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Thermogravimetric kinetic analysis of Nannochloropsis oculata combustion in air atmosphere
SUKARNI, SUDJITO, Nurkholis HAMIDI, Uun YANUHAR, I.N.G. WARDANA
Front. Energy. 2015, 9 (2): 125-133.
https://doi.org/10.1007/s11708-015-0346-x
The thermal behavior of Nannochloropsis oculata combustion in air atmosphere were investigated by performing experiments on STA PT1600 Thermal Analyzer at heating rates of 10°C/min, 40°C/min and 70°C/min and range of temperatures from room temperature to 1200°C. The kinetic parameters were evaluated by using Kissinger and Ozawa methods. The result showed that Nannochloropsis oculata combustion occurred in five stages. Started with initial devolatilization, the main thermal decomposition and combustion process, transition stage, the combustion of char and the last stage was the slow burning reaction of residual char. In line with increasing heating rate, the mass loss rate increased as well, but it delayed the thermal decomposition processes toward higher temperatures. The average activation energy at the main thermal decomposition stage and the stage of char combustion were approximately 251 kJ/mol and 178 kJ/mol, respectively.
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Ternary phase behavior of water microemulsified diesel-palm biodiesel
Nurul Atiqah Izzati MD ISHAK,Ismail Ab RAMAN,Mohd Ambar YARMO,Wan Mohd Faizal WAN MAHMOOD
Front. Energy. 2015, 9 (2): 162-169.
https://doi.org/10.1007/s11708-015-0355-9
This paper aims to develop a new microemulsions system comprising diesel and palm oil methyl ester (PME) that have the potential to be used as alternative fuels for diesel engines. The water-in-diesel-biodiesel microemulsions were prepared by applying PME mixed with diesel, non-ionic surfactants, co-surfactants and water to make the water-in-oil (W/O) microemulsion system. This microemulsified fuel was achieved through low-energy microemulsification by using the constant composition method. The diesel used was mixed with four different concentrations of PME, i.e., 10% (w/w) (B10), 20% (w/w) (B20), 30% (w/w) (B30) and neat diesel (B0). The amount of water was fixed at 20% (w/w). The phase behavior of the water/mixed non-ionic surfactant/diesel-PME system were studied by constructing pseudoternary phase diagrams with the goal of formulating optimized systems. The results showed that the microemulsions were formed and stabilized with a mixture of non-ionic surfactants at a weight ratio of 80:20 at 20% (w/w), and with mixed co-surfactants at a weight ratio of 25:75, 20:80 and 10:90 for B0, B10, B20 and B30 respectively. The particle size, kinematic viscosity at 40°C, refractive index, density, heating value, cloud point, pour point and flash point of the selected water-in-diesel microemulsion were 19.40 nm (polydispersity of 0.12), 2.86 mm2/s, 1.435, 0.8913 g/mL, 31.87 MJ/kg, 7.15°C, 10.5°C and 46.5°C respectively. The corresponding values of the water-in-diesel-PME selected were 20.72 nm to 23.74 nm, 13.02 mm2/s to 13.29 mm2/s, 1.442, 0.8939 g/mL to 0.8990 g/mL, 31.45 MJ/kg to 27.34 MJ/kg, 7.2°C to 6.8°C, 8.5°C to 1.5°C and 47.5°C to 52.0°C. These preliminary findings were further studied as potential fuels for diesel engines.
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Implementation of photovoltaic water pumping system with MPPT controls
Najet REBEI,Ali HMIDET,Rabiaa GAMMOUDI,Othman HASNAOUI
Front. Energy. 2015, 9 (2): 187-198.
https://doi.org/10.1007/s11708-015-0359-5
To increase the output efficiency of a photovoltaic (PV) system, it is important to apply an efficient maximum power point tracking (MPPT) technique. This paper describes the analysis, the design and the experimental implementation of the tracking methods for a stand-alone PV system, using two approaches. The first one is the constant voltage (CV) MPPT method based on the optimum voltage, which was deduced experimentally, and considered as a reference value to extract the optimum power. The second one is the increment conductance (Inc-Cond) MPPT method based on the calculation of the power derivative extracted by the installation. The output controller can adjust the duty ratio to the optimum value. This optimum duty ratio is the input of a DC/DC boost converter which feeds a set of Moto-pump via a DC/AC inverter. This paper presents the details of the two approaches implemented, based on the system performance characteristics. Contributions are made in several aspects of the system, including converter design, system simulation, controller programming, and experimental setup. The MPPT control algorithms implemented extract the maximum power point (MPP), with satisfactory performance and without steady-state oscillation. MATLAB/Simulink and dSpace DS1104 are used to conduct studies and implement algorithms. The two proposed methods have been validated by implementing the performance of the PV pumping systems installed on the roof of the research laboratory in INSAT Tunisia. Experimental results verify the feasibility and the improved functionality of the system.
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Energy consumption of 270 schools in Tianjin, China
Jincheng XING, Junjie CHEN, Jihong LING
Front. Energy. 2015, 9 (2): 217-230.
https://doi.org/10.1007/s11708-015-0352-z
With the rapid development of education cause, the increasing energy consumption of school buildings is gradually causing widespread concern in recent years in China. This paper presented an analysis of energy consumption of 270 schools located in the city of Tianjin, China. The analysis focused specifically on calculating the space heating energy consumption indexes and non-heating energy consumption indexes of different types of schools, aiming at providing reliable and precise data for the government to elaborate policies and measures. The space heating energy consumption of schools adopting district heating and gas boiler were 92.04 kWh/(m2·a) and 64.25 kWh/(m2·a), respectively. Comparing to the schools without a canteen, the non-heating energy consumption index of schools with a canteen can increase by 8%–37%. Furthermore, clustering of different energy sources, the total primary energy consumption indexes were also presented. Space heating energy consumption accounted for approximately 64%–79% of the total primary energy consumption. When using time-sharing control and self-contained gas boiler instead of district heating, an amount of almost 27.8 kWh/(m2·a) and 77.5 kWh/(m2·a) can be saved respectively. Through extensive statistical analysis of the data collected, this paper demonstrated that gross floor area, heating energy source and canteen had a close relationship with the total primary energy consumption regarding complete schools. Eventually, a linear regression equation was established to make a simple prediction about the total energy consumption of existing complete schools and to estimate the energy consumption of complete schools to be built.
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Inhibition of NO emission by adding antioxidant mixture in Jatropha biodiesel on the performance and emission characteristics of a C.I. engine
A. PRABU,R. B. ANAND
Front. Energy. 2015, 9 (2): 238-245.
https://doi.org/10.1007/s11708-015-0356-8
In this paper, the effect of adding an antioxidant mixture in Jatropha biodiesel as fuel, in a single cylinder, direct injection compression ignition engine was experimentally investigated and the level of pollutants in the exhaust and performance characteristics of the engine were analyzed. Nine test fuels were prepared with three antioxidants, namely, Succinimide (C4H5NO2), N,N-dimethyl-p-phenylenediamine-dihydrochloride (C8H14Cl2N2), and N-phenyl-p-phenylenediamine (C6H5NHC6H4NH2) added to neat biodiesel at 500 parts per million (ppm), 1000 ppm and 2000 ppm and the observed experimental results were compared with those of neat biodiesel and neat diesel as base fuels. The comparison showed that NO emission was reduced drastically for the test fuels with the antioxidant addition of 2000 ppm. The maximum reduction of 10% of NO emission was observed for the antioxidant mixture in neat biodiesel, with a slight increase in unburned HC, CO and smoke opacity. In addition, the obtained experimental results reveal that the addition of two antioxidants as mixture in neat biodiesel caused improved NO emission reduction for all test fuels.
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