Please wait a minute...
Frontiers of Optoelectronics

ISSN 2095-2759

ISSN 2095-2767(Online)

CN 10-1029/TN

Postal Subscription Code 80-976

Front Optoelec Chin    2011, Vol. 4 Issue (1) : 103-107    https://doi.org/10.1007/s12200-011-0201-6
RESEARCH ARTICLE
Studies of high-efficient and low-cost dye-sensitized solar cells
Qingqing MIAO, Mingxing WU, Wei GUO, Tingli MA()
State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024, China
 Download: PDF(246 KB)   HTML
 Export: BibTeX | EndNote | Reference Manager | ProCite | RefWorks
Abstract

Dye-sensitized solar cell (DSSC) is a new type of photoelectric device. To commercialize DSSC successfully, it is necessary to further improve the efficiency of energy conversion and reduce its cost. Nitrogen-doped (N-doped) TiO2 photoanode, the carbon counter electrode (CE), and a new type of hybrid photoanode were investigated in this study. The conversion efficiency of the DSSC reached by 10.10% as the DSSC was fabricated with the N-doped photoanode, and this efficiency is much higher than that of the undoped-DSSC with 8.90%; as the low-cost carbon was used as CE, the efficiency of the DSSC was 7.50%, it was as samilar as that of Pt CE (7.47%); the hybrid DSSC with multilayer photoanode by the film-transfer technique achieved a panchromatic response and a superposed short circuit current density (JSC) by using two complementary dyes.

Keywords high-efficiency      dye-sensitized solar cell (DSSC)      hybrid      nitrogen-doped (N-doped) TiO2      carbon counter electrode (CE)     
Corresponding Author(s): MA Tingli,Email:tinglima@dlut.edu.cn   
Issue Date: 05 March 2011
 Cite this article:   
Qingqing MIAO,Mingxing WU,Wei GUO, et al. Studies of high-efficient and low-cost dye-sensitized solar cells[J]. Front Optoelec Chin, 2011, 4(1): 103-107.
 URL:  
https://academic.hep.com.cn/foe/EN/10.1007/s12200-011-0201-6
https://academic.hep.com.cn/foe/EN/Y2011/V4/I1/103
Fig.1  UV-Vis absorption spectra of AP, ZnPc, hybrid of AP/ZnPc absorbed onto the TiO films
Fig.1  UV-Vis absorption spectra of AP, ZnPc, hybrid of AP/ZnPc absorbed onto the TiO films
titania electrodeVOC/mVJSC/(mA·cm-2)FF/%η/%
N-doped ST-01778±1019.05±0.070.68±0.0110.1±0.2
undoped ST-01756±1317.40±0.100.68±0.018.9±0.3
Tab.1  Performance of the DSSCs based on N-doped and undoped TiO electrodes
Fig.2  TEM images of the well-ordered Com. (a) Top view; (b) cross-section
Fig.2  TEM images of the well-ordered Com. (a) Top view; (b) cross-section
Fig.3  - curves for DSSCs using the four kinds of CEs and the Pt electrode
Fig.3  - curves for DSSCs using the four kinds of CEs and the Pt electrode
1 O’Regan B, Gr?tzel M. A low-cost, high-efficiency solar cell based on dye-sensitized TiO2 colloidal films. Nature , 1991, 353(6346): 737–740
doi: 10.1038/353737a0
2 Yamaguchi T, Uchida Y, Agatsuma S, Arakawa H. Series-connected tandem dye-sensitized solar cell for improving efficiency to more than 10%. Solar Energy Materials and Solar Cells , 2009, 93(6-7): 733–736
doi: 10.1016/j.solmat.2008.09.021
3 Inakazu F, Noma Y, Ogomi Y, Hayase S. Dye-sensitized solar cells consisting of dye-bilayer structure stained with two dyes for harvesting light of wide range of wavelength. Applied Physics Letters , 2008, 93(9): 093304
doi: 10.1063/1.2976677
4 Yanagida M, Komatsuzaki N O, Kurashigea M, Sayamaa K, Sugihara H. Optimization of tandem-structured dye-sensitized solar cell. Applied Physics Letters , 2010, 94(2): 297–302
5 Kuang D B, Walter P, Nüesch F, Kim S, Ko J J, Comte P, Zakeeruddin S M, Nazeeruddin M K, Gr?tzel M. Co-sensitization of organic dyes for efficient ionic liquid electrolyte-based dye-sensitized solar cells. Langmuir , 2007, 23(22): 10906–10909
doi: 10.1021/la702411n pmid:17880255
6 Ehret A, Stuhl L, Spitler M T. Spectral sensitization of TiO2 nanocrystalline electrodes with aggregated cyanine dyes. Journal of Physical Chemistry B , 2001, 105(41): 9960–9965
doi: 10.1021/jp011952+
7 Yum J H, Jang S R, Walter P, Geiger T, Nüesch F, Kim S, Ko J, Gr?tzel M, Nazeeruddin M K. Efficient co-sensitization of nanocrystalline TiO2 films by organic sensitizers. Chemical Communications , 2007, (44): 4680–4682
doi: 10.1039/b710759e pmid:17989831
8 Clifford J N, Palomares E, Nazeeruddin M K, Thampi R, Gr?tzel M, Durrant J R. Multistep electron transfer processes on dye co-sensitized nanocrystalline TiO2 films. Journal of the American Chemical Society , 2004, 126(18): 5670–5671
doi: 10.1021/ja049705h pmid:15125651
9 Choi H, Kim S, Kang S O, Ko J J, Kang M S, Clifford J, Forneli A, Palomares E, Nazeeruddin M K, Gr?tzel M. Stepwise co-sensitization of nanocrystalline TiO2 films utilizing Al2O3 layers in dye-sensitized solar cells. Angewandte Chemie International Edition , 2008, 47(43): 8259–8263
doi: 10.1002/anie.200802852
10 Lee K, Park S W, Ko M J, Kim K, Park N G. Selective positioning of organic dyes in a mesoporous inorganic oxide film. Nature Materials , 2009, 8(8): 665–671
doi: 10.1038/nmat2475 pmid:19561600
11 Dürr M, Bamedi A, Yasuda A, Nelles G. Tandem dye-sensitized solar cell for improved power conversion Efficiencies. Applied Physics Letters , 2004, 84(17): 3397–3399
doi: 10.1063/1.1723685
12 Murayama M, Mori T. Novel tandem cell structure of dye-sensitized solar cell for improvement in photocurrent. Thin Solid Films , 2008, 516(9): 2716–2722
doi: 10.1016/j.tsf.2007.04.076
13 Usagawa J, Pandey S S, Hayase S, Mitsuru K, Yoshihiro Y. Tandem dye-sensitized solar cells fabricated on glass rod without transparent conductive layers. Applied Physics Express , 2009, 2(6): 062203
doi: 10.1143/APEX.2.062203
14 Noma Y, Lizuka K, Ogomi Y, Pandey S S, Hayase S. Preparation of double dye-layer structure of dye-sensitized solar cells from cocktail solutions for harvesting light in wide range of wavelengths. Japanese Journal of Applied Physics , 2009, 48(2): 020213
doi: 10.1143/JJAP.48.020213
15 Nakamura I, Negishi N, Kutsuna S, Iharab T, Sugiharac S, Takeuchi K. Role of oxygen vacancy in the plasma-treated TiO2 photocatalyst with visible light activity for NO removal. Journal of Molecular Catalysis A: Chemical , 2000, 161(1-2): 205–212
doi: 10.1016/S1381-1169(00)00362-9
16 Ihara T, Miyoshi M, Iriyama Y, Matsumotoc O, Sugihara S. Visible-light-active titanium oxide photocatalyst realized by an oxygen-deficient structure and by nitrogen doping. Applied Catalysis B: Environmental , 2003, 42(4): 403–409
doi: 10.1016/S0926-3373(02)00269-2
17 Irie H, Watanabe Y, Hashimoto K. Nitrogen-concentraion dependence on photocatalytic activity of TiO2-xNx powders. Journal of Physical Chemistry B , 2003, 107(23): 5483–5486
doi: 10.1021/jp030133h
18 Mrowetz M, Balcerski W, Colussi A J, Hoffmann M R. Oxidative power of nitrogen-doped TiO2 photocatalysts under visible illumination. Journal of Physical Chemistry B , 2004, 108(45): 17269–17273
doi: 10.1021/jp0467090
19 Ma T, Akiyama M, Abe E, Imai I. High-efficiency dye-sensitized solar cell based on a nitrogen-doped nanostructured titania electrode. Nano Letters , 2005, 5(12): 2543–2547
doi: 10.1021/nl051885l pmid:16351212
20 Kong Z X, Zhou H Z, Cui J N, Ma T L, Yang X C, Sun L C. A new class of organic dyes based on acenaphthopyrazine for dye-sensitized solar cells. Journal of Photochemistry and Photobiology A Chemistry , 2010, 213(2-3): 152–157
doi: 10.1016/j.jphotochem.2010.05.017
21 Ma T, Kida T, Akiyama M, Inoue K, Tsunematsu S, Yao K, Noma H, Abe E. Preparation and properties of nanostructured TiO2 electrode by a polymer organic-medium screen-printing technique. Electrochemistry Communications , 2003, 5(4): 369–372
doi: 10.1016/S1388-2481(03)00070-5
22 Yang L, Wu L Q, Wu M X, Xin G, Lin H, Ma T. High-efficiency flexible dye-sensitized solar cells fabricated by a novel friction-transfer technique. Electrochemistry Communications , 2010, 12(7): 1000–1003
doi: 10.1016/j.elecom.2010.05.026
24 Wang H, Wang A Q, Wang X D, Zhang T. One-pot synthesized MoC imbedded in ordered mesoporous carbon as a catalyst for N2H4 decomposition. Chemical Communications , 2008, (22): 2565–2567
doi: 10.1039/b801057a pmid:18506245
25 Liang C D, Dai S. Synthesis of mesoporous carbon materials via enhanced hydrogen-bonding interaction. Journal of the American Chemical Society , 2006, 128(16): 5316–5317
doi: 10.1021/ja060242k pmid:16620083
[1] Love KUMAR, Amarpal SINGH, Vishal SHARMA. Analysis on multiple optical line terminal passive optical network based open access network[J]. Front. Optoelectron., 2019, 12(2): 208-214.
[2] Xiaoyan HU, Heng WANG. ZnO/Nb2O5 core/shell nanorod array photoanode for dye-sensitized solar cells[J]. Front. Optoelectron., 2018, 11(3): 285-290.
[3] Daoxin DAI,Yanlong YIN,Longhai YU,Hao WU,Di LIANG,Zhechao WANG,Liu LIU. Silicon-plus photonics[J]. Front. Optoelectron., 2016, 9(3): 436-449.
[4] Bat-El COHEN,Lioz ETGAR. Parameters that control and influence the organo-metal halide perovskite crystallization and morphology[J]. Front. Optoelectron., 2016, 9(1): 44-52.
[5] Xiaowei GUAN,Hao WU,Daoxin DAI. Silicon hybrid nanoplasmonics for ultra-dense photonic integration[J]. Front. Optoelectron., 2014, 7(3): 300-319.
[6] Cunxi CHENG, Jihuai WU, Yaoming XIAO, Yuan CHEN, Haijun YU, Ziying TANG, Jianming LIN, Miaoliang HUANG. Preparation of titanium dioxide-double-walled carbon nanotubes and its application in flexible dye-sensitized solar cells[J]. Front Optoelec, 2012, 5(2): 224-230.
[7] Ruixi ZENG, Yuan ZHANG, Sailing HE. Energy intensity analysis of modes in hybrid plasmonic waveguide[J]. Front Optoelec, 2012, 5(1): 68-72.
[8] Gentian YUE, Jihuai WU, Jianming LIN, Miaoliang HUANG, Ying YAO, Leqing FAN, Yaoming XIAO. Application of Poly (3, 4-ethylenedioxythiophene): polystyrenesulfonate counter electrode in polymer heterojunction dye-sensitized solar cells[J]. Front Optoelec Chin, 2011, 4(4): 369-377.
[9] Wei CHEN, Shihe YANG. Dye-sensitized solar cells based on ZnO nanotetrapods[J]. Front Optoelec Chin, 2011, 4(1): 24-44.
[10] Quanyou FENG, Hong WANG, Gang ZHOU, Zhong-Sheng WANG. Effect of deoxycholic acid on performance of dye-sensitized solar cell based on black dye[J]. Front Optoelec Chin, 2011, 4(1): 80-86.
[11] Shuangying XU, Linhua HU, Jiang SHENG, Dongxing KOU, Huajun TIAN, Songyuan DAI. Electron transportation and optical properties of micro-structure TiO2 films: applied in dye-sensitized solar cells[J]. Front Optoelec Chin, 2011, 4(1): 72-79.
[12] Minghui DENG, Shuqing HUANG, Zhexun YU, Dongmei LI, Yanhong LUO, Yubai BAI, Qingbo MENG. Enhanced electron injection/transportation by surface states increment in mesoporous TiO2 dye-sensitized solar cells[J]. Front Optoelec Chin, 2011, 4(1): 65-71.
[13] Chang-Ryul LEE, Hui-Seon KIM, Nam-Gyu PARK. Dependence of porosity, charge recombination kinetics and photovoltaic performance on annealing condition of TiO2 films[J]. Front Optoelec Chin, 2011, 4(1): 59-64.
[14] Hong LIN, Feng HAO, Jianbao LI. Electrolyte-dependent photovoltaic responses in dye-sensitized solar cells[J]. Front Optoelec Chin, 2011, 4(1): 45-52.
[15] Yang LIU, Hengli ZHANG, Ying YAN, Huaijin ZHANG, Jingliang HE, Jianguo XIN. A 123 W Nd:YVO4 slab laser with high beam quality output[J]. Front Optoelec Chin, 2009, 2(4): 407-409.
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed