Enhanced mechanical properties of linear segmented shape memory poly(urethane-urea) by incorporating flexible PEG400 and rigid piperazine

doi:10.1007/s11706-012-0181-5

Front Mater Sci

2012, Vol. 6

Issue (4) : 326-337 https://doi.org/10.1007/s11706-012-0181-5

RESEARCH ARTICLE

Enhanced mechanical properties of linear segmented shape memory poly(urethane-urea) by incorporating flexible PEG400 and rigid piperazine

Xiao-Yan ZHANG, Yu-Fei MA, Yong-Gang LI, Pin-Pin WANG, Yuan-Liang WANG, Yan-Feng LUO(

)

Key Lab of Biorheological Science and Technology (Ministry of Education), Research Center for Bio-inspired Material Science and Engineering, College of Bioengineering, Chongqing University, Chongqing 400030, China

Download: PDF(457 KB) HTML
Export: BibTeX | EndNote | Reference Manager | ProCite | RefWorks

Abstract

The goal of this study is to design and synthesize a linear segmented shape memory poly(urethane-urea) (SMPUU) that possesses near-body-temperature shape memory temperature (T_tran) and enhanced mechanical properties by incorporating flexible poly(ethylene glycol) 400 (PEG400) to form poly(D,L-lactic acid)-based macrodiols (PDLLA--PEG400--PDLLA) and then rigid piperazine (PPZ) as a chain extender to form the desired SMPUUs (PEG400--PUU--PPZ). PEG400 increased M_n while maintaining a lower T_g of PDLLA--PEG400--PDLLA, which together with PPZ improved the mechanical properties of PEG400--PUU--PPZ. The obtained optimum SMPUU with enhanced mechanical properties (σ_y = 24.28 MPa; ?_f = 698%; U_f = 181.5 MJ/m³) and a T_g of 40.62°C exhibited sound shape memory properties as well, suggesting a promising SMPUU for in vivo biomedical applications.

Keywords poly(urethane-urea) poly(D L-lactic acid) poly(ethylene glycol) piperazine shape memory property mechanical property

Corresponding Author(s): LUO Yan-Feng,Email:yfluo@cqu.edu.cn

Issue Date: 05 December 2012

Cite this article:

Xiao-Yan ZHANG,Yu-Fei MA,Yong-Gang LI, et al. Enhanced mechanical properties of linear segmented shape memory poly(urethane-urea) by incorporating flexible PEG400 and rigid piperazine[J]. Front Mater Sci, 2012, 6(4): 326-337.

URL:

https://academic.hep.com.cn/foms/EN/10.1007/s11706-012-0181-5
https://academic.hep.com.cn/foms/EN/Y2012/V6/I4/326

1	Ma Z, Hong Y, Nelson D M, . Biodegradable polyurethane ureas with variable polyester or polycarbonate soft segments: effects of crystallinity, molecular weight, and composition on mechanical properties. Biomacromolecules , 2011, 12(9): 3265-3274
2	Wang Y L, Li Y G, Luo Y F, . Synthesis and characterization of a novel biodegradable thermoplastic shape memory polymer. Materials Letters , 2009, 63(3-4): 347-349
3	Chun B C, Cho T K, Chung Y C. Enhanced mechanical and shape memory properties of polyurethane block copolymers chain-extended by ethylene diamine. European Polymer Journal , 2006, 42(12): 3367-3373
4	Mondal S, Hu J L. Polyurethanes: Influence of PEG 3400 studies of shape memory property on thermoplastic segmented polyurethanes: Influence of PEG 3400. Journal Elastomers and Plastics , 2007, 39(1): 81-91
5	Bower D I. An Introduction to Polymer Physics. 1st ed. Cambridge: Cambridge University Press, 2002, 235-238
6	Lendlein A. Shape memory polymers. In: Advances in Polymer Science . Berlin Heidelberg: Springer-Verlag, 2010, 226: 6-9
7	Wang W S, Ping P, Chen X S, . Biodegradable polyurethane based on random copolymer of L-lactide and ?-caprolactone and its shape-memory property. Journal of Applied Polymer Science , 2007, 104(6): 4182-4187
8	Yang J H, Chun B C, Chung Y C, . Comparison of thermal/mechanical properties and shape memory effect of polyurethane block-copolymers with planar or bent shape of hard segment. Polymer , 2003, 44(11): 3251-3258
9	Król P, Król B. Surface free energy of polyurethane coatings with improved hydrophobicity. Colloid & Polymer Science , 2012, 290(10): 879-893
10	Zhang C Y, Luo Y F, Wang S J, . Design, synthesis and characterization of novel biodegradable macrodiols based on poly(DL-lactic acid) and poly(p-dioxanone). Chinese Chemical Letters , 2009, 20(6): 743-746
11	Luo Y F, Huang M N, Wang S J, . Design, synthesis and characterization of novel poly(urethane-urea) based on a macrodiol from poly(lactic acid) and poly(p-dioxanone). Chinese Chemical Letters , 2011, 22(2): 237-240
12	Li X H, Deng X M, Yuan M L, . In vitro degradation and release pro?les of poly-DL-lactide-poly(ethylene glycol) microspheres with entrapped proteins. Journal of Applied Polymer Science , 2000, 78(1): 140-148
13	Ruan G, Feng S-S. Preparation and characterization of poly(lactic acid)–poly(ethylene glycol)–poly(lactic acid) (PLA–PEG–PLA) microspheres for controlled release of paclitaxel. Biomaterials , 2003, 24(27): 5037-5044
14	Zhang J-Y, Beckman E J, Hu J, . Synthesis, biodegradability, and biocompatibility of lysine diisocyanate–glucose polymers. Tissue Engineering , 2002, 8(5): 771-785
15	Szycher M. Biostability of polyurethane elastomers: a critical review. Journal of Biomaterials Applications , 1988, 3(2): 297-402
16	Zheng X T, Zhou S B, Li X H, . Shape memory properties of poly(D,L-lactide)/hydroxyapatite composites. Biomaterials , 2006, 27(24): 4288-4295
17	Ruan C S, Wang Y L, Zhang M L, . Design, synthesis and characterization of novel biodegradable shape memory polymers based on poly(D,L-lactic acid) diol, hexamethylene diisocyanate and piperazine. Polymer International , 2012, 61(4): 524-530
18	Niu X F, Feng Q L, Wang M B, . Porous nano-HA/collagen/PLLA scaffold containing chitosan microspheres for controlled delivery of synthetic peptide derived from BMP-2. Journal of Controlled Release , 2009, 134(2): 111-117
19	Bayraktar H H, Morgan E F, Niebur G L, . Comparison of the elastic and yield properties of human femoral trabecular and cortical bone tissue. Journal of Biomechanics , 2004, 37(1): 27-35
20	Du Y J, Lemstra P J, Nijenhuis A J, . ABA type copolymers of lactide with poly(ethylene glycol), kinetic, mechanistic, and model studies. Macromolecules , 1995, 28(7): 2124-2132
21	Rashkov I, Manolova N, Li S, . Synthesis characterization, and hydrolytic degradation of PLA-PEO-PLA tri-block copolymers with short poly(L-lactic acid) chains. Macromolecules , 1996, 29(1): 50-62
22	Nijenhuis A J, Colstee E, Grijpma D W, . High molecular weight poly (L-lactide) and poly (ethylene oxide) blends: thermal characterization and physical properties. Polymer , 1996, 37(26): 5849-5857
23	Sheth M, Kumar R A, Dave V, . Biodegradable polymer blends of poly(lactic acid) and poly(ethylene glycol). Journal of Applied Polymer Science , 1997, 66(8): 1495-1505
24	Yamamoto T, Furukawa H. Relationship between molecular structure and deformation-fracture mechanism of amorphous polymers: 1 Shear yield stress. Polymer , 1995, 36(12): 2389-2392

[1]	Xiang SUN, Qing-Song YAO, Yu-Chao LI, Fen ZHANG, Rong-Chang ZENG, Yu-Hong ZOU, Shuo-Qi LI. Biocorrosion resistance and biocompatibility of Mg--Al layered double hydroxide/poly(L-lactic acid) hybrid coating on magnesium alloy AZ31[J]. Front. Mater. Sci., 2020, 14(4): 426-441.
[2]	Junbo LI, Junting JIANG, Biyu ZHOU, Chaohuang NIU, Wendi WANG, Wenlan WU. Synthesis of poly(ethylene glycol)-SS-poly(ε-caprolactone)-SS-poly(ethylene glycol) triblock copolymers via end-group conjugation and self-assembly for reductively responsive drug delivery[J]. Front. Mater. Sci., 2019, 13(4): 410-419.
[3]	Zhicun WANG, Xiaoman HAN, Yixi WANG, Kenan MEN, Lin CUI, Jianning WU, Guihua MENG, Zhiyong LIU, Xuhong GUO. Facile preparation of low swelling, high strength, self-healing and pH-responsive hydrogels based on the triple-network structure[J]. Front. Mater. Sci., 2019, 13(1): 54-63.
[4]	Feng LI, Yang LIU, Xu-Bo LI. Dynamic recrystallization behavior of AZ31 magnesium alloy processed by alternate forward extrusion[J]. Front. Mater. Sci., 2017, 11(3): 296-305.
[5]	Xian-Ping WANG,Yi ZHANG,Yu XIA,Wei-Bing JIANG,Hui LIU,Wang LIU,Yun-Xia GAO,Tao ZHANG,Qian-Feng FANG. Enhanced micro-vibration sensitive high-damping capacity and mechanical strength achieved in Al matrix composites reinforced with garnet-like lithium electrolyte[J]. Front. Mater. Sci., 2017, 11(1): 75-81.
[6]	Dongthanh NGUYEN,Wei WANG,Haibo LONG,Hongqiang RU. Facile and controllable preparation of mesoporous TiO₂ using poly(ethylene glycol) as structure-directing agent and peroxotitanic acid as precursor[J]. Front. Mater. Sci., 2016, 10(4): 405-412.
[7]	Qianli HUANG,Xujie LIU,Xing YANG,Ranran ZHANG,Zhijian SHEN,Qingling FENG. Specific heat treatment of selective laser melted Ti–6Al–4V for biomedical applications[J]. Front. Mater. Sci., 2015, 9(4): 373-381.
[8]	Hui-Li DING,Tao ZHANG,Rui GAO,Xian-Ping WANG,Qian-Feng FANG,Chang-Song LIU,Jin-Ping SUO. Low-temperature mechanical and magnetic properties of the reduced activation martensitic steel[J]. Front. Mater. Sci., 2015, 9(3): 264-271.
[9]	Rong SONG,De-Bao LIU,Yi-Chi LIU,Wen-Bo ZHENG,Yue ZHAO,Min-Fang CHEN. Effect of corrosion on mechanical behaviors of Mg--Zn--Zr alloy in simulated body fluid[J]. Front. Mater. Sci., 2014, 8(3): 264-270.
[10]	N. RAGHAVENDRA, H. N. NARASIMHA MURTHY, M. KRISHNA, K. R. VISHNU MAHESH, R. SRIDHAR, S. FIRDOSH, G. ANGADI, S. C. SHARMA. Mechanical behavior of organo-modified Indian bentonite nanoclay fiber-reinforced plastic nanocomposites[J]. Front Mater Sci, 2013, 7(4): 396-404.
[11]	Wen-Guang GUO, Zhi-Ye QIU, Han CUI, Chang-Ming WANG, Xiao-Jun ZHANG, In-Seop LEE, Yu-Qi DONG, Fu-Zhai CUI. Strength and fatigue properties of three-step sintered dense nanocrystal hydroxyapatite bioceramics[J]. Front Mater Sci, 2013, 7(2): 190-195.
[12]	Chang-An WANG, Ming-Fu WANG. Thermal shock behavior of ZrB₂--SiC ceramics with different quenching media[J]. Front Mater Sci, 2013, 7(2): 184-189.
[13]	Shuigen HUANG, Kim VANMEENSEL, Omer VAN DER BIEST, Jozef VLEUGELS. Sintering, thermal stability and mechanical properties of ZrO₂-WC composites obtained by pulsed electric current sintering[J]. Front Mater Sci, 2011, 5(1): 50-56.
[14]	Chang YANG, Yun-Qing KANG, Xiao-Ming LIAO, Ya-Dong YAO, Zhong-Bing HUANG, Guang-Fu YIN, . Preparation of PLGA/β-TCP composite scaffolds with supercritical CO 2 foaming technique[J]. Front. Mater. Sci., 2010, 4(3): 314-320.
[15]	San-bao LIN, Jian-ling SONG, Guang-chao MA, Chun-li YANG. Dissimilar metals TIG welding-brazing of aluminum alloy to galvanized steel[J]. Front Mater Sci Chin, 2009, 3(1): 78-83.

Viewed

Full text

Abstract

Cited

Shared

Discussed