1. Department of Physics, Harbin Institute of Technology, Harbin 150001, China 2. School of Materials Science and Engineering, Jingdezhen Ceramic Institute, Jingdezhen 333001, China 3. School of Mechanical and Electronic Engineering, Jingdezhen Ceramic Institute, Jingdezhen 333403, China
No-precious bifunctional catalysts with high electrochemical activities and stability were crucial to properties of rechargeable zinc–air batteries. Herein, LaNiO3 modified with Ag nanoparticles (Ag/LaNiO3) was prepared by the co-synthesis method and evaluated as the bifunctional oxygen catalyst for oxygen reduction reaction (ORR) and oxygen evolution reaction (OER). Compared with LaNiO3, Ag/LaNiO3 demonstrated the enhanced catalytic activity towards ORR/OER as well as higher limited current density and lower onset potential. Moreover, the potential gap between ORR potential (at −3 mA·cm−2) and OER potential (at 5 mA·cm−2) was 1.16 V. The maximum power density of the primary zinc–air battery with Ag/LaNiO3 catalyst achieved 60 mW·cm−2. Furthermore, rechargeable zinc–air batteries operated reversible charge–discharge cycles for 150 cycles without noticeable performance deterioration, which showed its excellent bifunctional activity and cycling stability as oxygen electrocatalyst for rechargeable zinc–air batteries. These results indicated that Ag/LaNiO3 prepared by the co-synthesis method was a promising bifunctional catalyst for rechargeable zinc–air batteries.
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