1. School of Resources, Environment and Materials, Guangxi University, Nanning 530004, China 2. Key Laboratory on Resources Chemicals and Materials of Ministry of Education, Shenyang University of Chemical Technology, Shenyang 110142, China 3. State Key Laboratory of Featured Metal Materials and Life-Cycle Safety for Composite Structures, Guangxi University, Nanning 530004, China
The combination of high-voltage windows and bending stability remains a challenge for supercapacitors. Here, we present an “advantage-complementary strategy” using sodium lignosulfonate as a pseudocapacitive molecule to regulate the spatial stacking pattern of graphene oxide and the interfacial architectures of graphene oxide and polyaniline. Flexible and sustainable sodium lignosulfonate-based electrodes are successfully developed, showing perfect bending stability and high electronic conductivity and specific capacitance (521 F·g−1 at 0.5 A·g–1). Due to the resulting rational interfacial structure and stable ion-electron transport, the asymmetric supercapacitors provide a wide voltage window reaching 1.7 V, outstanding bending stability and high energy-power density of 83.87 Wh·kg–1 at 3.4 kW·kg–1. These properties are superior to other reported cases of asymmetric energy enrichment. The synergistic strategy of sodium lignosulfonate on graphene oxide and polyaniline is undoubtedly beneficial to advance the process for the construction of green flexible supercapacitors with remarkably wide voltage windows and excellent bending stability.
B Li, M Yu, Z Li, C Yu, H Wang, Q Li. Constructing flexible all-solid-state supercapacitors from 3D nanosheets active bricks via 3D manufacturing technology: a perspective review. Advanced Functional Materials, 2022, 32(29): 202201166 https://doi.org/10.1002/adfm.202201166
2
D Zhao, Y Zhu, W Cheng, W Chen, Y Wu, H Yu. Cellulose: cellulose-based flexible functional materials for emerging intelligent electronics. Advanced Materials, 2021, 33(28): 2000619 https://doi.org/10.1002/adma.202000619
3
T Lv, M Liu, D Zhu, L Gan, T Chen. Nanocarbon-based materials for flexible all-solid-state supercapacitors. Advanced Materials, 2018, 30(17): e1705489 https://doi.org/10.1002/adma.201705489
4
P Du, H C Liu, C Yi, K Wang, X Gong. Polyaniline-modified oriented graphene hydrogel film as the free-standing electrode for flexible solid-state supercapacitors. ACS Applied Materials & Interfaces, 2015, 7(43): 23932–23940 https://doi.org/10.1021/acsami.5b06261
5
C Yang, L Zhang, N Hu, Z Yang, H Wei, Y Zhang. Reduced graphene oxide/polypyrrole nanotube papers for flexible all-solid-state supercapacitors with excellent rate capability and high energy density. Journal of Power Sources, 2016, 302: 39–45 https://doi.org/10.1016/j.jpowsour.2015.10.035
6
Y Heng, G Teng, Y Chi, D Hu. Construction of biomass-derived hybrid organogel electrodes with a cross-linking conductive network for high-performance all-solid-state supercapacitors. Biomacromolecules, 2022, 23(3): 913–925 https://doi.org/10.1021/acs.biomac.1c01346
7
D Zhao, C Chen, Q Zhang, W Chen, S Liu, Q Wang, Y Liu, J Li, H Yu. High performance, flexible, solid-state supercapacitors based on a renewable and biodegradable mesoporous cellulose membrane. Advanced Energy Materials, 2017, 7(18): 1700739 https://doi.org/10.1002/aenm.201700739
8
