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Design and synthesis of ZnCo2O4/CdS for substantially improved photocatalytic hydrogen production |
Xiaohong Li1, Youji Li2(), Xin Guo1, Zhiliang Jin1() |
1. School of Chemistry and Chemical Engineering, North Minzu University, Yinchuan 750021, China 2. College of Chemistry and Chemical Engineering, Jishou University, Jishou 416000, China |
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Abstract In this study, the hydrogen evolution performance of CdS nanorods is improved using ZnCo2O4. ZnCo2O4 nanospheres are synthesized using the hydrothermal and calcination methods, and CdS nanorods are synthesized using the solvothermal method. From the perspective of morphology, numerous CdS nanorods are anchored on the ZnCo2O4 microspheres. According to the experimental results of photocatalytic hydrogen evolution, the final hydrogen evolution capacity of 7417.5 μmol∙g–1∙h–1 is slightly more than two times that of the single CdS, which proves the feasibility of our study. Through various characterization methods, it is proved that the composite sample has suitable optoelectronic properties. In addition, ZnCo2O4 itself exhibits good conductivity and low impedance, which shortens the charge-transfer path. Overall, the introduction of ZnCo2O4 expands the adsorption range of light and improves the performance of photocatalytic hydrogen evolution. This design can provide reference for developing high-efficiency photocatalysts.
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Keywords
ZnCo2O4 nanosphere
CdS nanorods
photocatalytic hydrogen evolution
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Corresponding Author(s):
Youji Li,Zhiliang Jin
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About author: *These authors equally shared correspondence to this manuscript. |
Online First Date: 16 February 2023
Issue Date: 28 April 2023
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