• Various low-cost adsorbents are studied for capturing urban stormwater pollutants.
• Adsorbents are selected based on both pollutant adsorption and unexpected leaching.
• Application modes of adsorbents influence their utilization efficacy in practice.
Stormwater represents a major non-point pollution source at an urban environment. To improve the treatment efficacy of stormwater infrastructure, low-cost adsorbents have increasingly gained attention over the past decades. This article aims to briefly discuss several key aspects and principles for utilization of low-cost adsorbents for urban stormwater treatment. To determine whether a low-cost adsorbent is suitable for stormwater treatment, two aspects should be carefully assessed, including: 1) its adsorption mechanisms and behaviors that can influence the binding stre.g.,h, adsorption kinetics, and treatment capacity; and 2) unwanted chemical leaching patterns that can affect the extent of water quality degradation. Furthermore, the application mode of an adsorbent in the system design influences the utilization efficiency. Adsorbents, after dosed to soil media in infrastructure, would eventually become ineffective after oversaturation. In contrast, standalone filters or innovative composite adsorbents (e.g., adsorbent-coated mulch chips) can enable a long-lasting adsorption due to periodic replacement with fresh adsorbents. The aforementioned principles play a key role in the success of urban stormwater treatment with low-cost adsorbents.
K Björklund, L Li (2015). Evaluation of low-cost materials for sorption of hydrophobic organic pollutants in stormwater. Journal of Environmental Management, 159: 106–114 https://doi.org/10.1016/j.jenvman.2015.05.005
3
K Chan, L Van Zwieten, I Meszaros, A Downie, S Joseph (2007). Agronomic values of greenwaste biochar as a soil amendment. Soil Research (Collingwood, Vic.), 45(8): 629–634 https://doi.org/10.1071/SR07109
4
R A Chavez, G O Brown, D E Storm (2013). Impact of variable hydraulic conductivity on bioretention cell performance and implications for construction standards. Journal of Hydraulic Engineering, 139(7): 707–715 https://doi.org/10.1061/(ASCE)HY.1943-7900.0000717
5
X Chen, L Yang, S C Myneni, Y Deng (2019). Leaching of polycyclic aromatic hydrocarbons (PAHs) from sewage sludge-derived biochar. Chemical Engineering Journal, 373: 840–845 https://doi.org/10.1016/j.cej.2019.05.059
6
Y W Chiang, K Ghyselbrecht, R M Santos, J A Martens, R Swennen, V Cappuyns, B Meesschaert (2012). Adsorption of multi-heavy metals onto water treatment residuals: Sorption capacities and applications. Chemical Engineering Journal, 200–202: 405–415 https://doi.org/10.1016/j.cej.2012.06.070
7
F H Chiew, L B Mudgway, H P Duncan, T A Mcmahon (1997). Urban Stormwater Pollution, Industry Report. Clayton: Cooperative Research Centre for Catchment Hydrology Melbourne
8
T B Councell, K U Duckenfield, E R Landa, E Callender (2004). Tire-wear particles as a source of zinc to the environment. Environmental Science & Technology, 38(15): 4206–4214 https://doi.org/10.1021/es034631f
9
Y Deng, C Morris, S Rakshit, E Landa, P Punamiya, D Sarkar (2016). Water treatment residuals and scrap tire rubber as green sorbents for removal of stormwater metals. Water Environment Research, 88(6): 500–509 https://doi.org/10.2175/106143016X14504669768697
10
S J Duranceau, P G Biscardi (2015). Comparing adsorptive media use for the direct treatment of phosphorous-impaired surface water. Journal of Environmental Engineering, 141(8): 04015012 https://doi.org/10.1061/(ASCE)EE.1943-7870.0000951
11
A J Erickson, J S Gulliver, P T Weiss (2012). Capturing phosphates with iron enhanced sand filtration. Water Research, 46(9): 3032–3042 https://doi.org/10.1016/j.watres.2012.03.009
12
H Genc-Fuhrman, P S Mikkelsen, A Ledin (2007). Simultaneous removal of As, Cd, Cr, Cu, Ni and Zn from stormwater: Experimental comparison of 11 different sorbents. Water Research, 41(3): 591–602 https://doi.org/10.1016/j.watres.2006.10.024
13
A S Gunasekara, J A Donovan, B Xing (2000). Ground discarded tires remove naphthalene, toluene, and mercury from water. Chemosphere, 41(8): 1155–1160 https://doi.org/10.1016/S0045-6535(00)00016-3
14
S E Hale, J Lehmann, D Rutherford, A R Zimmerman, R T Bachmann, V Shitumbanuma, A O’toole, K L Sundqvist, H P H Arp, G Cornelissen (2012). Quantifying the total and bioavailable polycyclic aromatic hydrocarbons and dioxins in biochars. Environmental Science & Technology, 46(5): 2830–2838 https://doi.org/10.1021/es203984k
15
K Harmayani (2012). Adsorption of nutrients from stormwater using sawdust. International Journal of Environmental Sciences and Development, 3(2): 114–117 https://doi.org/10.7763/IJESD.2012.V3.199
16
I Hilber, F Blum, J Leifeld, H P Schmidt, T D Bucheli (2012). Quantitative determination of PAHs in biochar: A prerequisite to ensure its quality and safe application. Journal of Agricultural and Food Chemistry, 60(12): 3042–3050 https://doi.org/10.1021/jf205278v
17
A Jang, S Lee, Y Seo, K Kim, I Kim, P Bishop (2007). Application of mulch for treating metals in urban runoff: batch and column test. Water Science and Technology, 55(1–2): 95–103 https://doi.org/10.2166/wst.2007.024
18
A Jang, Y Seo, P L Bishop (2005). The removal of heavy metals in urban runoff by sorption on mulch. Environmental Pollution, 133(1): 117–127 https://doi.org/10.1016/j.envpol.2004.05.020
19
Q Jin, C Cui, H Chen, J Wu, J Hu, Hu Jing, X Xing, J Geng, Y Wu (2019). Effective removal of Cd2+ and Pb2+ pollutants from wastewater by dielectrophoresis-assisted adsorption. Frontiers of Environmental Science & Engineering, 13(2): 16 doi.org/10.1007/s11783-019-1092-9
20
S Kesraoui-Ouki, C R Cheeseman, R Perry (1994). Natural zeolite utilisation in pollution control: A review of applications to metals’ effluents. Journal of Chemical Technology and Biotechnology (Oxford, Oxfordshire), 59(2): 121–126 https://doi.org/10.1002/jctb.280590202
J Lehmann, S Joseph (2015). Biochar for Environmental Management. New York: Routle.g.,, 33–46
24
H Li, X Dong, E B da Silva, L M De Oliveira, Y Chen, L Q Ma (2017). Mechanisms of metal sorption by biochars: biochar characteristics and modifications. Chemosphere, 178: 466–478 https://doi.org/10.1016/j.chemosphere.2017.03.072
25
Z Li, Z Qiu, J Yang, B Ma, S Lu, C Qin (2018). Investigation of phosphate adsorption from an aqueous solution using spent fluid catalytic cracking catalyst containing lanthanum. Frontiers of Environmental Science & Engineering, 12(6): 15 doi.org/10.1007/s11783-018-1082-3
26
J Liu, A P Davis (2013). Phosphorus speciation and treatment using enhanced phosphorus removal bioretention. Environmental Science & Technology, 48(1): 607–614 https://doi.org/10.1021/es404022b
27
Q Liu, L Wu, M Gorring, Y Deng (2019). Aluminum-impregnated biochar for adsorption of arsenic (V) in urban stormwater runoff. Journal of Environmental Engineering, 145(4): 04019008 https://doi.org/10.1061/(ASCE)EE.1943-7870.0001503
28
D K Makepeace, D W Smith, S J Stanley (1995). Urban stormwater quality: summary of contaminant data. Critical Reviews in Environmental Science and Technology, 25(2): 93–139 https://doi.org/10.1080/10643389509388476
29
L C Melo, A P Puga, A R Coscione, L Beesley, C A Abreu, O A Camargo (2016). Sorption and desorption of cadmium and zinc in two tropical soils amended with sugarcane-straw-derived biochar. Journal of Soils and Sediments, 16(1): 226–234 https://doi.org/10.1007/s11368-015-1199-y
30
S K Mohanty, A B Boehm (2014). Escherichia coli removal in biochar-augmented biofilter: effect of infiltration rate, initial bacterial concentration, biochar particle size, and presence of compost. Environmental Science & Technology, 48(19): 11535–11542 https://doi.org/10.1021/es5033162
31
S K Mohanty, K B Cantrell, K L Nelson, A B Boehm (2014). Efficacy of biochar to remove Escherichia coli from stormwater under steady and intermittent flow. Water Research, 61: 288–296 https://doi.org/10.1016/j.watres.2014.05.026
32
T Mwamulima, X Zhang, Y Wang, S Song, C Peng (2018). Novel approach to control adsorbent aggregation: iron fixed bentonite-fly ash for Lead (Pb) and Cadmium (Cd) removal from aqueous media. Frontiers of Environmental Science & Engineering, 12(2): 2 doi.org/10.1007/s11783-017-0979-6
33
R Nagar, D Sarkar, K C Makris, R Datta (2010). Effect of solution chemistry on arsenic sorption by Fe-and Al-based drinking-water treatment residuals. Chemosphere, 78(8): 1028–1035 https://doi.org/10.1016/j.chemosphere.2009.11.034
34
NJDEP (2004). New Jersey Stormwater Best management Practices Manual. Trenton: New Jersey Department of Environment Protection
35
M J Norris, I D Pulford, H Haynes, C C Dorea, V R Phoenix (2013). Treatment of heavy metals by iron oxide coated and natural gravel media in sustainable urban drainage systems. Water Science and Technology, 68(3): 674–680 https://doi.org/10.2166/wst.2013.259
36
NRC (2009). Urban Stormwater Management in the United States. Washington, DC: National Academies Press
37
S W O’Neill, A P Davis (2012a). Water treatment residual as a bioretention amendment for phosphorus. I: Evaluation studies. Journal of Environmental Engineering, 138(3): 318–327 https://doi.org/10.1061/(ASCE)EE.1943-7870.0000409
38
S W O’Neill, A P Davis (2012b). Water treatment residual as a bioretention amendment for phosphorus. II: Long-term column studies. Journal of Environmental Engineering, 138(3): 328–336 https://doi.org/10.1061/(ASCE)EE.1943-7870.0000436
39
C C Obropta, J S Kardos (2007). Review of urban stormwater quality models: Deterministic, stochastic, and hybrid approaches. Journal of the American Water Resources Association, 43(6): 1508–1523 https://doi.org/10.1111/j.1752-1688.2007.00124.x
40
S Pitcher, R Slade, N Ward (2004). Heavy metal removal from motorway stormwater using zeolites. Science of the Total Environment, 334: 161–166 https://doi.org/10.1016/j.scitotenv.2004.04.035
41
P Prakash, A K SenGupta (2003). Selective coagulant recovery from water treatment plant residuals using donnan membrane process. Environmental Science & Technology, 37(19): 4468–4474 https://doi.org/10.1021/es030371q
42
R S Quilliam, S Rangecroft, B A Emmett, T H Deluca, D L Jones (2013). Is biochar a source or sink for polycyclic aromatic hydrocarbon (PAH) compounds in agricultural soils? Global Change Biology. Bioene.g.,, 5(2): 96–103 https://doi.org/10.1111/gcbb.12007
43
K R Reddy, T Xie, S Dastgheibi (2014a). Evaluation of biochar as a potential filter media for the removal of mixed contaminants from urban storm water runoff. Journal of Environmental Engineering, 140(12): 04014043 https://doi.org/10.1061/(ASCE)EE.1943-7870.0000872
44
K R Reddy, T Xie, S Dastgheibi (2014b). Nutrients removal from urban stormwater by different filter materials. Water, Air, and Soil Pollution, 225(1): 1778 https://doi.org/10.1007/s11270-013-1778-8
45
K R Reddy, T Xie, S Dastgheibi (2014c). Removal of heavy metals from urban stormwater runoff using different filter materials. Journal of Environmental Chemical Engineering, 2(1): 282–292 https://doi.org/10.1016/j.jece.2013.12.020
46
L Semerjian (2010). Equilibrium and kinetics of cadmium adsorption from aqueous solutions using untreated Pinus halepensis sawdust. Journal of Hazardous Materials, 173(1–3): 236–242 doi:10.1016/j.jhazmat.2009.08.074
47
H Soleimanifar, Y Deng, K Barrett, H Feng, X Li, D Sarkar (2019). Water treatment residual‐coated wood mulch for addressing urban stormwater pollution. Water Environment Research, 91(6): 523–535 https://doi.org/10.1002/wer.1055
48
H Soleimanifar, Y Deng, L Wu, D Sarkar (2016). Water treatment residual (WTR)-coated wood mulch for alleviation of toxic metals and phosphorus from polluted urban stormwater runoff. Chemosphere, 154: 289–292 https://doi.org/10.1016/j.chemosphere.2016.03.101
49
J Tian, J Jin, P C Chiu, D K Cha, M Guo, P T Imhoff (2019). A pilot-scale, bi-layer bioretention system with biochar and zero-valent iron for enhanced nitrate removal from stormwater. Water Research, 148: 378–387 https://doi.org/10.1016/j.watres.2018.10.030
50
A J Turgeon, L B Mccarty, N E Christians (2009). Weed Control in Turf and Ornamentals. Upper Saddle River: Prentice Hall
51
B A Ulrich, E A Im, D Werner, C P Higgins (2015). Biochar and activated carbon for enhanced trace organic contaminant retention in stormwater infiltration systems. Environmental Science & Technology, 49(10): 6222–6230 https://doi.org/10.1021/acs.est.5b00376
52
United-Nations (2018). The World’s Cities (London, England). New York: United Nations
S Wang, B Gao, A R Zimmerman, Y Li, L Ma, W G Harris, K W Migliaccio (2015). Removal of arsenic by magnetic biochar prepared from pinewood and natural hematite. Bioresource Technology, 175: 391–395 https://doi.org/10.1016/j.biortech.2014.10.104
56
M Wanielista, N B Chang (2008). Alternative Stormwater Sorption Media for the Control of Nutrients. Orlando: Stormwater Management Academy, University of Central Florida
57
G Wei, J Zhang, J Luo, H Xue, D Huang, Z Cheng, X Jiang (2019). Nanoscale zero-valent iron supported on biochar for the highly efficient removal of nitrobenzene. Frontiers of Environmental Science & Engineering, 13(4): 61 doi.org/10.1007/s11783-019-1142-3
58
P Wu, Y S Zhou (2009). Simultaneous removal of coexistent heavy metals from simulated urban stormwater using four sorbents: A porous iron sorbent and its mixtures with zeolite and crystal gravel. Journal of Hazardous Materials, 168(2–3): 674–680 https://doi.org/10.1016/j.jhazmat.2009.02.093
59
T Xie, K R Reddy, C W Wang, E Yargicoglu, K Spokas (2015). Characteristics and applications of biochar for environmental remediation: A review. Critical Reviews in Environmental Science and Technology, 45(9): 939–969 https://doi.org/10.1080/10643389.2014.924180
60
W Zhang, G O Brown, D E Storm, H Zhang (2008). Fly-ash-amended sand as filter media in bioretention cells to improve phosphorus removal. Water Environment Research, 80(6): 507–516 https://doi.org/10.2175/106143008X266823
61
A M Ziyath, P Mahbub, A Goonetilleke, M O Adebajo, S Kokot, A Oloyede (2011). Influence of physical and chemical parameters on the treatment of heavy metals in polluted stormwater using zeolite: A review. Journal of Water Resource and Protection, 3(10): 758–767 https://doi.org/10.4236/jwarp.2011.310086