L Liu, X Yu, W Zhang, Q Lv, L Hou, Y Fautrelle, Z Ren, G Cao, X Lu, X Li. Strong magnetic-field-engineered porous template for fabricating hierarchical porous Ni-Co-Zn-P nanoplate arrays as battery-type electrodes of advanced all-solid-state supercapacitors. ACS Applied Materials & Interfaces, 2022, 14(2): 2782–2793 https://doi.org/10.1021/acsami.1c19997
9
L Zhou, H Cao, S Zhu, L Hou, C Yuan. Hierarchical micro-/mesoporous N- and O-enriched carbon derived from disposable cashmere: a competitive cost-effective material for high-performance electrochemical capacitors. Green Chemistry, 2015, 17(4): 2373–2382 https://doi.org/10.1039/C4GC02032D
10
D Zhao, B Pang, Y Zhu, W Cheng, K Cao, D Ye, C Si, G Xu, C Chen, H Yu. A stiffness-switchable, biomimetic smart material enabled by supramolecular reconfiguration. Advanced Materials, 2022, 34(10): 2107857 https://doi.org/10.1002/adma.202107857
11
G Jiang, G Wang, Y Zhu, W Cheng, G Xu, D Zhao, H Yu. A scalable bacterial cellulose ionogel for multisensory electronic skin. Research, 2022, 2022: 9814767 https://doi.org/10.34133/2022/9814767
12
Q Zhang, C Chen, W Chen, G Pastel, X Guo, S Liu, Q Wang, Y Liu, J Li, H Yu, L Hu. Nanocellulose-enabled, all-nanofiber, high-performance supercapacitor. ACS Applied Materials & Interfaces, 2019, 11(6): 5919–5927 https://doi.org/10.1021/acsami.8b17414
13
C Chen, Y Zhang, Y Li, J Dai, J Song, Y Yao, Y Gong, I Kierzewski, J Xie, L Hu. All-wood, low tortuosity, aqueous, biodegradable supercapacitors with ultra-high capacitance. Energy & Environmental Science, 2017, 10(2): 538–545 https://doi.org/10.1039/C6EE03716J
14
A Bora, K Mohan, S Doley, S K Dolui. Flexible asymmetric supercapacitor based on functionalized reduced graphene oxide aerogels with wide working potential window. ACS Applied Materials & Interfaces, 2018, 10(9): 7996–8009 https://doi.org/10.1021/acsami.7b18610
15
R Sahoo, D T Pham, T H Lee, T H T Luu, J Seok, Y H Lee. Redox-driven route for widening voltage window in asymmetric supercapacitor. ACS Nano, 2018, 12(8): 8494–8505 https://doi.org/10.1021/acsnano.8b04040
16
M S Asl, R Hadi, L Salehghadimi, A G Tabrizi, S Farhoudian, A Babapoor, M Pahlevani. Flexible all-solid-state supercapacitors with high capacitance, long cycle life, and wide operational potential window: recent progress and future perspectives. Journal of Energy Storage, 2022, 50: 104223 https://doi.org/10.1016/j.est.2022.104223
17
A MalekX LuP R ShearingD J L BrettG He. Strategic comparison of membrane-assisted and membrane-less water electrolyzers and their potential application in direct seawater splitting (DSS). Green Energy & Environment, 2022, 2468–0257
18
Z Liu, Z Zhao, A Xu, W Li, Y Qin. Facile preparation of graphene/polyaniline composite hydrogel film by electrodeposition for binder-free all-solid-state supercapacitor. Journal of Alloys and Compounds, 2021, 875: 159931 https://doi.org/10.1016/j.jallcom.2021.159931
19
H Wang, T Yan, P Liu, G Chen, L Shi, J Zhang, Q Zhong, D Zhang. In situ creating interconnected pores across 3D graphene architectures and their application as high performance electrodes for flow-through deionization capacitors. Journal of Materials Chemistry A, 2014, 2: 4739–4750 https://doi.org/10.1039/C3TA15152B
20
F Wang, X Dong, K Wang, W Duan, M Gao, Z Zhai, C Zhu, W Wang. Laser-induced nitrogen-doped hierarchically porous graphene for advanced electrochemical energy storage. Carbon, 2019, 150: 396–407 https://doi.org/10.1016/j.carbon.2019.05.037
21
