Please wait a minute...
Frontiers of Materials Science

ISSN 2095-025X

ISSN 2095-0268(Online)

CN 11-5985/TB

邮发代号 80-974

2019 Impact Factor: 1.747

Frontiers of Materials Science  2023, Vol. 17 Issue (4): 230665   https://doi.org/10.1007/s11706-023-0665-5
  本期目录
Highly sensitive flexible strain sensor based on microstructured biphasic hydrogels for human motion monitoring
Xin Gao1,2, Xinyu Wang2, Xingce Fan1()
1. Key Laboratory of Quantum Materials and Devices of Ministry of Education, School of Physics, Southeast University, Nanjing 211189, China
2. School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, China
 全文: PDF(9394 KB)   HTML
Abstract

Flexible strain sensors have been extensively used in human motion detection, medical aids, electronic skins, and other civilian or military fields. Conventional strain sensors made of metal or semiconductor materials suffer from insufficient stretchability and sensitivity, imposing severe constraints on their utilization in wearable devices. Herein, we design a flexible strain sensor based on biphasic hydrogel via an in-situ polymerization method, which possesses superior electrical response and mechanical performance. External stress could prompt the formation of conductive microchannels within the biphasic hydrogel, which originates from the interaction between the conductive water phase and the insulating oil phase. The device performance could be optimized by carefully regulating the volume ratio of the oil/water phase. Consequently, the flexible strain sensor with oil phase ratio of 80% demonstrates the best sensitivity with gauge factor of 33 upon a compressive strain range of 10%, remarkable electrical stability of 100 cycles, and rapid resistance response of 190 ms. Furthermore, the human motions could be monitored by this flexible strain sensor, thereby highlighting its potential for seamless integration into wearable devices.

