|
|
Basic properties of a new Nd-doped laser crystal: Nd:GdNbO4 |
Shoujun DING1,2, Qingli ZHANG1( ), Wenpeng LIU1, Jianqiao LUO1, Dunlu SUN1 |
1. Anhui Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Hefei 230031, China 2. University of Science and Technology of China, Hefei 230026, China |
|
|
Abstract A Nd-doped GdNbO4 single crystals have been grown successfully using the Czochralski technique. The chemical etching method was employed to study the defects in the structural morphology of Nd:GdNbO4 crystal with phosphoric acid etchant. Mechanical properties (such as hardness, yield strength, fracture toughness, and brittle index) of the as-grown crystal were systematically estimated on the basis of the Vickers hardness test for the first time. The transmission spectrum of Nd:GdNbO4 was measured in the wavelength range of 320–2400 nm at room temperature, and the absorption peaks were assigned. Results hold great significance for further research on Nd:GdNbO4.
|
Keywords
Nd:GdNbO4
laser crystal
mechanical properties
chemical etching
|
Corresponding Author(s):
Qingli ZHANG
|
Just Accepted Date: 27 May 2017
Online First Date: 22 June 2017
Issue Date: 05 July 2017
|
|
1 |
Sanghera J, Kim W, Villalobos G, Shaw B, Baker C, Frantz J, Sadowski B, Aggarwal I. Ceramic laser materials. Materials (Basel), 2012, 5(12): 258–277
https://doi.org/10.3390/ma5020258
|
2 |
Zhang H J, Meng X L, Zhu L, Wang C Q, Wang P, Zhang H Z, Chow Y T, Dawes J. Growth and laser properties of laser crystal Nd:Gd0.8La0.2VO4. Journal of Crystal Growth, 1998, 193(3): 370–373
https://doi.org/10.1016/S0022-0248(98)00495-3
|
3 |
Lee M C, Chang C S, Huang Y L, Chang S L, Chang C H, Lin Y F, Hu S. Treatment of melasma with mixed parameters of 1064-nm Q-switched Nd:YAG laser toning and an enhanced effect of ultrasonic application of vitamin C: a split-face study. Lasers in Medical Science, 2015, 30(1): 159–163
https://doi.org/10.1007/s10103-014-1608-2
pmid: 25073866
|
4 |
Kane T J, Kozlovsky W J, ByerR L, Byvik C E. Coherent laser radar at 1.06 μm using Nd:YAG lasers. Optics Letters, 1987, 12(4): 239–241
https://doi.org/10.1364/OL.12.000239
pmid: 19738851
|
5 |
Rodin A M, Grishin M, Michailovas A. Picosecond laser with 11 W output power at 1342 nm based on composite multiple doping level Nd:YVO4 crystal. Optics & Laser Technology, 2016, 76: 46–52
https://doi.org/10.1016/j.optlastec.2015.07.022
|
6 |
Yu H H, Liu J H, Zhang H J, Kaminskii A A, Wang Z P, Wang J Y. Advances in vanadate laser crystals at a lasing wavelength of 1 micrometer. Laser & Photonics Reviews, 2014, 8(6): 847–864
https://doi.org/10.1002/lpor.201400022
|
7 |
Nazarov M, Kim Y J, Lee E Y, Min K, Jeong M S, Lee S W, Noh D Y. Luminescence and Raman studies of YNbO4 phosphors doped by Eu3+, Ga3+, and Al3+. Journal of Applied Physics, 2010, 107(10): 103104
https://doi.org/10.1063/1.3392918
|
8 |
Wang Y Z, Zhang L L, Cao R P, Miao Q, Qiu J Q. Structure and properties of CaNb2O6:Sm3+ thin films by pulsed laser deposition. Applied Physics A, 2014, 115(4): 1365–1370
|
9 |
Ding S J, Peng F, Zhang Q L, Luo J Q, Liu W P, Sun D L, Dou R Q, Sun G H. Structure, spectroscopic properties and laser performance of Nd:YNbO4 at 1066 nm. Optical Materials, 2016, 62: 7–11
https://doi.org/10.1016/j.optmat.2016.09.032
|
10 |
Fang X, Roushan M, Zhang R, Peng J, Zeng H, Li J. Tuning and enhancing white light emission of II–VI based inorganic–organic hybrid semiconductors as single-phased phosphors. Chemistry of Materials, 2012, 24(10): 1710–1717
https://doi.org/10.1021/cm203137r
|
11 |
Jüstel T, Nikol H, Ronda C. New developments in the field of luminescent materials for lighting and displays. Angewandte Chemie International Edition, 1998, 37(22): 3084–3103
https://doi.org/10.1002/(SICI)1521-3773(19981204)37:22<3084::AID-ANIE3084>3.0.CO;2-W
|
12 |
Huang C, Liu W, Chen T. Single-phased white-light phosphors Ca9Gd(PO4)7:Eu 2+, Mn 2+ under near-ultraviolet excitation. Journal of Physical Chemistry C, 2010, 114(43): 18698–18701
https://doi.org/10.1021/jp106693z
|
13 |
Dou R Q, Zhang Q L, Luo J Q, Chen J K, Yang H J, Liu W P, Sun G H, Sun D L. Growth, structure, and spectroscopic properties of 5 at.% Yb:GdNbO4 laser crystal. Optical Materials, 2015, 42: 56–61
https://doi.org/10.1016/j.optmat.2014.12.018
|
14 |
Ding S J, Peng F, Zhang Q L, Luo J Q, Liu W P, Sun D L, Dou R Q, Gao J Y, Sun G H, Cheng M J. Crystal growth, spectral properties, and continuous wave laser operation of Nd:GdNbO4. Journal of Alloys and Compounds, 2017, 693: 339–343
https://doi.org/10.1016/j.jallcom.2016.09.256
|
15 |
Zhong D G, Teng B, Cao L F, Fei Y, Zhang S M, Li Y Y, Wang C, He L X, Huang W X. Characterization of dislocations and sub-grain boundaries in mixed rare earth orthovanadate of Yb:YxLu1-xVO4. Optical Materials, 2014, 36(12): 2034–2038
https://doi.org/ 10.1016/j.optmat.2013.12.033
|
16 |
Dou R Q, Zhang Q L, Liu W P, Luo J Q, Wang X F, Ding S J, Sun D L. Growth, structure, chemical etching, and spectroscopic properties of a 2.9 mm Tm,Ho:GdYTaO4 laser crystal. Optical Materials, 2015, 48: 80–85
https://doi.org/10.1016/j.optmat.2015.07.021
|
17 |
Ding S J, Liu W P, Zhang Q L, Peng F, Luo J Q, Dou R Q, Sun G H, Sun D L. Crystal growth, defects, and mechanical and spectral properties of a novel mixed laser crystal Nd:GdYNbO4. Applied Physics A, 2017, 123: 70
|
18 |
Thirumurugan R, Babu B, Anitha K, Chandrasekaran J. Structural, optical, thermal, mechanical, dielectric and laser damage threshold studies of a succinate salt of creatinine for nonlinear optical applications. Materials Letters, 2016, 185: 214–217
https://doi.org/10.1016/j.matlet.2016.08.127
|
19 |
Mythili P, Kanagasekaran T, Sharma S N, Gopalakrishnan R. Growth and characterization of sodium sulfanilate dihydrate (SSDH) crystals for NLO applications. Journal of Crystal Growth, 2007, 306(2): 344–350
https://doi.org/10.1016/j.jcrysgro.2007.05.025
|
20 |
Hanumantha Rao R, Kalainathan S. Microhardness, chemical etching, SEM, AFM and SHG studies of novel nonlinear optical crystal–l-threonine formate. Materials Research Bulletin, 2012, 47(4): 987–992
https://doi.org/10.1016/j.materresbull.2012.01.013
|
21 |
Singh P, Hasmuddin M, Shakir M, Vijayan N, Abdullah M M, Ganesh V, Wahab M A. Investigation on structural, optical, thermal, mechanical and dielectric properties of l-proline cadmium chloride monohydrate single crystals: an efficient NLO material. Materials Chemistry and Physics, 2013, 142(1): 154–164
https://doi.org/10.1016/j.matchemphys.2013.06.051
|
22 |
Gupta V, Bamzai K K, Kotru P N, Wanklyn B M. Mechanical characteristics of flux-grown calcium titanate and nickel titanate crystals. Materials Chemistry and Physics, 2005, 89(1): 64–71
https://doi.org/10.1016/j.matchemphys.2004.08.027
|
23 |
Jain A, Razdan A K, Kotru P N, Wanklyn B M. Load and directional effects on microhardness and estimation of toughness and brittleness for flux-grown LaBO3 crystals. Journal of Materials Science, 1994, 29(14): 3847–3856
https://doi.org/10.1007/BF00357358
|
24 |
Cahoon J P, Broughton W H, Kutzuk A R. The determination of yield strength from hardness measurements. Metallurgical and Materials Transactions B, Process Metallurgy and Materials Processing Science, 1971, 2(7): 1979–1983
|
25 |
Townsend D, Field J E. Fracture toughness and hardness of zinc sulphide as a function of grain size. Journal of Materials Science, 1990, 25(2): 1347–1352
https://doi.org/10.1007/BF00585448
|
|
Viewed |
|
|
|
Full text
|
|
|
|
|
Abstract
|
|
|
|
|
Cited |
|
|
|
|
|
Shared |
|
|
|
|
|
Discussed |
|
|
|
|