Please wait a minute...
Frontiers of Materials Science

ISSN 2095-025X

ISSN 2095-0268(Online)

CN 11-5985/TB

Postal Subscription Code 80-974

2018 Impact Factor: 1.701

Front. Mater. Sci.    2014, Vol. 8 Issue (3) : 264-270    https://doi.org/10.1007/s11706-014-0258-4
RESEARCH ARTICLE
Effect of corrosion on mechanical behaviors of Mg--Zn--Zr alloy in simulated body fluid
Rong SONG1,De-Bao LIU1,*(),Yi-Chi LIU1,Wen-Bo ZHENG1,Yue ZHAO1,2,Min-Fang CHEN1
1. School of Materials Science and Engineering, Tianjin University of Technology, Tianjin 300384, China
2. School of Mechanical, Materials and Mechatronic Engineering, Faculty of Engineering and Information Sciences, University of Wollongong, Northfield Ave, Wollongong, NSW 2522, Australia
 Download: PDF(2265 KB)   HTML
 Export: BibTeX | EndNote | Reference Manager | ProCite | RefWorks
Abstract

The main purpose of this paper is to investigate the effect of corrosion on mechanical behaviors of the Mg--Zn--Zr alloy immersed in simulated body fluid (SBF) with different immersion times. The corrosion behavior of the materials in SBF was determined by immersion tests. The surfaces of the corroded alloys were examined by SEM. The tensile samples of the extruded Mg--2Zn--0.8Zr magnesium alloy were immersed in the SBF for 0, 4, 7, 10, 14, 21 and 28 d. The tensile mechanical behaviors of test samples were performed on an electronic tensile testing machine. SEM was used to observe the fracture morphology. It was found that with extension of the immersion time, the ultimate tensile strength (UTS), yield strength (YS) and elongation (EL) of the Mg–2Zn–0.8Zr samples decreased rapidly at first and then decreased slowly. The main fracture mechanism of the alloy transformed from ductile fracture to cleavage fracture with the increasing immersion times, which can be attributed to stress concentration and embrittlement caused by pit corrosion.

