Preparation and properties of poly HTBN-based urethane--urea/organo reactive montmorillonite nanocomposites

doi:10.1007/s11706-012-0185-1

Front Mater Sci

2012, Vol. 6

Issue (4) : 338-346 https://doi.org/10.1007/s11706-012-0185-1

RESEARCH ARTICLE

Preparation and properties of poly HTBN-based urethane--urea/organo reactive montmorillonite nanocomposites

Zai-Feng LI¹(

), Yuan WU¹, Fu-Tao ZHANG², Yu-Yang CAO¹, Shou-Peng WU¹, Ting WANG¹

1. State Key Laboratory Base of Eco-chemical Engineering, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, China; 2. Oil Production Institute of Shengli Oilfield, Dongying 257001, China

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Abstract

With ultrasonic assistant mixing way, an intercalated mixture of polyol/organo reactive montmorillonite (ORMMT) was pretreated. The prepolymer composed MMT clay was prepared by reaction of polyol/ORMMT mixture with toluene diisocyanate (TDI). The resultant prepolymer reacted with extender (DMTDA) and then the polyurethane--urea/organo reactive montmorillonite (PUU/ORMMT) nanocomposites were obtained. The structure, morphology and properties of PUU/ORMMT nanocomposites were characterized by FT-IR, TEM, AFM, strain-stress machine, TGA, and dynamic mechanical analysis (DMA). The results showed that when the OMMT content is 3%, the PUU/ORMMT nanocomposities performed super mechanical properties. Because of the presence of ORMMT, both T_g of the soft segment and tanδ of the PUU increased, and the decomposition temperature for the first step and the second step increased respectively. TEM images showed that the organophilic MMT particles in the PUU composite exhibit a high degree of intercalation and exfoliation.

Keywords polyurethane--urea (PUU) organo-MMT morphology dynamic mechanical analysis (DMA) nanocomposite

Corresponding Author(s): LI Zai-Feng,Email:lizfengphd@126.com

Issue Date: 05 December 2012

Cite this article:

Zai-Feng LI,Yuan WU,Fu-Tao ZHANG, et al. Preparation and properties of poly HTBN-based urethane--urea/organo reactive montmorillonite nanocomposites[J]. Front Mater Sci, 2012, 6(4): 338-346.

URL:

https://academic.hep.com.cn/foms/EN/10.1007/s11706-012-0185-1
https://academic.hep.com.cn/foms/EN/Y2012/V6/I4/338

Fig.1 FT-IR spectra of PUU/ORMMT nanocomposites with the ORMMT content of 0 wt.% (a), 3 wt.% (b), 6 wt.% (c) and 8 wt.% (d).

Tab.1 Effect of the ORMMT content on the mechanical properties of HTBN–PUU

Fig.2 TGA curves of HTBN–PU/montromollite clay nanocomposites with the ORMMT content of 0%, 3%, 6%, and 8%.

Fig.3 DMA curves of HTBN-PU/montromollite nanocomposites with the ORMMT content of () 0%, 3%, and 6%.

Fig.4 TEM images of HTBN–PUU/ORMMT nanocomposites with the ORMMT content of 3%, 6%, and 8%.

Fig.5 AFM images of ORMMT/PUU nanocomposites with the ORMMT content of 3%, 6%, and 8%.

