Please wait a minute...
Frontiers in Energy

ISSN 2095-1701

ISSN 2095-1698(Online)

CN 11-6017/TK

Postal Subscription Code 80-972

2018 Impact Factor: 1.701

Front. Energy    2024, Vol. 18 Issue (4) : 474-482    https://doi.org/10.1007/s11708-024-0930-z
A fibrous hydroelectric generator derived from eco-friendly sodium alginate for low-grade energy harvesting
Feng GONG1, Jiaming SONG1, Haotian CHEN1, Hao LI2(), Runnan HUANG1, Yuhang JING1, Peng YANG1, Junjie FENG1, Rui XIAO1()
1. Key Laboratory of Energy Thermal Conversion and Control of the Ministry of Education, School of Energy and Environment, Southeast University, Nanjing 210096, China
2. Department of Mechanical Engineering, The University of Hong Kong, Hong Kong, China
 Download: PDF(2940 KB)   HTML
 Export: BibTeX | EndNote | Reference Manager | ProCite | RefWorks
Abstract

With the development of renewable energy technologies, the recovery and utilization of low-grade energy based on hydroelectric effect have drawn much attention owing to its environmental friendliness. Herein, a novel hydroelectric generator utilizing sodium alginate-graphene oxide (SA-GO) fibers is proposed, which is eco-friendly and low-cost. These fibers with a length of 5 cm and a diameter of 0.15 mm can generate an open circuit voltage (Voc) of approximately 0.25 V and a short circuit current (Isc) of 4 μA. By connecting SA-GO fibers in either series or parallel, this combination can power some electronic devices. Furthermore, these fibers enable the recovery of low-grade energy from the atmosphere or around the human body. Both experimental and theoretical analysis confirm that the directional flow of protons driven by water molecules is the main mechanism for power generation of SA-GO fibers. This study not only presents a simple energy transformation method that is expected to be applied to our daily life, but also provides a novel idea for the design of humidity electricity-generation devices.

Keywords fibrous hydroelectric generator      sodium alginate (SA)      graphene oxide (GO)      power generation     
Corresponding Author(s): Hao LI,Rui XIAO   
About author:

Chunqi Yang contributed equally to this work.

Online First Date: 22 February 2024    Issue Date: 31 July 2024
 Cite this article:   
Feng GONG,Jiaming SONG,Haotian CHEN, et al. A fibrous hydroelectric generator derived from eco-friendly sodium alginate for low-grade energy harvesting[J]. Front. Energy, 2024, 18(4): 474-482.
 URL:  
https://academic.hep.com.cn/fie/EN/10.1007/s11708-024-0930-z
https://academic.hep.com.cn/fie/EN/Y2024/V18/I4/474
Fig.1  Schematic diagram of fiber electricity generation process.
Fig.2  Characteristics of flexible fiber materials.
Fig.3  Electrical properties of flexible fibers.
MaterialFormMechanismVoltage/VCurrent/μARef.
GODeformableIon diffusion0.21.2Yang et al. [28]
CelluloseAerogelStreaming potential0.112.2 × 10?5Li et al. [46]
GOFilmIon diffusion0.0355Zhao et al. [56]
GO and copolymersFilmIon diffusion0.0186.4Daripa et al. [57]
CarbonCarbon dots on paperIon diffusion0.040.142Li et al. [58]
PolypyrroleNanowireIon diffusion0.154 × 10?3Chen et al. [59]
CellulosePaperIon diffusion0.251.5 × 10?5Gao et al. [60]
Cellulose acetateElectrospun membraneStreaming potential0.38 × 10?5Lyu et al. [61]
SilkNanofiber networkIon diffusion0.130.1Yang et al. [62]
SA/GO/CNF/CNTFabricStreaming potential0.254This work
Tab.1  Comparison of electricity generation between SA-GO and moist-electric power generations in references
Fig.4  Methods to improve the fiber power output.
Fig.5  Verification of principle of moisture generation of flexible fiber.