H X Dang, D P J Barz. Graphene electrode functionalization for high performance hybrid energy storage with vanadyl sulfate redox electrolytes. Journal of Power Sources, 2022, 517: 230712 https://doi.org/10.1016/j.jpowsour.2021.230712
22
H Lei, J Tu, S Li, Z Huang, Y Luo, Z Yu, S Jiao. Graphene-encapsulated selenium@polyaniline nanowires with three-dimensional hierarchical architecture for high-capacity aluminum-selenium batteries. Journal of Materials Chemistry A, 2022, 10(28): 15146–15154 https://doi.org/10.1039/D2TA04210J
23
D Lin, Y Li. Recent advances of aqueous rechargeable zinc-iodine batteries: challenges, solutions, and prospects. Advanced Materials, 2022, 34(23): 2108856 https://doi.org/10.1002/adma.202108856
24
Y Wang, H Liu, X Ji, Q Wang, Z Tian, S Liu. Recent advances in lignosulfonate filled hydrogel for flexible wearable electronics: a mini review. International Journal of Biological Macromolecules, 2022, 212: 393–401 https://doi.org/10.1016/j.ijbiomac.2022.05.154
25
D Kai, M J Tan, P L Chee, Y K Chua, Y L Yap, X J Loh. Towards lignin-based functional materials in a sustainable world. Green Chemistry, 2016, 18(5): 1175–1200 https://doi.org/10.1039/C5GC02616D
26
F N Ajjan, N Casado, T Rębiś, A Elfwing, N Solin, D Mecerreyes, O Inganäs. Inganäs. High performance PEDOT/lignin biopolymer composites for electrochemical supercapacitors. Journal of Materials Chemistry A, 2016, 4(5): 1838–1847 https://doi.org/10.1039/C5TA10096H
27
Z Peng, Y Zou, S Xu, W Zhong, W Yang. High-performance biomass-based flexible solid-state supercapacitor constructed of pressure-sensitive lignin-based and cellulose hydrogels. ACS Applied Materials & Interfaces, 2018, 10(26): 22190–22200 https://doi.org/10.1021/acsami.8b05171
28
S Mondal, U Rana, S Malik. Reduced graphene oxide/Fe3O4/polyaniline nanostructures as electrode materials for an all-solid-state hybrid supercapacitor. Journal of Physical Chemistry C, 2017, 121(14): 7573–7583 https://doi.org/10.1021/acs.jpcc.6b10978
29
R Joshi, A Adhikari, A Dey, I Lahiri. Green reduction of graphene oxide as a substitute of acidic reducing agents for supercapacitor applications. Materials Science and Engineering B, 2023, 287: 116128 https://doi.org/10.1016/j.mseb.2022.116128
30
R Liu, T Ding, P Deng, X Yan, F Xiong, J Chen, Z Wu. Preparation of LCST regulable DES-lignin-g-PNVCL thermo-responsive polymer by ARGET-ATRP. International Journal of Biological Macromolecules, 2022, 194: 358–365 https://doi.org/10.1016/j.ijbiomac.2021.11.077
31
Z Li, Q Shi, X Ma, Y Li, K Wen, L Qin, H Chen, W Huang, F Zhang, Y Lin, T J Marks, H Huang. Efficient room temperature catalytic synthesis of alternating conjugated copolymers via C–S bond activation. Nature Communications, 2022, 13(1): 144 https://doi.org/10.1038/s41467-021-27832-1
32
W Li, H Lu, N Zhang, M Ma. Enhancing the properties of conductive polymer hydrogels by freeze-thaw cycles for high-performance flexible supercapacitors. ACS Applied Materials & Interfaces, 2017, 9(23): 20142–20149 https://doi.org/10.1021/acsami.7b05963
33
R Li, Z Lu, Y Cai, F Jiang, C Tang, Z Chen, J Zheng, J Pi, R Zhang, J Liu, Z B Chen, Y Yang, J Shi, W Hong, H Xia. Switching of charge transport pathways via delocalization changes in single-molecule metallacycles junctions. Journal of the American Chemical Society, 2017, 139(41): 14344–14347 https://doi.org/10.1021/jacs.7b06400
34
Y Zou, Z Zhang, W Zhong, W Yang. Hydrothermal direct synthesis of polyaniline, graphene/polyaniline and N-doped graphene/polyaniline hydrogels for high performance flexible supercapacitors. Journal of Materials Chemistry A, 2018, 6(19): 9245–9256 https://doi.org/10.1039/C8TA01366G