Keywords magnesium alloy      simulated body fluid      mechanical property      fracture mechanism     
Corresponding Author(s): De-Bao LIU   
Online First Date: 27 August 2014    Issue Date: 12 September 2014
 Cite this article:   
Rong SONG,De-Bao LIU,Yi-Chi LIU, et al. Effect of corrosion on mechanical behaviors of Mg--Zn--Zr alloy in simulated body fluid[J]. Front. Mater. Sci., 2014, 8(3): 264-270.
 URL:  
https://academic.hep.com.cn/foms/EN/10.1007/s11706-014-0258-4
https://academic.hep.com.cn/foms/EN/Y2014/V8/I3/264
Fig.1  Diagrammatic sketch of the tensile sample.
Fig.2  The solution container for the tensile test sample.
Fig.3  OM microstructures of the Mg–2Zn–0.8Zr alloy experienced an extrusion and aging treatment.
Fig.4  The Nyquist diagram of Mg–2Zn–0.8Zr immersed in SBF for 6 h–7 d.
Fig.5  Surface morphology of Mg–2Zn–0.8Zr alloy after immersion in SBF for (a) 6 h, (b) 24 h, (c) 4 d, (d) 7 d, (e) 14 d and (f) 21 d.
Fig.6  Corrosion morphologies of the magnesium alloys after immersion in SBF for 14 d: (a) cross-section; (b) surface.
Fig.7  Stress–strain curves of Mg–2Zn–0.8Zr alloy tested after immersion of 0, 4, 7, 10, 14, 21 and 28 d in SBF.
Fig.8  The variation in UTS, YS and EL of Mg–2Zn–0.8Zr alloy in different immersion times.
Fig.9  Fractography of the tensile samples after immersion in SBF for (a) 0 d, (b) 4 d, (c) 14 d, and (d) 21 d.
1 Staiger M P, Pietak A M, Huadmai J, . Magnesium and its alloys as orthopedic biomaterials: a review. Biomaterials, 2006, 27(9): 1728–1734
2 Zheng Y F, Gu X N, Witte F. Biodegradable metals. Materials Science and Engineering R: Reports, 2014, 77: 1–34
3 Witte F, Hort N, Vogt C, . Degradable biomaterials based on magnesium corrosion. Current Opinion in Solid State and Materials Science, 2008, 12(5–6): 63–72
4 Witte F. The history of biodegradable magnesium implants: a review. Acta Biomaterialia, 2010, 6(5): 1680–1692
5 Choudhary L, Singh Raman R K. Magnesium alloys as body implants: fracture mechanism under dynamic and static loadings in a physiological environment. Acta Biomaterialia, 2012, 8(2): 916–923
6 Erinc M, Sillekens W H, Mannens R, . Magnesium Technology. PA: TMS Warrendale, 2009, 209–214
7 Choudhary L, Singh Raman R K. Mechanical integrity of magnesium alloys in a physiological environment: Slow strain rate testing based study. Engineering Fracture Mechanics, 2013, 103: 94–102
8 Winzer N, Atrens A, Dietzel W, . Characterization of stress corrosion cracking (SCC) of Mg–Al alloys. Materials Science and Engineering A, 2008, 488(1–2): 339–351
9 Atrens A, Dietzel W, Bala Srinivasan P, . Stress corrosion cracking (SCC) of magnesium alloys. In: Stress Corrosion Cracking: Theory and Practice. Cambridge, UK: Woodhead Publishing, 2011, 341–380
10 Wang Q, Liu Y, Zhu X, . Study on the effect of corrosion on the tensile properties of the 1.0 wt% yttrium modified AZ91 magnesium alloy. Materials Science and Engineering A, 2009, 517(1–2): 239–245
11 Zeng R, Han E, Ke W. Influence of load frequency and ageing heat treatment on fatigue crack propagation rate of as-extruded AZ61 alloy. International Journal of Fatigue, 2009, 31(3): 463–467
12 ASTM G31-72 Standard Practice for Laboratory Immersion Corrosion Testing of Metals
13 Li C, Liu Y, Wang Q, . Study on the corrosion residual strength of the 1.0 wt% Ce modified AZ91 magnesium alloy. Materials Characterization, 2010, 61(1): 123–127
14 Song G. Corrosion Prevention of Magnesium Alloys. UK: Woodhead Publishing Limited, 2013
15 Bobby Kannan M, Dietzel W. Pitting-induced hydrogen embrittlement of magnesium–aluminium alloy. Materials & Design, 2012, 42: 321–326
16 Chen J, Wang J, Han E, . Effect of hydrogen on stress corrosion cracking of magnesium alloy in 0.1 M Na2SO4 solution. Materials Science and Engineering A, 2008, 488(1–2): 428–434
17 Song G. Corrosion of Magnesium Alloys. UK: Woodhead publishing Limited, 2011