1 Ş Kılkış, G Krajačić, N Duić. et al.. Research frontiers in sustainable development of energy, water and environment systems in a time of climate crisis. Energy Conversion and Management, 2019, 199: 111938
https://doi.org/10.1016/j.enconman.2019.111938
2 Q Zhou, F Gong, Y L Xie. et al.. A general strategy for designing metal-free catalysts for highly-efficient nitric oxide reduction to ammonia. Fuel, 2022, 310: 122442
https://doi.org/10.1016/j.fuel.2021.122442
3 F Gong, W B Wang, H Li. et al.. Solid waste and graphite derived solar steam generator for highly-efficient and cost-effective water purification. Applied Energy, 2020, 261: 114410
https://doi.org/10.1016/j.apenergy.2019.114410
4 W Kempton, F M Pimenta, D E Veron. et al.. Electric power from offshore wind via synoptic-scale interconnection. Proceedings of the National Academy of Sciences of the United States of America, 2010, 107(16): 7240–7245
https://doi.org/10.1073/pnas.0909075107
5 F Gong, H Li, W B Wang. et al.. Scalable, eco-friendly and ultrafast solar steam generators based on one-step melamine-derived carbon sponges toward water purification. Nano Energy, 2019, 58: 322–330
https://doi.org/10.1016/j.nanoen.2019.01.044
6 P Moriarty. Global nuclear energy: An uncertain future. AIMS Energy, 2021, 9(5): 1027–1042
https://doi.org/10.3934/energy.2021047
7 Z Wang, L Tan, X M Pan. et al.. Self-powered viscosity and pressure sensing in microfluidic systems based on the piezoelectric energy harvesting of flowing droplets. ACS Applied Materials & Interfaces, 2017, 9(34): 28586–28595
https://doi.org/10.1021/acsami.7b08541
8 M J Cai, Z S Yang, J Y Cao. et al.. Recent advances in human motion excited energy harvesting systems for wearables. Energy Technology, 2020, 8(10): 2000533
https://doi.org/10.1002/ente.202000533
9 L Fang, Q W Zheng, W C Hou. et al.. A self-powered vibration sensor based on the coupling of triboelectric nanogenerator and electromagnetic generator. Nano Energy, 2022, 97: 107164
https://doi.org/10.1016/j.nanoen.2022.107164
10 L M Zhou, Y Y Liu, S L Liu. et al.. For more and purer hydrogen-the progress and challenges in water as shift reaction. Journal of Energy Chemistry, 2023, 83: 363–396
https://doi.org/10.1016/j.jechem.2023.03.055
11 S J Wang, F Gong, Q Zhou. et al.. Transition metal enhanced chromium nitride as composite nitrogen carrier for sustainable chemical looping ammonia synthesis. Applied Catalysis B: Environmental, 2023, 339: 123134
https://doi.org/10.1016/j.apcatb.2023.123134
12 C R Yang, C T Ko, S F Chang. et al.. Study on fabric-based triboelectric nanogenerator using graphene oxide/porous PDMS as a compound friction layer. Nano Energy, 2022, 92: 106791
https://doi.org/10.1016/j.nanoen.2021.106791
13 B Benadda, B Beldjilali, A Mankouri. et al.. Secure IoT solution for wearable health care applications, case study Electric Imp development platform. International Journal of Communication Systems, 2018, 31(5): e3499
https://doi.org/10.1002/dac.3499
14 E C Nelson, T Verhagen, M Vollenbroek-Hutten. et al.. Is wearable technology becoming part of us? Developing and validating a measurement scale for wearable technology embodiment.. HJMIR mealth and uHealth, 2019, 7(8): e12771
https://doi.org/10.2196/12771
15 P I Dolez. Energy harvesting materials and structures for smart textile applications: Recent progress and path forward. Sensors, 2021, 21(18): 6297
https://doi.org/10.3390/s21186297
16 G Q Jiang, T Dong, Z K Guo. Nonlinear dynamics of an unsymmetric cross-ply square composite laminated plate for vibration energy harvesting. Symmetry, 2021, 13(7): 1261
