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Frontiers of Optoelectronics

ISSN 2095-2759

ISSN 2095-2767(Online)

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Front. Optoelectron.    2021, Vol. 14 Issue (1) : 37-63    https://doi.org/10.1007/s12200-020-1070-7
REVIEW ARTICLE
Terahertz aqueous photonics
Qi JIN, Yiwen E, Xi-Cheng ZHANG()
The Institute of Optics, University of Rochester, Rochester, NY 14627, USA
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Abstract

Developing efficient and robust terahertz (THz) sources is of incessant interest in the THz community for their wide applications. With successive effort in past decades, numerous groups have achieved THz wave generation from solids, gases, and plasmas. However, liquid, especially liquid water has never been demonstrated as a THz source. One main reason leading the impediment is that water has strong absorption characteristics in the THz frequency regime.

A thin water film under intense laser excitation was introduced as the THz source to mitigate the considerable loss of THz waves from the absorption. Laser-induced plasma formation associated with a ponderomotive force-induced dipole model was proposed to explain the generation process. For the one-color excitation scheme, the water film generates a higher THz electric field than the air does under the identical experimental condition. Unlike the case of air, THz wave generation from liquid water prefers a sub-picosecond (200−800 fs) laser pulse rather than a femtosecond pulse (~50 fs). This observation results from the plasma generation process in water.

For the two-color excitation scheme, the THz electric field is enhanced by one-order of magnitude in comparison with the one-color case. Meanwhile, coherent control of the THz field is achieved by adjusting the relative phase between the fundamental pulse and the second-harmonic pulse.

To eliminate the total internal reflection of THz waves at the water-air interface of a water film, a water line produced by a syringe needle was used to emit THz waves. As expected, more THz radiation can be coupled out and detected. THz wave generation from other liquids were also tested.

Keywords terahertz (THz) wave generation      liquid water      laser-induced plasma     
Corresponding Author(s): Xi-Cheng ZHANG   
Just Accepted Date: 27 October 2020   Online First Date: 16 December 2020    Issue Date: 19 April 2021
 Cite this article:   
Qi JIN,Yiwen E,Xi-Cheng ZHANG. Terahertz aqueous photonics[J]. Front. Optoelectron., 2021, 14(1): 37-63.
 URL:  
https://academic.hep.com.cn/foe/EN/10.1007/s12200-020-1070-7
https://academic.hep.com.cn/foe/EN/Y2021/V14/I1/37
Fig.1  A generic arrangement for a THz time-domain spectroscopy (THz-TDS) system. Pulses from the femtosecond laser are split at the beam splitter (BS). There is a delay stage used to alter the time of arrival at the THz receiver between the THz pulse and the laser pulse
Fig.2  Photo of the water film. Two aluminum wires are separated by 4 mm. The thickness of the water film is controlled by the water flow rate
Fig.3  Thickness of the water film versus the water flow rate
Fig.4  Experimental set-up for THz wave generation from a water film. Broadband THz wave is generated by tightly focusing the laser beam into a gravity-driven wire-guided free-flowing water film [53]. The water film can be moved in the laser propagation direction by a mechanical translation stage. OAPM, off-axis parabolic mirror. HWP, half-wave plate
Fig.5  Measurements of the THz fields when the water film is translated along the direction of laser propagation [53]. (a) THz waveforms are plotted from curve A to curve C when the water film is before, near, and after the focus, respectively; curve B shows the THz waveform generated from liquid water; curve D is the reference with no water film. Yellow spark and bluish pane represent the plasma and the water film respectively. THz emission angle shown in the figure is not meant to be indicative of actual THz emission pattern. (b) THz waveforms when the water film is moved near the focal point. The 0 position is set to the place with the strongest THz field. Relative positions are listed with the corresponding waveforms. The negative sign means the water film is located after the focal point. The positive sign indicates the opposite case. (c) Comparison between the THz field from water and that from air plasma in the frequency domain. The dashed, solid, and dotted spectra correspond to curve A, curve B, and curve D in (a), respectively. The laser pulse is temporally stretched to 550 fs for these measurements
Fig.6  Comparison of THz waves generated from water and air in the (a) time domain and (b) frequency domain
Fig.7  Energy of p-polarized THz field from liquid water with different linearly optical polarization. 0° and 90° refer to p-polarized and s-polarized optical beam respectively [53]
Fig.8  Normalized THz energy from liquid water as a function of incident optical pulse energy [53]. The water film will be broken if the energy of the excitation pulse is over 420 µJ
Fig.9  THz wave generation from water films with different thicknesses. The refractive index of water at 0.5 THz is calculated to be 2.29 from the time shift of the THz field. The absorption coefficient of water at 0.5 THz is calculated to be 146.2 cm-1 from the attenuation of the THz field’s amplitude
Fig.10  Photo of a 120 µm thick water film formed by a water jet with a flat nozzle [62]. The laser beam is focused into the center of the film where is flat and stable
Fig.11  Normalized THz energy as a function of the optical pulse energy [62]. The red line shows a linear fit
Fig.12  2D cross-section of the THz wave generation process in a water film [62]. Intense pulses ionize water at the focal point in the direction of the refracted laser beam. The angle of incidence on the air-water interface is a. The black arrow shows the dipole orientation direction. Due to the total internal reflection at the water-air interface, THz emission at 0.5 THz can be coupled out only when -24.6°<qt<+ 24.6°
Fig.13  Visualization diagram of laser-induced plasma formation
Fig.14  Illustration of incident angle a and angle of detection b [62]. All angles are defined with respect to the z-axis
Fig.15  THz waveforms generated from a water film with opposite angles of incidence (a =±65°) [62]. The corresponding spectra and dipole approximation illustration are shown in the insets
Fig.16  Simulation result of normalized THz energy ITHz(a, b) using the dipole radiation model [62]. The dashed lines indicate the cases of |ab| = 90°, which means the detector is located in the plane of the water film. These dash lines separate the plots into three parts, labeled as “B”, “F”, and “B”. “B” and “F” indicate backward and forward propagating THz signal, respectively
Fig.17  THz energy versus the angle of incidence a with b = 0° [62]. The black squares are the data measured by EOS and the blue dots are measured by a Golay cell. Only forward propagating signals can be detected for b = 0°
Fig.18  THz energy versus the angle of incidence a with b = 55° [62]. The blue dots are measured by a Golay cell. Backward propagating signals are detected for -90°<a<-35°
Fig.19  Normalized THz energy from liquid water and air plasma with different pulse duration of the laser beam [53]. Black squares represent the THz energy from liquid water and red dots represent the case of air plasma. The optical pulse duration is at its minimum of 58 fs when no frequency chirp is applied. On the left-hand side of the figure, negative chirps are applied to increase the optical pulse duration while the case of positive chirps is shown on the right-hand side of the figure. The energy of the laser pulse is 0.4 mJ for these measurements
Fig.20  Spectra of THz radiation generated from the water film with a negative chirped 663 fs pulse and that with a positive chirped 647 fs pulse
Fig.21  Schematic diagram of THz wave generation from a two-color laser pulses induced air plasma. An intense femtosecond laser beam w and its second harmonic 2w are focused to generate plasma in the air. In the most common way, a b-BBO crystal is applied for the generation of 2w pulse. The output THz waves are determined by the phase delay between w pulse and 2w pulse
Fig.22  Schematic diagram of the experimental setup. A phase compensator composed of an a-BBO crystal, a pair of wedges, and a dual-wavelength wave plate (DWP) is applied to control the relative phase between w and 2w pulses. PM, parabolic mirror with an effective focal length of 1-inch
Fig.23  Comparison of THz waves generated from a 120 mm thick water film with one-color and two-color excitation schemes [95]. (a) and (b) Comparison in the case of a short optical pulse duration (58 fs) in the time domain and frequency domain, respectively. (c) and (d) Comparison in the case of a long optical pulse duration (300 fs) in the time domain and frequency domain, respectively. Unified normalization ratios are labeled
Fig.24  Modulation of THz wave generation from a water film [95]. (a) Comparison of THz waveforms obtained when the relative phase between w and 2w pulses is changed by p through the change of the insertion of one of the wedges in the phase compensator. Inset, THz electric field as a function of the phase delay between w and 2w pulses. (b) An overall phase scan for THz wave radiation from the water film obtained by gradually changing the phase between w and 2w pulses while monitoring the THz energy by using a Golay cell. The range of the phase delay is limited by the full length of the wedge
Fig.25  Normalized THz energy from liquid water as a function of the total excitation optical pulse (w and 2w) energy [95]. Blue squares, THz energy calculated from the temporal integral of the THz waveform measured by EOS. Blue dots, modulated THz energy measured by the Golay cell. Red circles, unmodulated THz energy measured by the Golay cell. The maximum pulse energy is limited by the available laser pulse energy in the experiment
Fig.26  Photograph of syringe needles. The color of a syringe needle indicates its gauge number and inner diameter
Fig.27  Photograph of the water line produced by a syringe needle with 260 mm inner diameter [98]. The diameter of the water line is 260 mm as well. The flow velocity is about 7 m/s along the y-direction. The laser beam propagates in the z-direction. The water line can be moved along the x-direction by a translation stage
Fig.28  (a) THz peak fields with different x positions when the 260 mm diameter water line is crossing the laser focal point along the x-direction. (b) THz waveforms of x =±90 mm in (a) [98]
Fig.29  Comparison of THz fields generated from a 210 mm water line and a 120 mm water film. EPL, effective path length. A shift of the 210 mm water line in the x-direction makes the EPL to be 158 mm. Oblique incidence on the 120 mm water film leads to a 151 mm EPL
Fig.30  Effect of optical pulse duration on THz energy and peak electron density for a 210 mm water line [98]. The black dots are the experimental data for THz energy. The red curve is the simulation data for peak electron density
Fig.31  Optimal optical pulse duration versus the diameter of the water line [98]. The blue squares are simulations of optimal pulse duration aiming for the highest electron density. The red dots are the experimental data of optimal pulse duration obtained with the strongest THz energy
Fig.32  THz energy versus the diameter of the water line
Fig.33  Waveform measurement of a-Pinene as the sample by using a standard THz-TDS system. The black curve is the reference waveform with no sample presented
Fig.34  Measured results of refractive index and field absorption coefficient of a-Pinene in the frequency region 0.5−2.5 THz [98]
Fig.35  Comparison of THz waves generated from a-Pinene and water in (a) time domain and (b) frequency domain [98]. The diameter of the liquid line is 210 mm. Laser pulse energy is 0.4 mJ. Optical pulse durations are individually optimized for a-Pinene and water. Both have a value around 345 fs. The dash line in (b) is calculated by removing the absorption of a-Pinene and adding the absorption of water to the black curve from 0.5 to 2.5 THz
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