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Numerical investigation of the chemical and electrochemical characteristics of planar solid oxide fuel cell with direct internal reforming |
Yuzhang WANG( ), Shilie WENG, Yiwu WENG |
| School of Mechanical Engineering, Key Laboratory for Power Machinery and Engineering of Ministry of Education, Shanghai Jiao Tong University, Shanghai 200240, China |
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Abstract A fully three-dimensional mathematical model of a planar solid oxide fuel cell (SOFC) with complete direct internal steam reforming was constructed to investigate the chemical and electrochemical characteristics of the porous-electrode-supported (PES)-SOFC developed by the Central Research Institute of Electric Power Industry of Japan. The effective kinetic models developed over the Ni/YSZ anode takes into account the heat transfer and species diffusion limitations in this porous anode. The models were used to simulate the methane steam reforming processes at the co- and counter-flow patterns. The results show that the flow patterns of gas and air have certain effects on cell performance. The cell at the counter-flow has a higher output voltage and output power density at the same operating conditions. At the counter-flow, however, a high hotspot temperature is observed in the anode with a non-fixed position, even when the air inlet flow rate is increased. This is disadvantageous to the cell. Both cell voltage and power density decrease with increased air flow rate.
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| Keywords
planar solid oxide fuel cell (SOFC)
direct internal reforming
chemical reaction
methane
electrochemical
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Corresponding Author(s):
WANG Yuzhang,Email:yuzhangwang@yahoo.com.cn
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Issue Date: 05 June 2011
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