https://doi.org/10.3390/sym13071261
17 J W Song, G H Sun, X Zeng. et al.. Piezoelectric energy harvester with double cantilever beam undergoing coupled bending-torsion vibrations by width-splitting method. Scientific Reports, 2022, 12(1): 583
https://doi.org/10.1038/s41598-021-04476-1
18 Z Li, S M Yuan, J Ma. et al.. Cutting force and specific energy for rotary ultrasonic drilling based on kinematics analysis of vibration effectiveness. Chinese Journal of Aeronautics, 2022, 35(1): 376–387
https://doi.org/10.1016/j.cja.2020.12.023
19 Q Zhou, F Gong, Y L Xie. et al.. 1+1 > 2: Learning from the interfacial modulation on single-atom electrocatalysts to design dual-atom electrocatalysts for dinitrogen reduction. ScienceDirect, 2023, 8(6): 1753–1763
https://doi.org/10.1016/j.gee.2022.06.005
20 P Yadav, K Sahay, M Srivastava. et al.. Emerging trends in self-healable nanomaterials for triboelectric nanogenerators: A comprehensive review and roadmap. Frontiers in Energy, 2023, 17(6): 727–750
https://doi.org/10.1007/s11708-023-0896-2
21 H Q Gao, M G Hu, J F Ding. et al.. Investigation of contact electrification between 2D MXenes and MoS2 through density functional theory and triboelectric probes. Advanced Functional Materials, 2023, 33(15): 2213410
https://doi.org/10.1002/adfm.202213410
22 Z Y Sun, X Wen, L M Wang. et al.. Emerging design principles, materials, and applications for moisture-enabled electric generation. eScience, 2022, 2: 32–46
https://doi.org/10.1016/j.esci.2021.12.009
23 Z L Luo, C H Liu, S S Fan. A moisture induced self-charging device for energy harvesting and storage. Nano Energy, 2019, 60: 371–376
https://doi.org/10.1016/j.nanoen.2019.03.073
24 Y Liang, F Zhao, Z H Cheng. et al.. Electric power generation via asymmetric moisturizing of graphene oxide for flexible, printable and portable electronics. Energy & Environmental Science, 2018, 11(7): 1730–1735
https://doi.org/10.1039/C8EE00671G
25 J Zhang, K Zhan, S S Zhang. et al.. Discontinuous streaming potential via liquid gate. eScience, 2022, 2: 615–622
https://doi.org/10.1016/j.esci.2022.08.001
26 J X Bai, Y X Huang, H Y Wang. et al.. Sunlight-coordinated high-performance moisture power in natural conditions. Advanced Materials, 2022, 34(10): 2103897
https://doi.org/10.1002/adma.202103897
27 L Ji, K Zheng, L Zheng. et al.. Direct transition of potential of water droplets to electric energy using aligned single-walled carbon nanotubes. Chinese Physics B, 2010, 19(6): 066101
https://doi.org/10.1088/1674-1056/19/6/066101
28 C Yang, Y X Huang, H H Cheng. et al.. Rollable, stretchable, and reconfigurable graphene hygroelectric generators. Advanced Materials, 2019, 31(2): 1805705
https://doi.org/10.1002/adma.201805705
29 Z H Zhang, X M Li, J Yin. et al.. Emerging hydrovoltaic technology. Nature Nanotechnology, 2018, 13(12): 1109–1119
https://doi.org/10.1038/s41565-018-0228-6
30 W X Guan, Y H Guo, G H Yu. Carbon materials for solar water evaporation and desalination. Small, 2021, 17(48): 2007176
https://doi.org/10.1002/smll.202007176
31 P X Zhang, Y Y Liu, S L Liu, et al. Precise design and modification engineering of single-atom catalytic materials for oxygen reduction. Small, 2024, 20(4): 2305782
32 H H Zhang, Y Y Liu, H J Wei. et al.. Atomic-bridge structure in B−Co−P dual-active sites on boron nitride nanosheets for catalytic hydrogen generation. Applied Catalysis B: Environmental, 2022, 314: 121495
https://doi.org/10.1016/j.apcatb.2022.121495
33 T Xu, X T Ding, Y X Huang. et al.. An efficient polymer moist-electric generator. Energy & Environmental Science, 2019, 12(3): 972–978
