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Frontiers of Materials Science

ISSN 2095-025X

ISSN 2095-0268(Online)

CN 11-5985/TB

邮发代号 80-974

2019 Impact Factor: 1.747

Frontiers of Materials Science in China  2009, Vol. 3 Issue (3): 285-300   https://doi.org/10.1007/s11706-009-0045-9
  RESEARCH ARTICLE 本期目录
Vibrational dynamics of Zr-based bulk metallic glasses
Vibrational dynamics of Zr-based bulk metallic glasses
Aditya M. VORA()
Humanities and Social Science Department, STBS College of Diploma Engineering, Opp. Spinning Mill, Varachha Road, Surat 395006, South Gujarat, India
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Abstract

The vibrational dynamics of some Zr-based bulkmetallic glasses were studied at room temperature in terms of phonon eigen frequencies of longitudinal and transverse modes employing three different approaches proposed by Hubbard-Beeby (HB), Takeno-Goda (TG) and Bhatia-Singh (BS). The well recognized model potential is employed successfully to explain electron-ion interaction in the metallic glass. The present findings of phonon dispersion curve are found to be in fair agreement with available theoretical as well as experimental data. The thermodynamic properties obtained by the HB and TG approaches are found to be much lower than those obtained by the BS approach.

Key wordspair potential    Zr-based bulk metallic glasses    phonon dispersion curves    thermal properties    elastic properties
收稿日期: 2009-02-05      出版日期: 2009-09-05
Corresponding Author(s): M. VORA Aditya,Email:voraam@yahoo.com   
 引用本文:   
. Vibrational dynamics of Zr-based bulk metallic glasses[J]. Frontiers of Materials Science in China, 2009, 3(3): 285-300.
Aditya M. VORA. Vibrational dynamics of Zr-based bulk metallic glasses. Front Mater Sci Chin, 2009, 3(3): 285-300.
 链接本文:  
https://academic.hep.com.cn/foms/CN/10.1007/s11706-009-0045-9
https://academic.hep.com.cn/foms/CN/Y2009/V3/I3/285
GlassZΩ0/aurC/auZdNCrd/au
Zr17Ni833.66142.730.70843.52122.44
Zr33Ni673.34129.540.71044.48122.23
Zr50Ni503.00115.520.73865.50122.00
Zr67Ni332.66101.500.71486.52121.78
Zr83Ni172.3488.310.71687.48121.57
Tab.1  
Fig.1  
Fig.2  
Fig.3  
Fig.4  
Fig.5  
Fig.6  
Fig.7  
App.SCRvL×105/(cm?s-1)vT×105 /(cm?s-1)BT×1011 /(dyne?cm-2)a)G×1011 /(dyne?cm-2)a)σY×1011 /(dyne?cm-2)a)θD/K
HBH1.82461.05341.33200.79920.25001.9979131.59
T1.83371.05871.34530.80720.25002.0179132.24
IU0.92790.53570.34450.20670.25000.516766.92
F0.91520.52840.33510.20110.25000.502766.00
S1.51970.87740.92400.55440.25001.3860109.60
TGH2.70701.41733.34861.44660.31123.7935178.37
T2.78021.60843.08251.8630.24854.6519200.87
IU2.75031.71472.62432.11740.18215.0058212.58
F2.80321.75942.68662.22940.17505.2391217.98
S2.10551.857000.11882.48351.25131.2481216.78
BSH7.17693.444225.02348.31690.350422.4621431.84
T7.29843.567925.44588.92540.34323.9732446.91
IU7.25083.520125.27778.68740.345823.3835441.08
F7.22613.502725.14048.60170.346423.1634438.94
S7.36433.623625.74869.20590.340324.6768453.72
Others [17]4.67, 4.362.59, 2.281.29, 9.04.99, 3.87---
MD [17]4.342.139.53.37---
Tab.2  
App.SCRvL×105/(cm?s-1)vT×105 /(cm?s-1)BT×1011 /(dyne?cm-2)a)G×1011 /(dyne?cm-2)a)σY×1011 /(dyne?cm-2)a)θD/K
HBH1.81291.04671.30370.78220.25001.9556130.37
T1.84161.06321.34530.80720.25002.0179132.43
IU0.90810.52430.32710.19630.25000.490765.31
F0.89370.5160.31680.19010.25000.475264.27
S1.54390.89140.94550.56730.25001.4182111.02
TGH2.69911.41473.29631.42900.31063.7457177.52
T2.78551.60943.07391.84950.24944.6216200.45
IU2.74061.71052.57752.08900.18104.9340211.43
F2.79331.75532.63782.19990.17375.1640216.81
S2.08521.85230.16182.44981.37071.8164215.22
BSH7.17693.444225.02348.31690.350422.4621431.84
T7.29843.567925.44588.92540.34323.9732446.91
IU7.25083.520125.27778.68740.345823.3835441.08
F7.22613.502725.14048.60170.346423.1634438.94
S7.36433.623625.74869.20590.340324.6768453.72
Others [17]5.11, 4.952.68, 2.811.50, 10.25.29, 5.82---
MD [17]4.672.1611.53.44---
Tab.3  
App.SCRvL×105/(cm?s-1)vT×105 /(cm?s-1)BT×1011 /(dyne?cm-2)a)G×1011 /(dyne?cm-2)a)σY×1011 /(dyne?cm-2)a)θD/K
HBH1.78091.02821.29260.77550.25001.9389132.33
T1.70410.98381.18350.71010.25001.7752126.62
IU1.03480.59740.43640.26180.25000.654676.89
F1.01740.58740.42190.25310.24990.632875.60
S1.50310.86780.92080.55250.25001.3812111.69
TGH2.61201.26643.43631.17660.34633.1682164.99
T2.63851.51732.85511.68890.25294.2322195.35
IU2.59431.54072.61531.74140.22754.2753197.78
F2.63961.58042.66821.83230.22064.4730202.72
S2.34001.34822.23911.33340.25163.3376173.54
BSH6.89303.201124.83327.51700.362520.4841417.93
T7.09213.397025.61018.46550.351122.8760442.83
IU7.05813.355625.53188.26020.354022.3683437.60
F7.02583.329725.36708.13300.355222.0433434.29
S7.15853.459925.88308.78180.347623.6686450.82
Others [12,17]9.11,9.53,4.626.58,6.96,2.711.74,1.80,8.305.26--370.50,419.90,443.77
MD [17]4.652.1111.13.19---
Tab.4  
App.SCRvL×105/(cm?s-1)vT×105 /(cm?s-1)BT×1011 /(dyne?cm-2)a)G×1011 /(dyne?cm-2)a)σY×1011 /(dyne?cm-2)a)θD/K
HBH1.78901.03291.24660.74800.24991.8699127.87
T1.80801.04381.27320.76390.25001.9099129.23
IU0.86880.50160.29400.17640.25000.441062.10
F0.85070.49110.28190.16910.25000.422860.80
S1.59120.91870.98620.59170.24991.4793113.73
TGH2.41171.36522.33571.30670.26423.3041169.30
T2.80001.61363.06261.82560.25144.5689199.80
IU2.72451.70352.49132.03470.17904.7979209.26
F2.77671.74842.54792.14330.17155.0217214.60
S2.40251.47652.00891.52840.19663.6576181.70
BSH7.17693.444225.02348.31690.350422.4621431.84
T7.29843.567925.44588.92540.343023.9732446.91
IU7.25083.520125.27778.68740.345823.3835441.08
F7.22613.502725.14048.60170.346423.1634438.94
S7.36433.623625.74869.20590.340324.6768453.72
Others [11,17]5.00, 4.19, 4.75, 4.462.50, 2.05, 1.95, 1.881.176,0.846,10.42.43--311,256,254±11,372.53
MD [11]4.102.027.82.80---
Tab.5  
App.SCRvL×105/(cm?s-1)vT×105 /(cm?s-1)BT×1011 /(dyne?cm-2)a)G×1011 /(dyne?cm-2)a)σY×1011 /(dyne?cm-2)a)θD/K
HBH1.77811.02661.22100.73260.25001.8314126.73
T1.81731.04921.27550.76530.25001.9133129.53
IU0.85160.49170.28010.1680.25000.420160.70
F0.83170.48020.26710.16030.25000.400759.28
S1.61160.93041.00300.60180.25001.5045114.86
TGH2.41821.36712.33291.29920.26513.2874169.07
T2.80781.61623.05931.81590.25224.5478199.57
IU2.71851.7012.45572.01130.17834.7398208.33
F2.77051.74582.51092.11880.17074.9610213.66
S2.39111.47811.94961.51870.19083.6169181.27
BSH7.17693.444225.02348.31690.350422.4621431.84
T7.29843.567925.44588.92540.343023.9732446.91
IU7.25083.520125.27778.68740.345823.3835441.08
F7.22613.502725.14048.60170.346423.1634438.94
S7.36433.623625.74869.20590.340324.6768453.72
Others [17]4.322.377.23.64---
MD [17]4.271.809.02.10---
Tab.6  
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