Magnetic Co-doped 1D/2D structured γ-Fe2O3/MoS2 effectively activated peroxymonosulfate for efficient abatement of bisphenol A via both radical and non-radical pathways

doi:10.1007/s11783-024-1797-2

Front. Environ. Sci. Eng.

2024, Vol. 18

Issue (3) : 37 https://doi.org/10.1007/s11783-024-1797-2

RESEARCH ARTICLE

Magnetic Co-doped 1D/2D structured γ-Fe₂O₃/MoS₂ effectively activated peroxymonosulfate for efficient abatement of bisphenol A via both radical and non-radical pathways

Junge Xu¹, Dong Wang¹, Die Hu², Ziwei Zhang¹, Junhong Chen¹, Yingmu Wang¹(

), Yifeng Zhang³(

)

¹. College of Civil Engineering, Fuzhou University, Fuzhou 350116, China
². China Nuclear Power Engineering Co., Ltd., Shenzhen 518120, China
³. Department of Environmental & Resource Engineering, Technical University of Denmark, Lyngby DK-2800, Denmark

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Abstract

● Magnetic Co- γ -Fe₂O₃/MoS₂ were prepared via facile hydrothermal methods.

● Doping γ -Fe₂O₃ with cobalt greatly increased PMS activation for BPA abatement.

● The compounding of MoS₂ significantly enhanced the stability of the catalyst.

● Hybrid radical-nonradical pathways acted for effective degradation of BPA.

● The toxicity of intermediates was lower than BPA via T.E.S.T analysis.

Iron-based catalysts have been widely used to treat refractory organic pollutants in wastewater. In this paper, magnetic Co-γ-Fe₂O₃ was synthesized by a facile tartaric acid-assisted hydrothermal method, and Co-γ-Fe₂O₃/MoS₂ nanocomposite catalyst was obtained via in situ growth of MoS₂ nanosheets on Co-γ-Fe₂O₃ nanoparticles. The nanocomposite catalysts were used to decompose bisphenol A (BPA) by activating peroxymonosulfate (PMS). It was shown that only 0.15 g/L catalyst and 0.5 mmol/L PMS degraded 10 mg/L of BPA (99.3% within 10 min) in the pH range of 3–9. PMS was activated due to redox cycling among the pairs Co(III)/Co(II), Fe(III)/Fe(II), and Mo(VI)/Mo(IV). Quenching experiments and electron paramagnetic resonance spectroscopy demonstrated that both radical and non-radical pathways were involved in BPA degradation, in which active radical sulfate radical and non-radical singlet oxygen were the main reactive oxygen species. Ten intermediates were identified by liquid chromatography-coupled mass spectrometry, and three possible BPA degradation pathways were proposed. The toxicity of several degradation intermediates was lower, and Co-γ-Fe₂O₃/MoS₂ exhibited excellent reusability and could be magnetically recovered.

Keywords Magnetic Co-γ-Fe₂O₃/MoS₂ Hydrothermal method Bisphenol A Degradation pathways Toxicity analysis

Corresponding Author(s): Yingmu Wang,Yifeng Zhang

Issue Date: 11 December 2023

Cite this article:

Junge Xu,Dong Wang,Die Hu, et al. Magnetic Co-doped 1D/2D structured γ-Fe₂O₃/MoS₂ effectively activated peroxymonosulfate for efficient abatement of bisphenol A via both radical and non-radical pathways[J]. Front. Environ. Sci. Eng., 2024, 18(3): 37.

URL:

https://academic.hep.com.cn/fese/EN/10.1007/s11783-024-1797-2
https://academic.hep.com.cn/fese/EN/Y2024/V18/I3/37

Fig.1 (a) XRD patterns of γ-Fe₂O₃, MoS₂, Co-γ-Fe₂O₃ and Co-γ-Fe₂O₃/MoS₂. SEM images of (b) Co-γ-Fe₂O₃ and (c) Co-γ-Fe₂O₃/MoS₂. (d) TEM images of Co-γ-Fe₂O₃/MoS₂, (e) SAED image of Co-γ-Fe₂O₃/MoS₂ and (f) EDS images of Co-γ-Fe₂O₃/MoS₂.

Fig.2 (a) XPS survey, (b) Fe 2p, (c) Co 2p, (d) Mo 3d, (e) S 2p, and (f) O 1s XPS spectra of Co-γ-Fe₂O₃/MoS₂.

Fig.3 (a) The removal efficiency of BPA under different reaction systems; the effects of (b) PMS concentration, (c) different catalyst dosages, (d) initial pH and (e, f) common anions (2, 10 mmol/L) and HA (5, 10 mg/L) on the removal of BPA; Experimental conditions: [BPA]₀ = 10 mg/L, [Catalyst]₀ = 0.15 g/L, [PMS]₀ = 0.5 mmol/L, pH₀ = 6.30.

Fig.4 (a) Effect of quenchers on BPA degradation in Co-γ-Fe₂O₃/MoS₂/PMS system; ESR spectra obtained using DMPO (b) and TEMP (c) as spin-trapping agent in H₂O- and D₂O-based. Experimental conditions: [BPA]₀ = 10 mg/L, [Catalyst]₀ = 0.15 g/L, [PMS]₀ = 0.5 mmol/L, pH₀ = 6.30.

Fig.5 (a) Fe 2p XPS spectra, (b) Co 2p XPS spectra, and (c) Mo 3d XPS spectra of the fresh and used Co-γ-Fe₂O₃/MoS₂.

Fig.6 Possible degradation mechanism of BPA in Co-γ-Fe₂O₃/MoS₂/PMS system.

Fig.7 Proposed degradation pathways of BPA in the Co-γ-Fe₂O₃/MoS₂/PMS system.

Fig.8 (a) mutagenicity, (b) developmental toxicity, (c) bioaccumulation factor, and (d) acute toxicity of BPA and its degradation intermediates.

Fig.9 (a) Cycling test of Co-γ-Fe₂O₃ for the degradation of BPA; (b) XRD patterns of Co-γ-Fe₂O₃ before and after the reaction; (c) stability of Co-γ-Fe₂O₃/MoS₂ for the degradation of BPA; (d) XRD patterns, (e) XPS survey patterns, and (f) magnetic hysteresis loops of fresh and used Co-γ-Fe₂O₃/MoS_2.

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[1]	Haiguang Zhang, Lei Du, Jiajian Xing, Gaoliang Wei, Xie Quan. Electro-conductive crosslinked polyaniline/carbon nanotube nanofiltration membrane for electro-enhanced removal of bisphenol A[J]. Front. Environ. Sci. Eng., 2023, 17(5): 59-.
[2]	Xiaohui Wang, Shuai Du, Tao Ya, Zhiqiang Shen, Jing Dong, Xiaobiao Zhu. Removal of tetrachlorobisphenol A and the effects on bacterial communities in a hybrid sequencing biofilm batch reactor-constructed wetland system[J]. Front. Environ. Sci. Eng., 2019, 13(1): 14-.
[3]	Yong YU, Laosheng WU. *Determination and occurrence of endocrine disrupting compounds, pharmaceuticals and personal care products in fish (Morone saxatilis)*[J]. Front. Environ. Sci. Eng., 2015, 9(3): 475-481.
[4]	Liping LIANG,Jing ZHANG,Pian FENG,Cong LI,Yuying HUANG,Bingzhi DONG,Lina LI,Xiaohong GUAN. Occurrence of bisphenol A in surface and drinking waters and its physicochemical removal technologies[J]. Front. Environ. Sci. Eng., 2015, 9(1): 16-38.
[5]	Xue BAI, Hanchang SHI, Zhengfang YE, Qiujin SUN, Qing WANG, Zhongyou WANG. Degradation of bisphenol A by microorganisms immobilized on polyvinyl alcohol microspheres[J]. Front Envir Sci Eng, 2013, 7(6): 844-850.
[6]	Liqin JI, Xue BAI, Lincheng ZHOU, Hanchang SHI, Wei CHEN, Zulin HUA. One-pot preparation of graphene oxide magnetic nanocomposites for the removal of tetrabromobisphenol A[J]. Front Envir Sci Eng, 2013, 7(3): 442-450.
[7]	Hongtao ZHU, Wenna LI. Bisphenol A removal from synthetic municipal wastewater by a bioreactor coupled with either a forward osmotic membrane or a microfiltration membrane unit[J]. Front Envir Sci Eng, 2013, 7(2): 294-300.
[8]	XU Bin, GAO Naiyun, RUI Min, WANG Hong, WU Haihui. Degradation of endocrine disruptor bisphenol A in drinking water by ozone oxidation[J]. Front.Environ.Sci.Eng., 2007, 1(3): 350-356.
[9]	ZHAN Manjun, YANG Xi, KONG Lingren, YANG Hongshen. Effect of natural aquatic humic substances on the photodegradation of bisphenol A[J]. Front.Environ.Sci.Eng., 2007, 1(3): 311-315.

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