1	Zhang X, Bhuvana S, Loo L S. Characterization of layered silicate dispersion in polymer nanocomposites using Fourier transform infrared spectroscopy. Journal of Applied Polymer Science , 2012, 125(S1): E175–E180
2	Pandey P, Anbudayanidhi S, Mohanty S, . Flammability and thermal characterization of PMMA/clay nanocomposites and thermal kinetics analysis. Polymer Composites , 2012, 33(11): 2058–2071
3	Zhang X, Loo L S. Variable-temperature Fourier transform infrared studies of matrix–nanofiller interactions in amorphous polyamide/layered silicate nanocomposites. Journal of Applied Polymer Science , 2012, 126(S2): E371–E379
4	Castiello S, Coltelli M-B, Conzatti L, . Comparative study about preparation of poly(lactide)/organophilic montmorillonites nanocomposites through melt blending or ring opening polymerization methods. Journal of Applied Polymer Science , 2012, 125(S1): E413–E428
5	Salahuddin N, Abo-El-Enein S A, Selim A, . Synthesis and characterization of polyurethane–urea clay nanocomposites using montmorillonite modified by oxyethylene–oxypropylene copolymer. Polymers for Advanced Technologies , 2010, 21(8): 533–542
6	Han X-J, Huang Z-M, Huang C, . Preparation and characterization of electrospun polyurethane/inorganic-particles nanofibers. Polymer Composites , 2012, 33(11): 2045–2057
7	Khan A S, Wong F S L, McKay I J, . Structural, mechanical, and biocompatibility analyses of a novel dental restorative nanocomposite. Journal of Applied Polymer Science , 2013, 127(1): 439–447
8	Barick A K, Tripathy D K. Effect of organoclay on the morphology, mechanical, thermal, and rheological properties of organophilic montmorillonite nanoclay based thermoplastic polyurethane nanocomposites prepared by melt blending. Polymer Engineering & Science , 2010, 50(3): 484–498
9	Zilg C, Thomann R, Mülhaupt R, . Polyurethane nanocomposites containing laminated anisotropic nanoparticles derived from organophilic layered silicates. Advanced Materials , 1999, 11(1): 49–52
10	Finnigan B, Martin D, Halley P, . Morphology and properties of thermoplastic polyurethane nanocomposites incorporating hydrophilic layered silicates. Polymer , 2004, 45(7): 2249–2260
11	Mishra J K, Kim I, Ha C S. New millable polyurethane/organoclay nanocomposite: preparation, characterization and properties. Macromolecular Rapid Communications , 2003, 24(11): 671– 675
13	Ma J S, Zhang S F, Qi Z N. Synthesis and characterization of elastomeric polyurethane/clay nanocomposites. Journal of Applied Polymer Science , 2001, 82(6): 1444–1448
14	Chen T K, Tien Y I, Wei K H. Synthesis and characterization of novel segmented polyurethane/clay nanocomposite via poly(?-caprolactone)/clay. Journal of Polymer Science Part A: Polymer Chemistry , 1999, 37(13): 2225–2233
15	Chen T-K, Tien Y-I, Wei K-H. Synthesis and characterization of novel segmented polyurethane/clay nanocomposite. Polymer , 2000, 41(4): 1345–1353
16	Osman M A, Mittal V, Morbidelli M, . Polyurethane adhesive nanocomposites as gas permeation barrier. Macromolecules , 2003, 36(26): 9851–9858
18	Xia H S, Shaw S J, Song M. Relationship between mechanical properties and defoliation degree of clay in polyurethane nanocomposites. Polymer International , 2005, 54(10): 1392–1400
19	Li Z-F, Ma T, Ma X-L, . Investigation of properties for the intercalative behavior of the cationic polyether polyurethane polyelectrolyte on the MMT clay. Polymer Materials Science & Engineering , 2007, 23(1): 48–52 (in Chinese)
20	Sun B Q, Shi Z T, Li J Y, . Structure and properties of polyurethane/organic montmorillonite nanocomposites II. Effect of ultrasonic dispersion on structure and properties of polyurethane–urea/organic montmorilonite nanocomposites. China Synthetic Rubber Industry , 2008, 31(2): 148–151 (in Chinese)
21	French D M. Functionally terminated butadiene polymers. Rubber Chemistry and Technology , 1969, 42(1): 71–109
22	Li Z Y, Yang Z, Zhang Q Y. Calculation formula and synthesis for controlling the composition of hydroxy-terminated butadiene acrylonitrile cooligomer. Acta Chimica Sinica , 1999, 57(9): 1038–1042 (in Chinese)
23	Singh B, Gupta M, Randhawa A, . Hybrid polymer networks of unsaturated polyester–urethane as composite matrices for jute reinforcement. Journal of Applied Polymer Science , 2011, 122(2): 1206–1218
24	Bao J-J, Gao M-Z, Zhou H-F, . Advance on the application of atomic force microscope to polyurethane material analysis. China Elastomerics , 2006, 16(3): 53–57 (in Chinese)
25	Kojio K, Kugumiya S, Furukawa M. Atomic force microscopic study on the microphase separation of polyurethanes. Symposium of International Rubber Conference , 2004, 357 –359

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