[1] Xiang SUN, Qing-Song YAO, Yu-Chao LI, Fen ZHANG, Rong-Chang ZENG, Yu-Hong ZOU, Shuo-Qi LI. Biocorrosion resistance and biocompatibility of Mg--Al layered double hydroxide/poly(L-lactic acid) hybrid coating on magnesium alloy AZ31[J]. Front. Mater. Sci., 2020, 14(4): 426-441.
[2] Lei CHANG, Xiangrui LI, Xuhui TANG, He ZHANG, Ding HE, Yujun WANG, Jiayin ZHAO, Jingan LI, Jun WANG, Shijie ZHU, Liguo WANG, Shaokang GUAN. Micro-patterned hydroxyapatite/silk fibroin coatings on Mg--Zn--Y--Nd--Zr alloys for better corrosion resistance and cell behavior guidance[J]. Front. Mater. Sci., 2020, 14(4): 413-425.
[3] Zheng-Zheng YIN, Wei HUANG, Xiang SONG, Qiang ZHANG, Rong-Chang ZENG. Self-catalytic degradation of iron-bearing chemical conversion coating on magnesium alloys ---- Influence of Fe content[J]. Front. Mater. Sci., 2020, 14(3): 296-313.
[4] Zai-Meng QIU, Fen ZHANG, Jun-Tong CHU, Yu-Chao LI, Liang SONG. Corrosion resistance and hydrophobicity of myristic acid modified Mg--Al LDH/Mg(OH)2 steam coating on magnesium alloy AZ31[J]. Front. Mater. Sci., 2020, 14(1): 96-107.
[5] Mengke PENG, Fenyan HU, Minting DU, Bingjie MAI, Shurong ZHENG, Peng LIU, Changhao WANG, Yashao CHEN. Hydrothermal growth of hydroxyapatite and ZnO bilayered nanoarrays on magnesium alloy surface with antibacterial activities[J]. Front. Mater. Sci., 2020, 14(1): 14-23.
[6] Xiao-Jing JI, Qiang CHENG, Jing WANG, Yan-Bin ZHAO, Zhuang-Zhuang HAN, Fen ZHANG, Shuo-Qi LI, Rong-Chang ZENG, Zhen-Lin WANG. Corrosion resistance and antibacterial effects of hydroxyapatite coating induced by polyacrylic acid and gentamicin sulfate on magnesium alloy[J]. Front. Mater. Sci., 2019, 13(1): 87-98.
[7] Zhicun WANG, Xiaoman HAN, Yixi WANG, Kenan MEN, Lin CUI, Jianning WU, Guihua MENG, Zhiyong LIU, Xuhong GUO. Facile preparation of low swelling, high strength, self-healing and pH-responsive hydrogels based on the triple-network structure[J]. Front. Mater. Sci., 2019, 13(1): 54-63.
[8] Lian GUO, Fen ZHANG, Jun-Cai LU, Rong-Chang ZENG, Shuo-Qi LI, Liang SONG, Jian-Min ZENG. A comparison of corrosion inhibition of magnesium aluminum and zinc aluminum vanadate intercalated layered double hydroxides on magnesium alloys[J]. Front. Mater. Sci., 2018, 12(2): 198-206.
[9] Ling-Yu LI, Bin LIU, Rong-Chang ZENG, Shuo-Qi LI, Fen ZHANG, Yu-Hong ZOU, Hongwei (George) JIANG, Xiao-Bo CHEN, Shao-Kang GUAN, Qing-Yun LIU. In vitro corrosion of magnesium alloy AZ31 --- a synergetic influence of glucose and Tris[J]. Front. Mater. Sci., 2018, 12(2): 184-197.
[10] Feng LI, Yang LIU, Xu-Bo LI. Dynamic recrystallization behavior of AZ31 magnesium alloy processed by alternate forward extrusion[J]. Front. Mater. Sci., 2017, 11(3): 296-305.
[11] Xian-Ping WANG,Yi ZHANG,Yu XIA,Wei-Bing JIANG,Hui LIU,Wang LIU,Yun-Xia GAO,Tao ZHANG,Qian-Feng FANG. Enhanced micro-vibration sensitive high-damping capacity and mechanical strength achieved in Al matrix composites reinforced with garnet-like lithium electrolyte[J]. Front. Mater. Sci., 2017, 11(1): 75-81.
[12] Tao JIN,Fan-mei KONG,Rui-qin BAI,Ru-liang ZHANG. Anti-corrosion mechanism of epoxy-resin and different content Fe2O3 coatings on magnesium alloy[J]. Front. Mater. Sci., 2016, 10(4): 367-374.
[13] Li-Da HOU,Zhen LI,Yu PAN,MuhammadIqbal SABIR,Yu-Feng ZHENG,Li LI. A review on biodegradable materials for cardiovascular stent application[J]. Front. Mater. Sci., 2016, 10(3): 238-259.
[14] Yu-Hong ZOU,Rong-Chang ZENG,Qing-Zhao WANG,Li-Jun LIU,Qian-Qian XU,Chuang WANG,Zhiwei LIU. Blood compatibility of zinc–calcium phosphate conversion coating on Mg–1.33Li–0.6Ca alloy[J]. Front. Mater. Sci., 2016, 10(3): 281-289.
[15] Lan-Yue CUI,Rong-Chang ZENG,Xiao-Xiao ZHU,Ting-Ting PANG,Shuo-Qi LI,Fen ZHANG. Corrosion resistance of biodegradable polymeric layer-by-layer coatings on magnesium alloy AZ31[J]. Front. Mater. Sci., 2016, 10(2): 134-146.
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed