Advances and perspectives in catalysts for liquid-phase oxidation of cyclohexane

doi:10.1007/s11705-012-0903-3

Front Chem Sci Eng

2012, Vol. 6

Issue (3) : 356-368 https://doi.org/10.1007/s11705-012-0903-3

REVIEW ARTICLE

Advances and perspectives in catalysts for liquid-phase oxidation of cyclohexane

Hui LI, Yuanbin SHE(

), Tao WANG

Institute of Green Chemistry and Fine Chemicals, Beijing University of Technology, Beijing 100124, China

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Abstract

The latest progress and developments in catalysts for the oxidation of cyclohexane are reviewed. Catalytic systems for the oxidation of cyclohexane including metal supported, metal oxides, molecular sieves, metal substituted polyoxometalates, photocatalysts, organocatalysts, Gif systems, metal-organic catalysts and metalloporphyrins are discussed with a particular emphasis on metalloporphyrin catalytic systems. The advantages and disadvantages of these methods are summarized and analyzed. Finally, the development trends in the oxidation technology of cyclohexane are examined.

Keywords cyclohexane liquid-phase oxidation catalysis

Corresponding Author(s): SHE Yuanbin,Email:sheyb@bjut.edu.cn

Issue Date: 05 September 2012

Cite this article:

Hui LI,Yuanbin SHE,Tao WANG. Advances and perspectives in catalysts for liquid-phase oxidation of cyclohexane[J]. Front Chem Sci Eng, 2012, 6(3): 356-368.

URL:

https://academic.hep.com.cn/fcse/EN/10.1007/s11705-012-0903-3
https://academic.hep.com.cn/fcse/EN/Y2012/V6/I3/356

Fig.1 The mechanism of catalytic oxidation with NHPI or NHS

Fig.2 Structures of the metallporphyrins

Fig.3 Structure of the bisironporphyrin complex (-ClTPPFe)O

Fig.4 Structures of metallo-deuteroporphyrins and metallo-tetraphenylporphyrins []

Tab.1 Selective oxidation of cyclohexane over MPc complexes in acetonitrile

Fig.5 Structures of MnAPTMPP, MnAPTPP and MnAPTCPP

Fig.6 Proposed biologic-chemical-cycle coupling mechanism

Fig.7 Possible mechanism for the aerobic oxidation of cyclohexane

Fig.8 Complete mechanism for the conversion of cyclohexane to adipic acid

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