Key wordsflexible strain sensor    biphasic hydrogel    conductive hydrogel    human motion monitoring
收稿日期: 2023-07-31      出版日期: 2023-10-23
Corresponding Author(s): Xingce Fan   
 引用本文:   
. [J]. Frontiers of Materials Science, 2023, 17(4): 230665.
Xin Gao, Xinyu Wang, Xingce Fan. Highly sensitive flexible strain sensor based on microstructured biphasic hydrogels for human motion monitoring. Front. Mater. Sci., 2023, 17(4): 230665.
 链接本文:  
https://academic.hep.com.cn/foms/CN/10.1007/s11706-023-0665-5
https://academic.hep.com.cn/foms/CN/Y2023/V17/I4/230665
Fig.1  
Fig.2  
Fig.3  
Fig.4  
Fig.5  
1 B H, Zheng H W, Zhou Z, Wang et al.. Fishing net-inspired mutiscale ionic organohydrogels with outstanding mechanical robustness for flexible electronic devices.Advanced Functional Materials, 2023, 33(28): 2213501
https://doi.org/10.1002/adfm.202213501
2 X, Xiao Z Y, Zheng X W, Zhong et al.. Rational design of flexible Zn-based batteries for wearable electronic devices.ACS Nano, 2023, 17(3): 1764–1802
https://doi.org/10.1021/acsnano.2c09509
3 X F, Gong Z Y, Chu G C, Li et al.. Efficient fabrication of carbon nanotube-based stretchable electrodes for flexible electronic devices.Macromolecular Rapid Communications, 2023, 44(5): 2200795
https://doi.org/10.1002/marc.202200795
4 Y, Wu C, Chen Y, Meng et al.. Flexible carbon-based 3D conductive network structure blade-coated on poly(ethylene terephthalate) substrate for light-emitting electronic devices.Advanced Engineering Materials, 2022, 24(7): 2101355
https://doi.org/10.1002/adem.202101355
5 J, Lu J F, Gu O D, Hu et al.. Highly tough, freezing-tolerant, healable and thermoplastic starch/poly(vinyl alcohol) organohydrogels for flexible electronic devices.Journal of Materials Chemistry A: Materials for Energy and Sustainability, 2021, 9(34): 18406–18420
https://doi.org/10.1039/D1TA04336F
6 H, Li J Q, Cao J L, Chen et al.. Highly sensitive MXene helical yarn/fabric tactile sensors enabling full scale movement detection of human motions.Advanced Electronic Materials, 2022, 8(4): 2100890
https://doi.org/10.1002/aelm.202100890
7 X Y, Lu Y F, Qin X Z, Chen et al.. An ultra-wide sensing range film strain sensor based on a branch-shaped PAN-based carbon nanofiber and carbon black synergistic conductive network for human motion detection and human-machine interfaces.Journal of Materials Chemistry C: Materials for Optical and Electronic Devices, 2022, 10(16): 6296–6305
https://doi.org/10.1039/D1TC05886J
8 Y, Zong S, Tan J Z Ma . Flame-retardant PEDOT:PSS/LDHs/leather flexible strain sensor for human motion detection.Macromolecular Rapid Communications, 2022, 43(8): 2100873
https://doi.org/10.1002/marc.202100873
9 B D, Pendley E Lindner . Designing medical, point of care sensors to aid health care providers in diagnosing and managing diseases: addressing pertinent issues and some contemporary opportunities.Electroanalysis, 2018, 30(2): 310–313
https://doi.org/10.1002/elan.201700694
10 X L, Zhao Q L, Hua R M, Yu et al.. Flexible, stretchable and wearable multifunctional sensor array as artificial electronic skin for static and dynamic strain mapping.Advanced Electronic Materials, 2015, 1(7): 1500142
https://doi.org/10.1002/aelm.201500142
11 W W, Peng L, Han H L, Huang et al.. A direction-aware and ultrafast self-healing dual network hydrogel for a flexible electronic skin strain sensor.Journal of Materials Chemistry A: Materials for Energy and Sustainability, 2020, 8(48): 26109–26118
https://doi.org/10.1039/D0TA08987G
12 C, Han H, Zhang Q, Chen et al.. A directional piezoelectric sensor based on anisotropic PVDF/MXene hybrid foam enabled by unidirectional freezing.Chemical Engineering Journal, 2022, 450(11): 138280
https://doi.org/10.1016/j.cej.2022.138280
13 J T, Wu F, Ye F, Hugo et al.. Strain response of a semi-rigid base asphalt pavement based on heavy-load full-scale accelerated pavement testing with fibre Bragg grating sensors.Road Materials and Pavement Design, 2015, 16(2): 316–333
