Rational design of practical layered transition metal oxide cathode materials for sodium-ion batteries
Yan Wang1, Ning Ding1, Rui Zhang1(), Guanhua Jin2(), Dan Sun1, Yougen Tang1, Haiyan Wang1()
1. Hunan Provincial Key Laboratory of Chemical Power Sources, College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China 2. College of Energy and Chemical Engineering, Xinjiang Institute of Technology, Aksu Prefecture 843100, China
Sodium-ion batteries (SIBs), which serve as alternatives or supplements to lithium-ion batteries, have been developed rapidly in recent years. Designing advanced high-performance layered NaxTMO2 cathode materials is beneficial for accelerating the commercialization of SIBs. Herein, the recent research progress on scalable synthesis methods, challenges on the path to commercialization and practical material design strategies for layered NaxTMO2 cathode materials is summarized. Co-precipitation method and solid-phase method are commonly used to synthesize NaxTMO2 on mass production and show their own advantages and disadvantages in terms of manufacturing cost, operative difficulty, sample quality and so on. To overcome drawbacks of layered NaxTMO2 cathode materials and meet the requirements for practical application, a detailed and deep understanding of development trends of layered NaxTMO2 cathode materials is also provided, including high specific energy materials, high-entropy oxides, single crystal materials, wide operation temperature materials and high air stability materials. This work can provide useful guidance in developing practical layered NaxTMO2 cathode materials for commercial SIBs.
Corresponding Author(s):
Rui Zhang,Guanhua Jin,Haiyan Wang
引用本文:
. [J]. Frontiers of Chemical Science and Engineering, 2024, 18(7): 80.
Yan Wang, Ning Ding, Rui Zhang, Guanhua Jin, Dan Sun, Yougen Tang, Haiyan Wang. Rational design of practical layered transition metal oxide cathode materials for sodium-ion batteries. Front. Chem. Sci. Eng., 2024, 18(7): 80.
√ Uniform morphology and distribution of elements√ Easy to scale production
× Complicated control parameters× High cost × Wastewater treatment
Soluble salt
Solid-phase method
√ Simple operation process√ Easy to control√ Low cost√ Easy to scale production
× Long calcination time× Large energy consumption× Low efficiency× Poor sample uniformity × Slightly poor performance
Flexibility
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