35
M Kotal, H Kim, S Roy, I K Oh. Sulfur and nitrogen co-doped holey graphene aerogel for structurally resilient solid-state supercapacitors under high compressions. Journal of Materials Chemistry A, 2017, 5(33): 17253–17266 https://doi.org/10.1039/C7TA05237E
36
J L Shi, W C Du, Y X Yin, Y G Guo, L J Wan. Hydrothermal reduction of three-dimensional graphene oxide for binder-free flexible supercapacitors. Journal of Materials Chemistry A, 2014, 2(28): 10830–10834 https://doi.org/10.1039/c4ta01547a
37
L Chang, Z Peng, T Zhang, C Yu, W Zhong. Nacre-inspired composite films with high mechanical strength constructed from MXenes and wood-inspired hydrothermal cellulose-based nanofibers for high performance flexible supercapacitors. Nanoscale, 2021, 13(5): 3079–3091 https://doi.org/10.1039/D0NR08090J
38
Y Yang, T Zhu, L Shen, Y Liu, D Zhang, B Zheng, K Gong, J Zheng, X Gong. Recent progress in the all-solid-state flexible supercapacitors. SmartMat, 2022, 3(3): 1103 https://doi.org/10.1002/smm2.1103
39
C Xu, W Y Jiang, L Guo, M Shen, B Li, J Q Wang. High supercapacitance performance of nitrogen-doped Ti3C2Tx prepared by molten salt thermal treatment. Electrochimica Acta, 2022, 403: 139528 https://doi.org/10.1016/j.electacta.2021.139528
40
V Augustyn, J Come, M A Lowe, J W Kim, P L Taberna, S H Tolbert, H D Abruña, P Simon, B Dunn. High-rate electrochemical energy storage through Li+ intercalation pseudocapacitance. Nature Materials, 2013, 12(6): 518–522 https://doi.org/10.1038/nmat3601
41
S K Kim, Y K Kim, H Lee, S B Lee, H S Park. Superior pseudocapacitive behavior of confined lignin nanocrystals for renewable energy-storage materials. ChemSusChem, 2014, 7(4): 1196–1196 https://doi.org/10.1002/cssc.201400091
42
L Dai, M Ma, J Xu, C Si, X Wang, Z Liu, Y Ni. All-lignin-based hydrogel with fast pH-stimuli responsiveness for mechanical switching and actuation. Chemistry of Materials, 2020, 32(10): 4324–4330 https://doi.org/10.1021/acs.chemmater.0c01198
43
K Jin, W Zhang, Y Wang, X Guo, Z Chen, L Li, Y Zhang, Z Wang, J Chen, L Sun, T Zhang. In-situ hybridization of polyaniline nanofibers on functionalized reduced graphene oxide films for high-performance supercapacitor. Electrochimica Acta, 2018, 285: 221–229 https://doi.org/10.1016/j.electacta.2018.07.220
44
L Zhu, C Hao, X Wang, Y Guo. Fluffy Cotton-Like GO/Zn–Co–Ni Layered Double Hydroxides Form from a Sacrificed Template GO/ZIF-8 for High Performance Asymmetric Supercapacitors. ACS Sustainable Chemistry & Engineering, 2020, 8(31): 11618–11629 https://doi.org/10.1021/acssuschemeng.0c02916
45
S Jha, S Mehta, Y Chen, L Ma, P Renner, D Y Parkinson, H Liang. Correction to “design and synthesis of lignin-based flexible supercapacitors”. ACS Sustainable Chemistry & Engineering, 2020, 8(25): 9597–9598 https://doi.org/10.1021/acssuschemeng.0c04171
46
B G Choi, M Yang, W H Hong, J W Choi, Y S Huh. 3D macroporous graphene frameworks for supercapacitors with high energy and power densities. ACS Nano, 2012, 6(5): 4020–4028 https://doi.org/10.1021/nn3003345
47
N Liu, Y Su, Z Wang, Z Wang, J Xia, Y Chen, Z Zhao, Q Li, F Geng. Electrostatic-interaction-assisted construction of 3D networks of manganese dioxide nanosheets for flexible high-performance solid-state asymmetric supercapacitors. ACS Nano, 2017, 11(8): 7879–7888 https://doi.org/10.1021/acsnano.7b02344