https://doi.org/10.1080/14680629.2014.995211
14 T Y, Jin S H K, Park D W, Fang et al.. Highly-stable flexible pressure sensor using piezoelectric polymer film on metal oxide TFT.RSC Advances, 2022, 12(33): 21014–21021
https://doi.org/10.1039/D2RA02613A
15 J, Lee M, Lim J, Yoon et al.. Transparent, flexible strain sensor based on a solution-processed carbon nanotube network.ACS Applied Materials & Interfaces, 2017, 9(31): 26279–26285
https://doi.org/10.1021/acsami.7b03184
16 Y, Song J I, Lee S, Pyo et al.. A highly sensitive flexible strain sensor based on the contact resistance change of carbon nanotube bundles.Nanotechnology, 2016, 27(20): 205502
https://doi.org/10.1088/0957-4484/27/20/205502
17 O, Kanoun C, Muller A, Benchirouf et al.. Flexible carbon nanotube films for high performance strain sensors.Sensors, 2014, 14(6): 10042–10071
https://doi.org/10.3390/s140610042
18 J, Chen J J, Zhang Z B, Luo et al.. Superelastic, sensitive, and low hysteresis flexible strain sensor based on wave-patterned liquid metal for human activity monitoring.ACS Applied Materials & Interfaces, 2020, 12(19): 22200–22211
https://doi.org/10.1021/acsami.0c04709
19 H P, Wu H C, Qi X, Wang et al.. Stretchable, sensitive, flexible strain sensor incorporated with patterned liquid metal on hydrogel for human motion monitoring and human–machine interaction.Journal of Materials Chemistry C: Materials for Optical and Electronic Devices, 2022, 10(21): 8206–8217
https://doi.org/10.1039/D2TC01012G
20 T, Ji S, Jung A K Varadan . Field-controllable flexible strain sensors using pentacene semiconductors.IEEE Electron Device Letters, 2007, 28(12): 1105–1107
https://doi.org/10.1109/LED.2007.909977
21 S J, Kim S, Mondal B K, Min et al.. Highly sensitive and flexible strain–pressure sensors with cracked paddy–shaped MoS2/graphene foam/Ecoflex hybrid nanostructures.ACS Applied Materials & Interfaces, 2018, 10(42): 36377–36384
https://doi.org/10.1021/acsami.8b11233
22 Y M, Wang Y, Wang Y Yang . Graphene–polymer nanocomposite-based redox-induced electricity for flexible self-powered strain sensors.Advanced Energy Materials, 2018, 8(22): 1800961
https://doi.org/10.1002/aenm.201800961
23 B L, Chen Y, Liu G S, Wang et al.. Low-cost flexible strain sensor based on thick CVD graphene.Nano, 2018, 13(11): 1850126
https://doi.org/10.1142/S1793292018501266
24 X Y, Chen X Z, Zhang D, Xiang et al.. 3D printed high-performance spider web-like flexible strain sensors with directional strain recognition based on conductive polymer composites.Materials Letters, 2022, 306(11): 130935
https://doi.org/10.1016/j.matlet.2021.130935
25 Z Y, Pan J Z, Ma W B, Zhang et al.. Flexible conductive polymer composites in strain sensors.Progress in Chemistry, 2020, 32(10): 1592–1607
https://doi.org/10.7536/PC200322
26 C, Cochrane M, Lewandowski V Koncar . A flexible strain sensor based on a conductive polymer composite for in situ measurement of parachute canopy deformation.Sensors, 2010, 10(9): 8291–8303
https://doi.org/10.3390/s100908291
27 J C, Yeo J H, Yu Z M, Koh et al.. Wearable tactile sensor based on flexible microfluidics.Lab on a Chip, 2016, 16(17): 3244–3250
https://doi.org/10.1039/C6LC00579A
28 C J, Zhang H, Li A M, Huang et al.. Rational design of a flexible CNTs@PDMS film patterned by bio-inspired templates as a strain sensor and supercapacitor.Small, 2019, 15(18): 1805493
https://doi.org/10.1002/smll.201805493
29 X X, Gong G T, Fei W B, Fu et al.. Flexible strain sensor with high performance based on PANI/PDMS films.Organic Electronics, 2017, 47(11): 51–56
https://doi.org/10.1016/j.orgel.2017.05.001
30 M C, Qu Y J, Qin Y, Sun et al.. Biocompatible, flexible strain sensor fabricated with polydopamine-coated nanocomposites of nitrile rubber and carbon black.ACS Applied Materials & Interfaces, 2020, 12(37): 42140–42152
https://doi.org/10.1021/acsami.0c11937
31 S, Tadakaluru W, Thongsuwan P Singjai . Stretchable and flexible high-strain sensors made using carbon nanotubes and graphite films on natural rubber.Sensors, 2014, 14(1): 868–876
https://doi.org/10.3390/s140100868
32 M C, Wang H W, Zhou X L, Jin et al.. Highly compliant and low strain hysteresis sensory electronic skins based on solution processable hybrid hydrogels.Journal of Materials Chemistry C: Materials for Optical and Electronic Devices, 2021, 9(5): 1822–1828
https://doi.org/10.1039/D0TC05255H
33 Y, Cheng K H, Chan X Q, Wang et al.. Direct-ink-write 3D printing of hydrogels into biomimetic soft robots.ACS Nano, 2019, 13(11): 13176–13184
https://doi.org/10.1021/acsnano.9b06144
34 Y, Ma C X, Yang E X, Liang et al.. Facile synthesis of ultra-tensile hydrogels for flexible all-solid-state supercapacitor energy storage devices.Journal of Sol-Gel Science and Technology, 2022, 103(2): 335–344
https://doi.org/10.1007/s10971-022-05833-w
35 L X, Zheng L T, Guan G, Yang et al.. One-pot synthesis of CoFe2O4/rGO hybrid hydrogels with 3D networks for high capacity electrochemical energy storage devices.RSC Advances, 2018, 8(16): 8607–8614
https://doi.org/10.1039/C8RA00285A
36 Z X, Zhang L, Tang C, Chen et al.. Liquid metal-created macroporous composite hydrogels with self-healing ability and multiple sensations as artificial flexible sensors.Journal of Materials Chemistry A: Materials for Energy and Sustainability, 2021, 9(2): 875–883
https://doi.org/10.1039/D0TA09730F
37 L L, Fan M H, Duan Z C, Xie et al.. Injectable and radiopaque liquid metal/calcium alginate hydrogels for endovascular embolization and tumor embolotherapy.Small, 2020, 16(2): 1903421
https://doi.org/10.1002/smll.201903421
38 Z H, Qin X, Sun Q Y, Yu et al.. Carbon nanotubes/hydrophobically associated hydrogels as ultrastretchable, highly sensitive, stable strain, and pressure sensors.ACS Applied Materials & Interfaces, 2020, 12(4): 4944–4953
https://doi.org/10.1021/acsami.9b21659
39 Z, Zhang L Lucia . Toward synergistic reinforced graphene nanoplatelets composite hydrogels with self-healing and multi-stimuli responses.Polymer, 2021, 234(11): 124228
https://doi.org/10.1016/j.polymer.2021.124228
40 T L, Gao X, Gao T Q, Li et al.. Microstructured biphasic hydrogels for highly sensitive and asymmetric sensors with temperature-dependent sensitivity.Journal of Polymer Science, 2022, 60(18): 2701–2709
https://doi.org/10.1002/pol.20210720
41 M, Amjadi K U, Kyung I, Park et al.. Stretchable, skin-mountable, and wearable strain sensors and their potential applications: a review.Advanced Functional Materials, 2016, 26(11): 1678–1698
https://doi.org/10.1002/adfm.201504755
42 T, Wang Y, Zhang Q, Liu et al.. A self-healable, highly stretchable, and solution processable conductive polymer composite for ultrasensitive strain and pressure sensing.Advanced Functional Materials, 2018, 28(7): 1705551
https://doi.org/10.1002/adfm.201705551
43 J, Duan X, Liang J, Guo et al.. Ultra-stretchable and force-sensitive hydrogels reinforced with chitosan microspheres embedded in polymer networks.Advanced Materials, 2016, 28(36): 8037–8044
https://doi.org/10.1002/adma.201602126
44 Y, Wang R, Yang Z, Shi et al.. Super-elastic graphene ripples for flexible strain sensors.ACS Nano, 2011, 5(5): 3645–3650
https://doi.org/10.1021/nn103523t
45 Y Z, Zhang K H, Lee D H, Anjum et al.. MXenes stretch hydrogel sensor performance to new limits.Science Advances, 2018, 4(6): eaat0098
https://doi.org/10.1126/sciadv.aat0098
46 W H, Lee C W, Lee G D, Cha et al.. Floatable photocatalytic hydrogel nanocomposites for large-scale solar hydrogen production.Nature Nanotechnology, 2023, 18(7): 754–762
https://doi.org/10.1038/s41565-023-01385-4
47 X, Li J, Liu G C, Jiang et al.. Self-supported CsPbBr3/Ti3C2Tx MXene aerogels towards efficient photocatalytic CO2 reduction.Journal of Colloid and Interface Science, 2023, 643(11): 174–182
https://doi.org/10.1016/j.jcis.2023.04.015
[1] FMS-23665-OF-Gx_suppl_1 Download
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed