Competitive adsorption and desorption of copper and lead in some soil of North China

doi:10.1007/s11783-012-0423-x

Front Envir Sci Eng

2012, Vol. 6

Issue (4) : 484-492 https://doi.org/10.1007/s11783-012-0423-x

RESEARCH ARTICLE

Competitive adsorption and desorption of copper and lead in some soil of North China

Fengjie ZHANG^1,2, Xiaoxia OU², Shuo CHEN¹(

), Chunqiu RAN², Xie QUAN¹

1. Key Laboratory of Industrial Ecology and Environmental Engineering (Ministry of Education), School of Environmental Science and Technology, Dalian University of Technology, Dalian 116024, China; 2. College of Environment and Resources, Dalian Nationalities University, Dalian 116600, China

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Abstract

The competitive adsorption and desorption of Pb(II) and Cu(II) ions in the soil of three sites in North China were investigated using single and binary metal solutions with 0.01 mol·L^-1 CaCl₂ as background electrolyte. The desorption isotherms of Pb(II) and Cu(II) were similar to the adsorption isotherms, which can be fitted well by Freundlich equation (R₂>0.96). The soil in the three sites had greater sorption capacities for Pb(II) than Cu(II), which was affected strongly by the soil characteristics. In the binary metal solution containing 1∶1 molar ratio of Pb(II) and Cu(II), the total amount of Pb(II) and Cu(II) adsorption was affected by the simultaneous presence of the two metal ions, indicating the existence of adsorption competition between the two metal ions. Fourier transform infrared (FT-IR) spectroscopy was used to investigate the interaction between soil and metal ions, and the results revealed that the carboxyl and hydroxyl groups in the soil were the main binding sites of metal ions.

Keywords competitive adsorption desorption copper lead soil

Corresponding Author(s): CHEN Shuo,Email:shuochen@dlut.edu.cn

Issue Date: 01 August 2012

Cite this article:

Fengjie ZHANG,Xiaoxia OU,Shuo CHEN, et al. Competitive adsorption and desorption of copper and lead in some soil of North China[J]. Front Envir Sci Eng, 2012, 6(4): 484-492.

URL:

https://academic.hep.com.cn/fese/EN/10.1007/s11783-012-0423-x
https://academic.hep.com.cn/fese/EN/Y2012/V6/I4/484

Tab.1 Properties of the three soil samples studied

Fig.1 Adsorption and desorption of Cu (●) and Pb (○) onto the three soil samples in single-component solution.((a) HB soil adsorption; (b) HB soil desorption; (c) PJ soil adsorption; (d) PJ soil desorption; (e) DL soil adsorption; (f) DL soil desorption)

Tab.2 Freundlich coefficients for adsorption and desorption of Cu(II) and Pb(II) onto three soil in binary-component solution

Fig.2 Adsorption and desorption of Cu(+Pb) (●), Pb(+Cu) (○), and Cu-Pb (?)onto the three soil samples in binary-component solution.((a) HB soil adsorption; (b) HB soil desorption; (c) PJ soil adsorption; (d) PJ soil desorption; (e) DL soil adsorption; (f) DL soil desorption)

Fig.3 Comparison of amounts of adsorption (a) and desorption (b) ( and : 1260 μmol·L in single-component solution; : 630 μmol·L in 1∶1 molar ratio of the binary-component solution)

Fig.4 FT-IR spectra of PJ soil before and after the adsorption. (a: soil; b: soil+1260 μmol·L Pb; c: soil+1260 μmol·L Cu; d: soil+630 μmol·L Pb+630 μmol·L Cu)

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