|
|
|
Luminescence and recombine centre in ZnO/Si films |
Cihui LIU( ), Ran YAO, Jianfeng SU, Zeyu MA, Zhuxi FU |
| Department of Physics, University of Science and Technology of China |
|
|
|
|
Abstract The D0h luminescence of ZnO films deposited on p-type Si substrates is produced by metal-organic chemical vapor deposition (MOCVD). After annealing in the air at 700°C for an hour, the photoluminescence (PL) spectra, the I-V characteristics and the deep level transient spectroscopy (DLTS) of the samples are measured. All the samples have a rectification characteristic. DLTS signals show two deep levels of E1 and E2. The Gaussian fit curves of the PL spectra at room temperature show three luminescence lines b, c and d, of which b is attributed to the exciton emission. The donor level E1 measured by DLTS and the location state donor ionization energy Ed of the closely neighboring emission lines c and d are correlated. E1 is judged as neutral donor bound to hole emission (D0h). Moreover, the intensity of the PL spectra decreases while the relative density of E2 increases, showing that E2 has the property of a non-radiative center.
|
| Keywords
metal-organic chemical vapor deposition (MOCVD)
ZnO/p-Si
heterojunction
defect
|
|
Corresponding Author(s):
LIU Cihui,Email:chliu@ustc.edu.cn
|
|
Issue Date: 05 March 2009
|
|
| 1 |
van de polF C M, BlomF R, PopmaT J A. RF planar magnetron sputtered ZnO films I: structural properties. Thin Solid Films , 1991, 204: 349–364 doi: 10.1016/0040-6090(91)90074-8
|
| 2 |
GorlaC R, EmanetogluN W, LiangS, . Structural, optical, and surface acoustic wave properties of epitaxial ZnO films grown on (011ˉ2) sapphire by metalorganic chemical vapor deposition . Journal of Applied Physics , 1999, 85(5): 2595–2602 doi: 10.1063/1.369577
|
| 3 |
GaoP, WangZ. Nanoarchitectures of semiconducting and piezoelectric zinc oxide. Journal of Applied Physics , 2005, 97(4): 044304 doi: 10.1063/1.1847701
|
| 4 |
ChenZ Q, KawasusoA, XuY, . Production and recovery of defects in phosphorus-implanted ZnO. Journal of Applied Physics , 2005, 97(1): 013528 doi: 10.1063/1.1821636
|
| 5 |
HurT B, HwangY H, KimH K, . Strain effects in ZnO thin films and nanoparticles. Journal of Applied Physics , 2006, 99(6): 064308 doi: 10.1063/1.2183391
|
| 6 |
VayssieresL, KeisK, HagfeldtA, . Three-dimensional array of highly oriented crystalline ZnO microtubes. Chemistry of Materials , 2001, 13(12): 4395–4398 doi: 10.1021/cm011160s
|
| 7 |
ChuT L, ChuS S. Thin film II–VI photovoltaics. Solid-State Electronics , 1995, 38(3): 533–549 doi: 10.1016/0038-1101(94)00203-R
|
| 8 |
KeisK, MagnussonE, LindstromH, . A 5% efficient photoelectrochemical solar cell based on nanostructured ZnO electrodes. Solar Energy Materials and Solar Cells , 2002, 73(1): 51–58 doi: 10.1016/S0927-0248(01)00110-6
|
| 9 |
YuP, TangZ K, WongG K L, . Room temperature stimulated emission from ZnO quantum dot films. In: Proceedings of the 23rd International Conference on the Physics of Semiconductors . Singapore: World Scientific, 1996, 2: 1453–1456
|
| 10 |
LiuC H, ZhuJ J, LinB X, . Deep level of ZnO/p-Si heterostructure and its influence on the photoluminescence. Chinese Journal of Luminescence , 2001, 22(3): 218–222 (in Chinese)
|
| 11 |
ChenZ M, WangJ L. Basic material physics for semiconductor devices. Beijing: Science Press, 1999: 49–50 (in Chinese)
|
| 12 |
LiuC H, ChenY L, LinB X, . Electrical properties of ZnO/Si heterostructure. Chinese Physics Letters , 2001, 18(8): 1108–1110 doi: 10.1088/0256-307X/18/8/338
|
| 13 |
SzeS M. Physics of Semiconductor Devices. New York: Wiley, 1981, 255–265
|
| 14 |
NikitinS E, NikolaevY A, PolushinaI K, . Photoelectric phenomena in ZnO: Al-p-Si heterostructures. Semiconductors , 2003, 37(11): 1291–1295 doi: 10.1134/1.1626210
|
| 15 |
ParkW I, YiG C. Photoluminescent properties of ZnO thin films grown on SiO2/Si (100) by metal-organic chemical vapor deposition. Journal of Electronic Materials , 2001, 30(10): L32–L35 doi: 10.1007/s11664-001-0127-7
|
| 16 |
TamuraK, MakinoT, TsukazakiA, . Donor-acceptor pair luminescence in nitrogen-doped ZnO films grown on lattice-matched ScAlMgO4 (0001) substrates. Solid State Communications , 2003, 127(4): 265–269 doi: 10.1016/S0038-1098(03)00424-1
|
| 17 |
BaltrameyunasR, GavryushinV, RachyukaitisG, . Effects of deformation of the fundamental edge by defects on two-photon spectroscopy of semiconductors. Soviet Physics-Solid State , 1991, 33(3): 537–538
|
|
Viewed |
|
|
|
Full text
|
|
|
|
|
Abstract
|
|
|
|
|
Cited |
|
|
|
|
| |
Shared |
|
|
|
|
| |
Discussed |
|
|
|
|