https://doi.org/10.1039/C9EE00252A
34 G B Xue, Y Xu, T P Ding. et al.. Water-evaporation-induced electricity with nanostructured carbon materials. Nature Nanotechnology, 2017, 12(4): 317–321
https://doi.org/10.1038/nnano.2016.300
35 J Li, K Liu, G B Xue. et al.. Electricity generation from water droplets via capillary infiltrating. Nano Energy, 2018, 48: 211–216
https://doi.org/10.1016/j.nanoen.2018.02.061
36 F Gong, H Li, Q Zhou. et al.. Agricultural waste-derived moisture-absorber for all-weather atmospheric water collection and electricity generation. Nano Energy, 2020, 74: 104922
https://doi.org/10.1016/j.nanoen.2020.104922
37 Y Liang, F Zhao, Z H Cheng. et al.. Self-powered wearable graphene fiber for information expression. Nano Energy, 2017, 32: 329–335
https://doi.org/10.1016/j.nanoen.2016.12.062
38 J H Li, B L Xia, X Xiao. et al.. Stretchable thermoelectric fibers with three-dimensional interconnected porous network for low-grade body heat energy harvesting. ACS Nano, 2023, 17(19): 19232–19241
https://doi.org/10.1021/acsnano.3c05797
39 H Cho, S Kim, H Liang. et al.. Electric-potential-induced uniformity in graphene oxide deposition on porous alumina substrates. Ceramics International, 2020, 46(10): 14828–14839
https://doi.org/10.1016/j.ceramint.2020.03.008
40 Z Han, A Fina. Thermal conductivity of carbon nanotubes and their polymer nanocomposites: A review. Progress in Polymer Science, 2011, 36(7): 914–944
https://doi.org/10.1016/j.progpolymsci.2010.11.004
41 H P Yan, Z Liu, R H Qi. A review of humidity gradient-based power generator: Devices, materials and mechanisms. Nano Energy, 2022, 101: 107591
https://doi.org/10.1016/j.nanoen.2022.107591
42 K Q Wang, W H Xu, X Zhang. et al.. Bio-inspired water-driven electricity generators: From fundamental mechanisms to practical applications. Nano Research Energy, 2023, 2: e9120042
https://doi.org/10.26599/NRE.2023.9120042
43 P X Zhang, K Sun, Y Y Liu. et al.. Improving bifunctional catalytic activity of biochar via in-situ growth of nickel–iron hydroxide as cathodic catalyst for zinc-air batteries. Biochar, 2023, 5(1): 60
https://doi.org/10.1007/s42773-023-00259-1
44 P X Zhang, Y Y Liu, S L Wang. et al.. Wood-derived monolithic catalysts with the ability of activating water molecules for oxygen electrocatalysis. Small, 2022, 18(34): 2202725
https://doi.org/10.1002/smll.202202725
45 S H Hassan, T S Velayutham, Y W Chen. et al.. TEMPO-oxidized nanocellulose films derived from coconut residues: Physicochemical, mechanical and electrical properties. International Journal of Biological Macromolecules, 2021, 180: 392–402
https://doi.org/10.1016/j.ijbiomac.2021.03.066
46 M J Li, L Zong, W Q Yang. et al.. Biological nanofibrous generator for electricity harvest from moist air flow. Advanced Functional Materials, 2019, 29(32): 1901798
https://doi.org/10.1002/adfm.201901798
47 F Shakeri, S Ariaeenejad, M Ghollasi. et al.. Synthesis of two novel bio-based hydrogels using sodium alginate and chitosan and their proficiency in physical immobilization of enzymes. Scientific Reports, 2022, 12(1): 2072
https://doi.org/10.1038/s41598-022-06013-0
48 Y Q Li, H Zhang, M Z Fan. et al.. A robust salt-tolerant superoleophobic alginate/graphene oxide aerogel for efficient oil/water separation in marine environments. Scientific Reports, 2017, 7(1): 46379
https://doi.org/10.1038/srep46379
49 J Bae, T G Yun, B L Suh. et al.. Self-operating transpiration-driven electrokinetic power generator with an artificial hydrological cycle. Energy & Environmental Science, 2020, 13(2): 527–534
https://doi.org/10.1039/C9EE02616A
50 R Zhang, M J Qu, H Wang. et al.. Moist-electric films based on asymmetric distribution of sodium alginate oxygen-containing functional groups. Reactive & Functional Polymers, 2022, 181: 105421
https://doi.org/10.1016/j.reactfunctpolym.2022.105421
51 Z D Chen, J Song, Y M Xia. et al.. High strength and strain alginate fibers by a novel wheel spinning technique for knitting stretchable and biocompatible wound-care materials. Materials Science and Engineering C, 2021, 127: 112204
https://doi.org/10.1016/j.msec.2021.112204
52 F Gong, H Li, J G Huang. et al.. Low-grade energy harvesting from dispersed exhaust steam for power generation using a soft biomimetic actuator. Nano Energy, 2022, 91: 106677
https://doi.org/10.1016/j.nanoen.2021.106677
53 Y L Lv, F Gong, H Li. et al.. A flexible electrokinetic power generator derived from paper and ink for wearable electronics. Applied Energy, 2020, 279: 115764
https://doi.org/10.1016/j.apenergy.2020.115764
54 H R Abbasi, S M H Karimian. Water mass flow rate in a finite SWCNT under electric charge: A molecular dynamic simulation. Journal of Molecular Liquids, 2016, 224: 165–170
https://doi.org/10.1016/j.molliq.2016.09.083
55 Y F Xu, P N Chen, H S Peng. Generating electricity from water through carbon nanomaterials. Chemistry, 2018, 24(24): 6287–6294
https://doi.org/10.1002/chem.201704638
56 F Zhao, H H Cheng, Z P Zhang. et al.. Direct power generation from a graphene oxide film under moisture. Advanced Materials, 2015, 27(29): 4351–4357
https://doi.org/10.1002/adma.201501867
57 S Daripa, K Khawas, R P Behere. et al.. Efficient moisture-induced energy harvesting from water-soluble conjugated block copolymer-functionalized reduced graphene oxide. ACS Omega, 2021, 6(11): 7257–7265
https://doi.org/10.1021/acsomega.0c03717
58 Q J Li, M Zhou, Q F Yang. et al.. Flexible carbon dots composite paper for electricity generation from water vapor absorption. Journal of Materials Chemistry. A, Materials for Energy and Sustainability, 2018, 6(23): 10639–10643
https://doi.org/10.1039/C8TA02505C
59 N Chen, Q Liu, C Liu. et al.. MEG actualized by high-valent metal carrier transport. Nano Energy, 2019, 65: 104047
https://doi.org/10.1016/j.nanoen.2019.104047
60 X Gao, T Xu, C X Shao. et al.. Electric power generation using paper materials. Journal of Materials Chemistry. A, Materials for Energy and Sustainability, 2019, 7(36): 20574–20578
https://doi.org/10.1039/C9TA08264F
61 Q Q Lyu, B L Peng, Z J Xie. et al.. Moist-induced electricity generation by electrospun cellulose acetate membranes with optimized porous structures. ACS Applied Materials & Interfaces, 2020, 12(51): 57373–57381
https://doi.org/10.1021/acsami.0c17931
62 W Q Yang, L L Lv, X K Li. et al.. Qatarized silk nanofibrils for electricity generation from moisture and ion rectification. ACS Nano, 2020, 14(8): 10600–10607
https://doi.org/10.1021/acsnano.0c04686
63 J Bae, T G Yun, B L Suh. et al.. Self-operating transpiration-driven electrokinetic power generator with an artificial hydrological cycle. Energy & Environmental Science, 2020, 13(2): 527–534
https://doi.org/10.1039/C9EE02616A
64 B P Sharfarets, V E Kurochkin, V A Sergeev. On the operation of an electroacoustic transducer based on electrokinetic phenomena under turbulent fluid motion. Acoustical Physics, 2020, 66(5): 559–563
https://doi.org/10.1134/S1063771020050139
65 T G Yun, J Bae, A Rothschild. et al.. Transpiration driven electrokinetic power generator. ACS Nano, 2019, 13(11): 12703–12709
https://doi.org/10.1021/acsnano.9b04375
66 D C Grahame. The electrical double layer and the theory of electrocapillarity. Chemical Reviews, 1947, 41(3): 441–501
https://doi.org/10.1021/cr60130a002
67 R J Hunter. Zeta Potential in Colloid Science: Principles and Applications. Cambridge: Academic Press, 1988
68 B J Kirby, E F Jr Hasselbrink. Zeta potential of microfluidic substrates: 1. Theory, experimental techniques, and effects on separations. Electrophoresis, 2004, 25(2): 187–202
https://doi.org/10.1002/elps.200305754
69 W Olthuis, B Schippers, J Eijkel, et al. Energy from streaming current and potential. Sensors and Actuators. B, Chemical, 2005, 111–112: 385–389 10.1016/j.snb.2005.03.039
70 G B Xue, Y Xu, T P Ding. et al.. Water-evaporation-induced electricity with nanostructured carbon materials. Nature Nanotechnology, 2017, 12(4): 317–321
https://doi.org/10.1038/nnano.2016.300
71 T Xu, X T Ding, H H Cheng, et al. Moisture-enabled electricity from hygroscopic materials: A new type of clean energy. Advanced Materials, 2023, early access, https://doi.org/10.1002/adma.202209661
72 C Albayrak, G Barim, O Dag. Effect of hygroscopicity of the metal salt on the formation and air stability of lyotropic liquid crystalline mesophases in hydrated salt-surfactant systems. Journal of Colloid and Interface Science, 2014, 433: 26–33
https://doi.org/10.1016/j.jcis.2014.07.008
73 J Tan, S M Fang, Z H Zhang. et al.. Self-sustained electricity generator driven by the compatible integration of ambient moisture adsorption and evaporation. Nature Communications, 2022, 13(1): 3643
https://doi.org/10.1038/s41467-022-31221-7
[1] Muhammad Tauseef NASIR, Mirae KIM, Jaehwa LEE, Seungho KIM, Kyung Chun KIM. A review on technologies with electricity generation potentials using liquified natural gas regasification cold energy[J]. Front. Energy, 2023, 17(3): 332-379.
[2] Xingchao WANG, Chunjian PAN, Carlos E. ROMERO, Zongliang QIAO, Arindam BANERJEE, Carlos RUBIO-MAYA, Lehua PAN. Thermo-economic analysis of a direct supercritical CO2 electric power generation system using geothermal heat[J]. Front. Energy, 2022, 16(2): 246-262.
[3] Yan ZHANG, Yukun ZHU, Yanhua PENG, Xiaolong YANG, Jian LIU, Wei JIAO, Jianqiang YU. Spontaneous polarization enhanced bismuth ferrate photoelectrode: fabrication and boosted photoelectrochemical water splitting property[J]. Front. Energy, 2021, 15(3): 781-790.
[4] Harald SCHWARZ. Will Germany move into a situation with unsecured power supply?[J]. Front. Energy, 2019, 13(3): 551-570.
[5] Huayi ZHANG, Can ZHANG, Fushuan WEN, Yan XU. A comprehensive energy solution for households employing a micro combined cooling, heating and power generation system[J]. Front. Energy, 2018, 12(4): 582-590.
[6] Xiaojing LV, Yu WENG, Xiaoyi DING, Shilie WENG, Yiwu WENG. Technological development of multi-energy complementary system based on solar PVs and MGT[J]. Front. Energy, 2018, 12(4): 509-517.
[7] Feier XUE,Yu CHEN,Yonglin JU. A review of cryogenic power generation cycles with liquefied natural gas cold energy utilization[J]. Front. Energy, 2016, 10(3): 363-374.
[8] Hicham SERHOUD, Djilani BENATTOUS. Simulation of grid connection and maximum power point tracking control of brushless doubly-fed generator in wind power system[J]. Front Energ, 2013, 7(3): 380-387.
[9] S. Senthil KUMAR, N. KUMARESAN, N. Ammasai GOUNDEN, Namani RAKESH. Analysis and control of wind-driven self-excited induction generators connected to the grid through power converters[J]. Front Energ, 2012, 6(4): 403-412.
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed