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Frontiers of Environmental Science & Engineering

ISSN 2095-2201

ISSN 2095-221X(Online)

CN 10-1013/X

Postal Subscription Code 80-973

2018 Impact Factor: 3.883

Front Envir Sci Eng    0, Vol. Issue () : 177-183    https://doi.org/10.1007/s11783-011-0354-y
RESEARCH ARTICLE
Concentrations and classification of HCHs and DDTs in soil from the lower reaches of the Jiulong River, China
Jiaquan ZHANG1,2, Shihua QI1(), Xinli XING1, Lingzhi TAN1, Wei CHEN1, Ying HU1, Dan YANG1, Chenxi WU1
1. State Key Laboratory of Biogeology and Environmental Geology, and School of Environmental Studies, China University of Geosciences, Wuhan 430074, China; 2. School of Environmental Science and Engineering, Huangshi Institute of Technology, Huangshi 435003, China
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Abstract

Soil is an important source to other environmental media and organisms for organochlorine pesticides (OCPs) bioaccumulation. Twenty-four representative surface soil samples were collected from the lower reaches of the Jiulong River, China, in 2009. The concentrations of hexachlorocyclohexane isomers (HCHs) ranged from 0.38 to 39.52 ng·g-1, with a mean value of 9.51 ng·g-1. The concentrations of dichlorodiphenyltrichloroethanes (DDTs) and their metabolites were within the ranges of 0.94–700.99 ng·g-1, with a mean value of 71.17 ng·g-1. The concentrations of HCHs and DDTs in the soil were lower than the first grade level (50 ng·g-1) of the Chinese Environmental Quality Standard (GB15618-1995). Hierarchical Cluster Analysis (HCA) and Pearson’s bivariate Correlations Analysis (PCA) were used to analyse the distribution and contamination levels of OCPs in this region. The results showed that DDTs were the major contaminants and there were no significant correlations between various OCPs concentrations and the total organic carbon (TOC) contents. A significant positive correlation was observed between HCHs and DDTs (p<0.01), which indicates that HCHs and DDTs may have similar sources and fate in the study area.

Keywords Jiulong River      hexachlorocyclohexane (HCH) and dichlorodiphenyltrichloroethan (DDT)      classification      Hierarchical Cluster Analysis (HCA)      Pearson’s bivariate Correlations Analysis (PCA)     
Corresponding Author(s): QI Shihua,Email:shihuaqi@cug.edu.cn   
Issue Date: 01 April 2012
 Cite this article:   
Xinli XING,Lingzhi TAN,Wei CHEN, et al. Concentrations and classification of HCHs and DDTs in soil from the lower reaches of the Jiulong River, China[J]. Front Envir Sci Eng, 0, (): 177-183.
 URL:  
https://academic.hep.com.cn/fese/EN/10.1007/s11783-011-0354-y
https://academic.hep.com.cn/fese/EN/Y0/V/I/177
Fig.1  Map of sampling sites
meanstandard deviationmedianminimummaximumdetection rate/%target values
chna)nethb)
α-HCH2.472.362.110.159.95100.003
β-HCH2.945.790.69n.d.24.9662.509
γ-HCH1.681.161.870.144.51100.000.05
δ-HCH2.426.120.790.0630.62100.00
HCHs9.5110.675.510.3839.52100.005010
p,p′-DDE14.1628.014.260.58128.24100.00
p,p′-DDD3.775.690.68n.d.19.4387.50
p,p′-DDT49.82127.783.800.28523.82100.00
о,p′-DDT3.427.830.06n.d.29.5054.20
DDTs71.17158.8810.580.94700.99100.005010
TOC/%1.400.781.190.223.66
α-HCH/γ-HCH1.551.041.280.585.29
(DDE + DDD) /p,p′-DDT2.653.821.300.0614.08
Tab.1  Concentrations (ng·g dry weight) of OCPs and selected properties in soil samples
Fig.2  Dendrogram of Hierarchical Cluster Analysis for variables (R-cluster)
Fig.3  Dendrogram of Hierarchical Cluster Analysis for cases (Q-cluster)
α-HCHβ-HCHγ-HCHδ-HCHHCHsp,p′-DDEp,p′-DDDp,p′-DDTо,p′-DDTDDTsTOC
α-HCH1.000
β-HCH0.3541.000
γ-HCH0.893a)0.3231.000
δ-HCH0.819a)0.547b)0.744a)1.000
HCHs0.939a)0.4420.827a)0.924a)1.000
p,p′-DDE0.599a)0.3630.493b)0.572a)0.581a)1.000
p,p′-DDD-0.3440.462-0.139-0.309-0.3440.0731.000
p,p′-DDT0.471b)0.1090.578a)0.496b)0.465b)0.613a)0.1381.000
о,p′-DDT-0.116-0.034-0.361-0.156-0.055-0.262-0.081-0.3411.000
DDTs0.536a)0.1690.563a)0.523a)0.538a)0.826a)0.1460.924a)-0.3311.000
TOC-0.0390.196-0.2090.0770.1010.098-0.134-0.2140.146-0.0191.000
Tab.2  orrelations between OCPs and TOC in soil samples
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