Facile preparation of low swelling, high strength, self-healing and pH-responsive hydrogels based on the triple-network structure

doi:10.1007/s11706-019-0450-7

Frontiers of Materials Science

2019, Vol. 13

Issue (1): 54-63 https://doi.org/10.1007/s11706-019-0450-7

本期目录

Facile preparation of low swelling, high strength, self-healing and pH-responsive hydrogels based on the triple-network structure

Zhicun WANG¹, Xiaoman HAN¹, Yixi WANG¹, Kenan MEN², Lin CUI³(

), Jianning WU¹, Guihua MENG¹, Zhiyong LIU¹(

), Xuhong GUO^1,⁴

¹. School of Chemistry and Chemical Engineering, Shihezi University/Key Laboratory for Green Processing of Chemical Engineering of Xinjiang Bingtuan/Key Laboratory of Materials-Oriented Chemical Engineering of Xinjiang Uygur Autonomous Region/Engineering Research Center of Materials-Oriented Chemical Engineering of Xinjiang Bingtuan, Shihezi 832003, China
². Bingtuan Sishi Hospital, Yili 835000, China
³. School of Medicine, Shihezi University, Shihezi 832003, China
⁴. State Key Laboratory of Chemical Engineering, East China University of Science and Technology, Shanghai 200237, China

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Abstract：

A polyacrylic acid (PAA)/gelatin (Gela)/polyvinyl alcohol (PVA) hydrogel was prepared by copolymerization, cooling, and freezing/thawing methods. This triple-network (TN) structure hydrogel displayed superior mechanical properties, low swelling ratio and self-healing properties. The superior mechanical properties are attributed to the triple helix association of Gela and PVA crystallites by reversible hydrogen bonding. The characterization results indicated that the fracture stress and the strain were 808 kPa and 370% respectively, while the compression strength could reach 4443 kPa and the compressive modulus was up to 39 MPa under the deformation of 90%. The hydrogen bonding in PVA contributed to maintain and improve the self-healing ability of hydrogels. Every type of hydrogels exhibited a higher swelling ratio under alkaline conditions, and the swelling ratios of PAA, PAA/PVA and PAA/Gela hydrogels were 27.71, 12.30 and 9.09, respectively. The PAA/Gela/PVA TN hydrogel showed the lowest swelling ratio (6.57) among these hydrogels. These results indicate that the novel TN hydrogels possess good environmental adaptability and have potential applications in the biomedical engineering and sensor field.

Key words： hydrogel triple-network structure mechanical property swelling self-healing

收稿日期: 2018-10-10 出版日期: 2019-03-07

Corresponding Author(s): Lin CUI,Zhiyong LIU

引用本文:

. [J]. Frontiers of Materials Science, 2019, 13(1): 54-63.
Zhicun WANG, Xiaoman HAN, Yixi WANG, Kenan MEN, Lin CUI, Jianning WU, Guihua MENG, Zhiyong LIU, Xuhong GUO. Facile preparation of low swelling, high strength, self-healing and pH-responsive hydrogels based on the triple-network structure. Front. Mater. Sci., 2019, 13(1): 54-63.

链接本文:

https://academic.hep.com.cn/foms/CN/10.1007/s11706-019-0450-7
https://academic.hep.com.cn/foms/CN/Y2019/V13/I1/54

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