Revealing component synergy of Ni‒Fe/black phosphorous composites synthesized by self-designed electrochemical method for enhancing photoelectrocatalytic oxygen evolution reaction
He Xiao1, Shoufeng Xue1, Zimei Fu1, Man Zhao1(), Li Zhang1, Junming Zhang1, Haishun Wu1, Jianfeng Jia1(), Nianjun Yang2()
1. Key Laboratory of Magnetic Molecules & Magnetic Information Materials (Ministry of Education), School of Chemistry and Materials Science, Shanxi Normal University, Taiyuan 030032, China 2. Department of Chemistry, Hasselt University, 3590 Diepenbeek, Belgium
Developing high-activity and low-cost catalysts is the key to eliminate the limitation of sluggish anodic oxygen evolution reaction (OER) during electrocatalytic overall water splitting. Herein, Ni‒Fe/black phosphorous (BP) composites are synthesized using a simple three-electrode system, where exfoliation of bulky BP and synthesis of NiFe composites are simultaneously achieved. Under light illumination, the optimized Ni‒Fe/BP composite exhibits excellent photoelectrocatalytic OER performance (e.g., the overpotential is 58 mV lower than a commercial RuO2 electrocatalyst at a current density of 10 mA·cm−2). The electron transfer on this composite is proved to follow a Ni‒BP‒Fe pathway. The electronic structure of this Ni‒Fe/BP composite is effectively regulated, leading to optimized adsorption strength of the intermediate OH* and improved intrinsic activity for the OER. Together with active sites on the support, this Ni‒Fe/BP composite possesses abundant electrochemical active sites and a bug surface area for the OER. The introduction of light further accelerates the electrocatalytic OER. This work provides a novel and facile method to synthesize high-performance metal/BP composites as well as the approaches to reveal their OER mechanisms.
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