Study on a green synthetic method of TRPPMCl (M= Fe, Mn, Co)

doi:10.1007/s11705-009-0059-y

Front Chem Eng Chin

2009, Vol. 3

Issue (2) : 222-223 https://doi.org/10.1007/s11705-009-0059-y

RESEARCH ARTICLE

Study on a green synthetic method of TRPPMCl (M= Fe, Mn, Co)

Jing FAN, Yuanbin SHE(

), Aixin WANG

Institute of Green Chemistry and Fine Chemicals, Beijing University of Technology, Beijing 100124, China

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Abstract

A green synthetic method using mixted solvents of di-methyl formamide(DMF) and acids instead of single DMF to synthesize metalloporphyrins(TRPPMCl) from TRPPH₂ and MCl₂ metallization was proposed in this paper. A series of TRPPMCl (M= Fe, Mn, Co) were synthesized through this innovative synthetic method, and these complexes were characterized with various spectroscopic techniques, including IR and UV-Vis spectroscopy. The results showed that the metallization time was markedly reduced from about 10 h to 0.5 h in contrast with the conventional synthetic methods.

Keywords TRPPMCl metalloporphyrins green synthesis acid

Corresponding Author(s): SHE Yuanbin,Email:sheyb@bjut.edu.cn

Issue Date: 05 June 2009

Cite this article:

Jing FAN,Yuanbin SHE,Aixin WANG. Study on a green synthetic method of TRPPMCl (M= Fe, Mn, Co)[J]. Front Chem Eng Chin, 2009, 3(2): 222-223.

URL:

https://academic.hep.com.cn/fcse/EN/10.1007/s11705-009-0059-y
https://academic.hep.com.cn/fcse/EN/Y2009/V3/I2/222

Tab.1 Data on IR and UV-Vis of metalloporphyrins (Fe, Mn, Co)

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