Advances in self-assembled ultrathin polyoxomolybdates multilayers
Advances in self-assembled ultrathin polyoxomolybdates multilayers
Liang-bao YANG1, Xiu-fang WANG1, An-jian XIE1,2, Gang HU1, Yu-hua SHEN1,2()
1. School of Chemistry and Chemical Engineering, Anhui University, Hefei 230039, China; 2. State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, China
The research on the assembly and function of organized molecular films has gained more and more interest. Electrostatic interactions can be employed to assemble polyoxomolybdates in surface confined multilayers. Ultrathin multilayer films of polyoxomolybdates and organic molecules by the self-assembly method have been reviewed. At the same time, self-assemblies in aqueous solution are also reported, such as wheel-shaped clusters (Mo154), hollow spherical “blackberry”-like vesicles (Mo72Fe30) and Keggin structures. Polyoxomolybdate multilayers are promising candidates for diverse applications including electrocatalytic, photo- and electro-chromic systems. The development in this particular field of materials science may be highlighted in the future.
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