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Tailoring properties of reticulated vitreous carbon foams with tunable density |
Oleg SMORYGO1,*(),Alexander MARUKOVICH1,Vitali MIKUTSKI1,Vassilis STATHOPOULOS2,Siarhei HRYHORYEU3,Vladislav SADYKOV4,5 |
1. Powder Metallurgy Institute, National Academy of Sciences of Belarus, 41 Platonov Str., Minsk 220005, Belarus 2. Technological Educational Institute of Sterea Ellada, Psahna Evias 34400, Greece 3. Belarusian National Technical University, 65 Nezavisimosty Ave., Minsk 220013, Belarus 4. Boreskov Institute of Catalysis, Sibrian Branch of Russian Academy of Sciences, 5 Lavrentiev Ave., 630090, Novosibirsk, Russia 5. Novosibirsk State University, 2 Pirogova Str., 630009, Novosibirsk, Russia |
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Abstract Reticulated vitreous carbon (RVC) foams were manufactured by multiple replications of a polyurethane foam template structure using ethanolic solutions of phenolic resin. The aims were to create an algorithm of fine tuning the precursor foam density and ensure an open-cell reticulated porous structure in a wide density range. The precursor foams were pyrolyzed in inert atmospheres at 700°C, 1100°C and 2000°C, and RVC foams with fully open cells and tunable bulk densities within 0.09–0.42 g/cm3 were synthesized. The foams were characterized in terms of porous structure, carbon lattice parameters, mechanical properties, thermal conductivity, electric conductivity, and corrosive resistance. The reported manufacturing approach is suitable for designing the foam microstructure, including the strut design with a graded microstructure.
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Keywords
foam
vitreous carbon
reticulated
cellular structure
pyrolysis
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Corresponding Author(s):
Oleg SMORYGO
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Online First Date: 13 April 2016
Issue Date: 11 May 2016
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1 |
Friedrich J M, Ponce-de-Leon C, Reade G W, . Reticulated vitreous carbon as an electrode material. Journal of Electroanalytical Chemistry, 2004, 561: 203–217
|
2 |
Czarnecki J S, Blackmore M, Jolivet S, . Bone growth on Reticulated Vitreous Carbon foam scaffolds and implementation of Cellular Automata modeling as a predictive tool. Carbon, 2014, 79: 135–148
|
3 |
Banerjee A, Saha D, Guru Row T N, . A soluble-lead redox flow battery with corrugated graphite sheet and reticulated vitreous carbon as positive and negative current collectors. Bulletin of Materials Science, 2013, 36(1): 163–170
|
4 |
Chakhovskoi A G, Hunt C E, Forsberg G, . Reticulated vitreous carbon field emission cathodes for light source applications. Journal of Vacuum Science & Technology B, 2003, 21(1): 571–575
|
5 |
Gallego N C, Klett J W. Carbon foams for thermal management. Carbon, 2003, 41(7): 1461–1466
|
6 |
Li Q, Batchelor-McAuley C, Lawrence N S, . A flow system for hydrogen peroxide production at reticulated vitreous carbon via electroreduction of oxygen. Journal of Solid State Electrochemistry, 2014, 18(5): 1215–1221
|
7 |
Xiao N, Zhou Y, Ling Z, . Carbon foams made of in situ produced carbon nanocapsules and the use as a catalyst for oxidative dehydrogenation of ethylbenzene. Carbon, 2013, 60: 514–522
|
8 |
Gokhale A A, Kumar N V R, Sudhakar B, . Cellular metals and ceramics for defence applications. Defence Science Journal, 2011, 61(5): 567–575
|
9 |
Xiao N, Zhou Y, Ling Z, . Synthesis of a carbon nanofiber/carbon foam composite from coal liquefaction residue for the separation of oil and water. Carbon, 2013, 59: 530–536
|
10 |
Letellier M, Macutkevic J, Paddubskaya A, . Microwave dielectric properties of tannin-based carbon foams. Ferroelectrics, 2015, 479(1): 119–126
|
11 |
Xiao N, Ling Z, Zhou Y, . Synthesis and structure of carbon belts made of carbon nanofibers supported on carbon foams. Carbon, 2013, 61: 386–394
|
12 |
Goncalves E S, Dalmolin C, Biaggio S R, . Influence of heat treatment temperature on the morphological and structural aspects of reticulated vitreous carbon used in polyaniline electrosynthesis. Applied Surface Science, 2007, 253(20): 8340–8344
|
13 |
Manocha S M, Patel K, Manocha L M. Development of carbon foam from phenolic resin via template route. Indian Journal of Engineering & Materials Science., 2010, 17(5): 338–342
|
14 |
Inagaki M, Qiu J S, Guo Q G. Carbon foam: preparation and application. Carbon, 2015, 87: 128–152
|
15 |
Cowlard F C, Lewis J C. Vitreous carbon - a new form of carbon. Journal of Materials Science, 1967, 2(6): 507–512
|
16 |
Smorygo O, Marukovich A, Mikutski V, . Macrocellular vitreous carbon with the improved mechanical strength. Frontiers of Materials Science, 2015, 9(4): 413–417
|
17 |
Zhang Y, Yuan Z, Zhou Y. Effect of furfural alcohol/phenol-formaldehyde resin mass ratio on the properties of porous carbon. Materials Letters, 2013, 109: 124–126
|
18 |
Martinez de Yuso A, Lagel M C, Pizzi A, . Structure and properties of rigid foams derived from quebracho tannin. Materials & Design, 2014, 63: 208–212
|
19 |
Tondi G, Fierro V, Pizzi A, . Tannin-based carbon foams. Carbon, 2009, 47(6): 1480–1492
|
20 |
ERG Materials and Aerospace Corporation. 900 Stanford Avenue, Oakland, CA 94608, USA: Duocel® reticulated vitreous carbon foam datasheet
|
21 |
Ultramet. Advanced Materials Solutions. 12173 Montague Street, Pacoima CA 91331, USA: Reticulated vitreous carbon foam datasheet
|
22 |
Ashby M F. The properties of foams and lattices. Philosophical Transactions of the Royal Society A, 2006, 364(1838): 15–30
|
23 |
Smorygo O, Mikutski V, Marukovich A, . An inverted spherical model of an open-cell foam structure. Acta Materialia, 2011, 59(7): 2669–2678
|
24 |
Jana P, Fierro V, Pizzi A, . Thermal conductivity improvement of composite carbon foams based on tannin-based disordered carbon matrix and graphite fillers. Materials & Design, 2015, 83: 635–643
|
25 |
Pekala W R, Hopper R W. Low-density microcellular carbon foams. Journal of Materials Science, 1987, 22(5): 1840–1844
|
26 |
Leonov A N, Smorygo O L, Sheleg V K. Monolithic catalyst supports with foam structure. Reaction Kinetics and Catalysis Letters, 1997, 60(2): 259–267
|
27 |
Klug H P, Alexander L E. X-ray Diffraction Procedures for Polycrystalline and Amorphous Materials. 2nd ed. New York: Wiley, 1974
|
28 |
Kurauchi T, Sato N, Kamigaito O, . Mechanism of high energy absorption by foamed materials-foamed rigid polyurethane and foamed glass. Journal of Materials Science, 1984, 19(3): 871–880
|
29 |
Gibson L J, Ashby M F. The mechanics of three-dimensional cellular materials. Proceedings of the Royal Society of London. Series A, 1782, 1982(382): 43–59
|
30 |
Brezny R, Green D. Fracture behavior of open-cell ceramics. Journal of the American Ceramic Society, 1989, 72(7): 1145–1152
|
31 |
Li X, Basso M C, Braghiroli F L, . Tailoring the structure of cellular vitreous carbon foams. Carbon, 2012, 50(5): 2026–2036
|
32 |
Szczurek A, Fierro V, Pizzi A, . Carbon meringues derived from flavanoid tannins. Carbon, 2013, 65: 214–227
|
33 |
Klett J W, McMillan A D, Gallego N C, . The role of structure on the thermal properties of graphitic foams. Journal of Materials Science, 2004, 39(11): 3659–3676
|
34 |
Nakamura K, Morooka H, Tanabe Y, . Surface oxidation and/or corrosion behavior of glass-like carbon in sulfuric and nitric acids, and in aqueous hydrogen peroxide. Corrosion Science, 2011, 53(12): 4010–4013
|
35 |
Nakamura K, Tanabe Y, Yasuda E. Analysis of the oxidation behavior of neat and Ta-alloyed glass-like carbons heat-treated at 1200 and 3000°C by nitric, sulfuric and hydrofluoric acid. Journal of Alloys and Compounds, 2006, 414(1–2): 186–189
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