, M M Lv, Y L Xu, H B Yang, X T Liu, F Y Wei. Selective adsorption of cationic dyes by UiO-66-NH2. Applied Surface Science, 2015, 327 : 77– 85 https://doi.org/10.1016/j.apsusc.2014.11.103
37
D Q Yang, B Hennequin, E Sacher. XPS demonstration of π-π interaction between benzyl mercaptan and multiwalled carbon nanotubes and their use in the adhesion of Pt nanoparticles. Chemistry of Materials, 2006, 18( 21): 5033– 5038 https://doi.org/10.1021/cm061256s
38
H Ting, H Y Chi, C H Lam, K Y Chan, D Y Kang. High-permeance metal-organic framework-based membrane adsorber for the removal of dye molecules in aqueous phase. Environmental Science Nano, 2017, 4( 11): 2205– 2214 https://doi.org/10.1039/C7EN00639J
39
M A Ahmed, N M Abdelbar, A A Mohamed. Molecular imprinted chitosan-TiO2 nanocomposite for the selective removal of rose bengal from wastewater. International Journal of Biological Macromolecules, 2018, 107 : 1046– 1053 https://doi.org/10.1016/j.ijbiomac.2017.09.082
40
M Naushad, Z A Alothman, M R Awual, S M Alfadul, T Ahamad. Adsorption of rose bengal dye from aqueous solution by amberlite Ira-938 resin: kinetics, isotherms, and thermodynamic studies. Desalination and Water Treatment, 2016, 57( 29): 13527– 13533 https://doi.org/10.1080/19443994.2015.1060169
41
R Cai, Y P Du, S J Peng, H C Bi, W Y Zhang, D Yang, J Chen, T M Lim, H Zhang, Y C Cao, Q Yan. Synthesis of porous, hollow metal MCO3 (M = Mn, Co, Ca) microstructures and adsorption properties thereof. Chemistry, 2014, 20( 2): 421– 425 https://doi.org/10.1002/chem.201302052
42
M Wang, Y F Ma, Y Sun, S Y Hong, S K Lee, B Yoon, L Chen, L J Ci, J D Nam, X Y Chen, J Suhr. Hierarchical porous chitosan sponges as robust and recyclable adsorbents for anionic dye adsorption. Scientific Reports, 2017, 7( 1): 18054 https://doi.org/10.1038/s41598-017-18302-0
